Search results for "Complex."
showing 10 items of 5824 documents
Crystal structure of bis(μ2-methanolato-κO:κO)hexamethylbis(μ2-triphenylacetato-κO:κO′)bis(μ2-triphenylacetato-κ2O,O′:κO)dialuminiumdilanthanum tolue…
2018
The complex [{La(Ph3CCOO)2(Me3AlOMe)}2] has an La2(μ-OCO)4 core, contains the carboxylate ligands in μ2-κ1 O:κ1 O′ bridging and μ2-κ2 O,O′:κ1 O semi-bridging coordination modes, and displays La—C interactions with the π-system of a phenyl ring.
Import and impact : characterization of parvovirus-nucleus interactions
2016
Metabolic Changes in Tumor Microenvironment: How Could They Affect γδ T Cells Functions?
2021
The metabolic changes that occur in tumor microenvironment (TME) can influence not only the biological activity of tumor cells, which become more aggressive and auto sustained, but also the immune response against tumor cells, either producing ineffective responses or polarizing the response toward protumor activity. γδ T cells are a subset of T cells characterized by a plasticity that confers them the ability to differentiate towards different cell subsets according to the microenvironment conditions. On this basis, we here review the more recent studies focused on altered tumor metabolism and γδ T cells, considering their already known antitumor role and the possibility of manipulating th…
On the mechanism of imine elimination from Fischer tungsten carbene complexes
2016
(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)5W=C(NHFc)Fc (W(CO)5(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)5W=C(OEt)Fc (M(CO)5(1Et)) by ferrocenyl amide Fc-NH– (Fc = ferrocenyl). W(CO)5(E-2) thermally and photochemically eliminates bulky E-1,2-diferrocenylimine (E-3) via a formal 1,2-H shift from the N to the carbene C atom. Kinetic and mechanistic studies to the formation of imine E-3 are performed by NMR, IR and UV–vis spectroscopy and liquid injection field desorption ionization (LIFDI) mass spectrometry as well as by trapping experiments for low-coordinate tungsten complexes with triphenylphosphane. W(CO)5(E-2) decays thermally i…
Emergence of scattered and leapfrog urban development : from analytical proof to complex simulation outputs with realistic calibration
2013
International audience
Ureteral stent encrustation: evaluation of available scores as predictors of a complex surgery
2022
Background: Stent Encrustation is an uncommon event (13%) with a significant impact in patients' management. Aim of our study was to evaluate the available grading systems for encrusted stents. Methods: A retrospective analysis of encrusted stents was performed in four Italian centers between 2006 and 2020. Encrusted stents were classified according to four classifications: the Forgotten Encrusted Calcificated (FECal) score, the Kidney Ureter Bladder (KUB) score, the Visual Grading for Ureteral Encrusted Stent Classification and the Encrustation Burden Score (EBS). Classifications were evaluated to predict complex surgery defined as: long operative time (>60min); need of more than one su…
PHILOSOPHICAL INVESTIGATIONS ON INTEGRATIVE COMPLEXITY
2019
Integrative complexity (IC) refers to a psychological construct, a measurement, and an experience. As a construct IC refers to our less than conscious thinking style in the face of difference or disagreement, how we process information, make decisions, solve problems. The cross-culturally validated empirical measurement frame of IC has predictive values. ’Low IC’ indicates a simple thinking style that is rigid and closed, a ’tunnel vision’ way of thinking that cannot respect or recognize different dimensions or perspectives on a topic, predicting destructive conflict or violence. An increasingly complex thinking style is able to ’see the big picture’, to …
Variational approach for analysis of harmonic vibration and stabiligy of moving panels
2014
In this paper, the stability of a simply supported axially moving elastic panel (plate undergoing cylindrical deformation) is considered. A complex variable technique and bifurcation theory are applied. As a result, variational equations and a variational principle are derived. Analysis of the variational principle allows the study of qualitative properties of the bifurcation points. Asymptotic behaviour in a small neighbourhood around an arbitrary bifurcation point is analyzed and presented. It is shown analytically that the eigenvalue curves in the (ω, V0) plane cross both the ω and V0 axes perpendicularly. It is also shown that near each bifurcation point, the dependence ω(V0) for each m…
Complex Authority Network Interactions in the Common Information Sharing Environment
2019
European authorities collaborate as a community toward a coherent approach of situational understanding and open trust base information sharing. Innovation in multi-stakeholder collaboration networks involve complex collaboration between user community members, providing cross-sector, cross-border and cross-authority interaction and information sharing for collaborative situation awareness, and cooperation to increase safety and security. This study analyses data consisting of elements of use cases, collected from EU funded innovation projects. These were placed in a table based on similarity, difference and relevance to produce a classification. The results of this study indicate that use …
EFFETTI DELLA PROTEZIONE E DELLA COMPLESSITÀ TOPOGRAFICA SUI POPOLAMENTI BENTONICI DEI REEF A VERMETI
2009
Vermetid reef can be considered a key intertidal habitat of Mediterranean Sea and increasing knowledge about this natural system is important for its conservation. Aims of this study is to assess topography complexity, structure and composition of the benthic assemblages associated to reef formation in a marine protected area highlighting possible effects of the protection.