Search results for "Complex"
showing 10 items of 5889 documents
Introduction to the Symposium on Exploring the Complexities of Performance Management
2017
ABSTRACTThe editors of this symposium hope that this collection of articles can help advance the public administration literature stream across the multiple organizational and cultural settings in which these performance management studies were conducted. However, this symposium also focused on articles that can help advance the practice of performance management, where specific recommendations are needed to help public officials collect, analyze, and use meaningful outcome measures specifically for the benefits for making better management and policy decisions.
An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide
2016
The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings. peerReviewed
Preparation of a Series of “Ru(p-cymene)” Complexes with Different N-Heterocyclic Carbene Ligands for the Catalytic β-Alkylation of Secondary Alcohol…
2008
A series of five different “(p-cymene)Ru(NHC)” complexes (NHC = imidazolin-2-ylidene, imidazolin-4-ylidene, and pyrazolin-3-ylidene) have been obtained and fully characterized. The crystal structure of two of the new complexes has been determined by X-ray diffraction methods. All five complexes have been tested in the catalytic β-alkylation of secondary alcohols with primary alcohols and the dimerization of phenylacetylene, showing an excellent activity in both processes. A clear improvement on the catalytic activity of the complexes is observed when the more basic NHC ligands are used. The pyrazolylidene-Ru complex lies among the best catalysts for the β-alkylation of secondary alcohols re…
Net currents obtained from zero-average potentials in single amphoteric nanopores
2013
We have studied experimentally and theoretically the rectifying properties of a single asymmetric nanopore functionalized with amphoteric lysine groups and characterized the net current obtained with zero-average time dependent potentials. The pH-controlled rectification phenomena may be relevant to bio-electrochemistry, pH sensing and regulation, and energy conversion. (C) 2013 Elsevier B.V. All rights reserved.
Avaluació d´un programa d´intervenció multidisciplinària i multidimensional destinat a optimitzar la terapèutica del pacient crònic complex
2022
Objetivo: Evaluar las mejoras derivadas de la utilización de la Guía de revisión de la medicación en pacientes crónicos complejos (GRMPCC) en la revisión de la medicación en términos d´optimización y adecuación farmacoterapéutica (FT) y alineamiento entre los objetivos FT y los clínico-asistenciales establecidos en el plan individual de decisiones avanzadas. Métodos: Para evaluar el impacto de la aplicación en la práctica asistencial de la metodología de revisión de la medicación en pacientes crónicos complejos ambulatorios basada en la GRMPCC se diseñó y realizó un estudio de intervención cuasi-experimental, multicéntrico, longitudinal y ambispectivo. El estudio se realizó entre noviembre …
Combustion behavior of black liquors : droplet swelling and influence of liquor composition
2017
The combustion of black liquor (BL) in a recovery boiler is a central process in a kraft pulp mill for recovering the cooking chemicals and for producing heat and power. This work explored the most important combustion behavior of BL, the swelling of in-flight droplets, from the viewpoint of liquor composition. It also studied the combustion behavior of BL droplets obtained from two biorefining subprocesses (carbonation and hot-water pretreatment, HWP) and sulfur-free pulping alternatives (soda-anthraquinone (AQ) and oxygen-alkali pulping). The formation of a plastic state essential for the swelling of BL droplet was found to result from the melting of an array of carbohydrate-derived aliph…
Promotions and Earnings – Gender or Merit? Evidence from Longitudinal Personnel Data
2017
This study examines the determinants of promotions, performance evaluations and earnings using unique longitudinal data from the personnel records of a large university. The study focuses on the role of gender in remuneration using, first, information on the complexity ratings of job tasks to define promotions on job ladders and, second, information on objective individual productivity. The study finds that individual research productivity was an important determinant of promotions and earnings. The results indicate that gender has no effect on the probability of being promoted, conditional on productivity, nor does it play a role in the performance evaluation of employees. Furthermore, the…
A Cation-Captured Palladium(0) Anion: Synthesis, Structure, and Bonding of [PdBr(PPh3)2]− Ligated by an N-Heterocyclic Phosphenium Cation
2009
Unsaturated N-heterocyclic phosphenium cations (uNHP) stabilize the [Pd0(PR3)2X]− anion proposed over the past decade to be the crucial but elusive intermediate in palladium-catalyzed cross-coupling reactions (X = halide). Insertion of metal into the P−Br bond of the precursor mesityl-substituted bromophosphine gives the structurally characterized Pd(0)-phosphenium complex (uNHPMes)Pd(PPh3)2Br, which features a long Pd−Br bond (2.7240(9) Å) and the shortest known Pd−P bond (2.1166(17) Å). The reaction is proposed to proceed by an associative pathway involving a Pd-bromophosphine complex that undergoes P-to-Pd bromide transfer. peerReviewed
Party autonomy regarding jurisdiction under the property regimes regulations
2021
The main accomplishment of the Property Regimes Regulations lies in their bringing more coherence into the cross-border family law adjudication. In the field of international jurisdiction, they strive to align the competence in couples? patrimony disputes to that in succession and in separation proceedings, or else to align the competence of the courts to the applicable law. These tendencies are clearly visible in the Regulations? provisions on choice of court agreements. Namely, the Regulations allow for such agreements, but severely limit parties? choice and the possible effects of these clauses. When succession or separation proceedings are pending, it is often only possible to institute…
Permutations of zero-sumsets in a finite vector space
2020
Abstract In this paper, we consider a finite-dimensional vector space 𝒫 {{\mathcal{P}}} over the Galois field GF ( p ) {\operatorname{GF}(p)} , with p being an odd prime, and the family ℬ k x {{\mathcal{B}}_{k}^{x}} of all k-sets of elements of 𝒫 {\mathcal{P}} summing up to a given element x. The main result of the paper is the characterization, for x = 0 {x=0} , of the permutations of 𝒫 {\mathcal{P}} inducing permutations of ℬ k 0 {{\mathcal{B}}_{k}^{0}} as the invertible linear mappings of the vector space 𝒫 {\mathcal{P}} if p does not divide k, and as the invertible affinities of the affine space 𝒫 {\mathcal{P}} if p divides k. The same question is answered also in the case where …