Search results for "Composite"

Enhanced Mechanical Properties in Organofluorosilica Thin Films

2008

Fluorinated hybrid organic-inorganic silicates (ORMOSIL) thin films display exceptional mechanical properties in terms of both hardness and elastic modulus that can be finely tuned by varying the angular velocity of the spin coating process. Hence, as traditional alkyl-modified silica xerogels generally show poor mechanical behavior, these materials offer a solution to a major limitation to applicability of ORMOSIL-based films.

<title>Irradiation effects in lead zirconate thin films</title>

2003

Lead zirconate PbZrO3 (PZ) and PbZr0.53Ti0.47O3 (PZT) sol-gel films with a thickness of up to 1.5 μm were deposited on TiO2/Pt/TiO2/SiO2/Si substrates by spin coating technique and heterostructures of the same composition as well as on Pb0.92La0.08 (Zr0.65Ti0.35)O3 (PLZT-8) (with a thickness of 0.4 μm) were pulse laser deposited (PLD) on Pt/Ti/SiO2/Si. Observation of a typical antiferroelectric (AFE) double hysteresis loop in obtained PZ heterostructures at room temperature was attributed to the superior dielectric strength in case of thin film materials. The thermal behavior of dielectric permittivity e of PZ film reveals a maximum near 225°C on heating and 219°C on cooling. The higher res…

Freestanding ferroelectric elastomer films

1998

Thermal and light induced polymorphism in iron(II) spin crossover compounds.

2004

The spin crossover complexes {Fe[H2B(pz)2]2L} ([H2B(pz)2]2 = dihydrobis(pyrazolyl)borate, L = 2,2'-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for 2 are different from that of the thermally induced high spin state and from those of 1. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es

Monte Carlo studies of polymer interdiffusion and spinodal decomposition: A review

1991

Abstract Putting a layer of polymer A on top of a layer of polymer B, the broadening of the interfacial profile is observed in the framework of a lattice model (‘bond fluctuation method’). The interdiffusion constant is studied as a function of chain length, vacancy concentration, and interaction energy between unlike monomers, and a comparison with pertinent theoretical predictions is made. A lattice model where polymers are represented as self-avoiding walks on a simple cubic lattice is used to model ‘spinodal decomposition’, i.e. phase separation by ‘uphill diffusion’ in the unstable part of the phase diagram of a polymer mixture. For chain lengths N ≤ 32, the linearized Cahn-like theory…

Crystal structure determination of a new LaPO4 phase in a multicomponent glass ceramic via 3D electron diffraction

2022

Abstract A glass ceramic from the MgO–Al2O3–SiO2 system containing additives of ZrO2, TiO2, La2O3 and P2O5 was investigated. Via x-ray powder diffraction (XRPD) and Transmission electron microscopy(TEM) the crystalline phases present could be identified as MgAl2O4 (Spinel), orthorhombic ZrTiO4 and a polymorph of LaPO4 with a previously unknown crystal structure. The crystal structure of this LaPO4 phase was solved ab initio via 3D ED Data. The polymorph occurs in a distorted barite structure type in the same space group (P21/n) as the stable monazite type polymorph, however the density is higher and the La has a higher coordination number. Furthermore the LaPO4 is present in a spinodal reli…

ChemInform Abstract: Genetic, Biological and Structural Hierarchies During Sponge Spicule Formation: from Soft Sol-Gels to Solid 3D Silica Composite …

2012

Ferroelectric liquid-crystalline elastomers

1994

Competitive Profiling of Ligandable Cysteines in Staphylococcus aureus with an Organogold Compound

2022

With the idea of exploiting metal-templated reactions to achieve selective modification of cysteines in proteins for antibacterial applications, an organometallic cyclometalated Au(III) compound was explored in a competitive chemoproteomic approach based on the isoDTB-ABPP (isotopically labelled desthiobiotin azide-activity-based protein profiling) technology in S. aureus cell extracts. In this way, more than 100 ligandable cysteines where identified, of which 10 were close to functional sites of proteins encoded by essential genes indicating potential for antibiotic development. Interestingly, more than 50% of the identified ligandable sites were not engaged by organic α-chloroacetamides i…

Towards Laser-Textured Antibacterial Surfaces

2018

AbstractEscherichia coli and Staphylococcus aureus bacterial retention on mirror-polished and ultrashort pulse laser-textured surfaces is quantified with a new approach based on ISO standards for measurement of antibacterial performance. It is shown that both wettability and surface morphology influence antibacterial behavior, with neither superhydrophobicity nor low surface roughness alone sufficient for reducing initial retention of either tested cell type. Surface structures comprising spikes, laser-induced periodic surface structures (LIPSS) and nano-pillars are produced with 1030 nm wavelength 350 fs laser pulses of energy 19.1 μJ, 1.01 μJ and 1.46 μJ, respectively. SEM analysis, optic…