Search results for "Composites"
showing 10 items of 1905 documents
Heat-Resistant Fully Bio-Based Nanocomposite Blends Based on Poly(lactic acid)
2013
Poly(lactic acid) (PLA) is melt mixed with polyamide 11 (PA11) to obtain a heat-resistant fully bio-based blend with PLA as the dominant component. The goal is achieved by adding small amounts of organoclay (OMMT), which is used to manipulate the blend microstructure. The selective positioning of the OMMT inside the PA11 and at the PLA/PA11 interface turns the blend morphology from drop/matrix into co-continuous at high PLA content (70 wt%). The OMMT-rich PA11 framework that interpenetrates the major PLA phase effectively contributes to bear stresses, and the nanocomposite blend keeps its structural integrity up to ≈160 °C, i.e., about 100 °C above the PLA glass transition.
Electrochemical formation of N,N′-diarylhydrazines by dehydrogenative N–N homocoupling reaction
2020
Hydrazines represent a class of compounds of high interest due to their applicability as versatile starting materials in many important transformations. Herein, we report a synthetic approach to hydrazine derivatives using commercially available anilines and an anodic dehydrogenative N-N coupling reaction as the key step.
Film-substrate lattice-engineering of HTS thin films
2008
Materials may show anisotropic properties on different crystal directions and this is also the case of High Temperature Superconductors (HTS). To take advantage of the materials anisotropy one concept of interest is 'orientation engineering' in thin films. This can be realized through the control of the film-substrate lattice relationship. Some examples in this regard are presented in this work and through comparative analysis we try to evaluate the viability of this approach and of he entcountered problems. It is expected that in the future this approach will generate new nano composite materials with new properties and effects leading to development of new devices with new or improved fun…
Holographic recording in amorphous As2S3 films at 633nm
2006
Abstract Holographic grating recording with focused (light intensity I = 14–124 W/cm 2 ) and unfocused ( I = 0.50–0.78 W/cm 2 ) 633 nm He–Ne laser sub-bandgap light in non-annealed and annealed a-As 2 S 3 films has been experimentally studied. The focused light recording is found to be much more efficient (diffraction efficiency up to 14.9%, specific recording energy down to 216 J/(cm 2 %)) than the unfocused light recording (0.11%, 72 400 J/(cm 2 %)). Some other properties are also different. The hologram lifetime of more than two years and positive refractive index changes take place in the case of focused recording versus two days and negative refractive index changes for unfocused r…
Folding induced supramolecular assembly into pH-responsive nanorods with a protein repellent shell
2018
We report the synthesis of ABA' triblock peptide-polysarcosine-peptide conjugates featuring two complementary phenylalanine-histidine pentapeptide strands A/A'. These sequences encode for antiparallel beta-sheet formation into folded conjugates, which promote the self-assembly into polysarcosine-shielded core-shell nanorods. These do not cause aggregation of serum proteins in human blood plasma underlining an enhanced stability.
Mechanical behavior of carbon/flax hybrid composites for structural applications
2012
In this work, the influence of an unidirectional carbon fabric layer on the mechanical performances of bidirectional flax fabric/epoxy composites used for structural applications was studied. Two different bidirectional flax fabrics were used to produce flax fabric reinforced plastic (FFRP) laminates by a vacuum bagging process: one is normally used to make curtains; the other, heavier and more expensive than the previous one, is usually used as reinforcement in composite structures. In order to realize hybrid structures starting from FFRP, an unidirectional UHM carbon fabric was used to replace a bidirectional flax fabric. Tensile and three-point bending tests were performed to evaluate t…
Nanoscopic hybrid systems with a polarity-controlled gate-like scaffolding for the colorimetric signalling of long-chain carboxylates
2007
Hybrid mesoporous systems containing a gate-like ensemble functionalised with imidazolium groups and a dye are used for the selective colorimetric sensing of long-chain carboxylates. Amoros del Toro, Pedro Jose, Pedro.Amoros@uv.es
Synthesis and characterization of a new layered organic-inorganic hybrid nickel(II) 1,4 : 5,8-naphthalenediimide bis-phosphonate, exhibiting canted a…
2008
A new Ni(II) layered hybrid organic-inorganic compound of formula Ni{sub 2}[(NDI-BP)(H{sub 2}O){sub 2}].2H{sub 2}O has been prepared in very mild conditions from N,N'-bis(2-phosphonoethyl)napthalene-1,4:5,8-tetracarboximide (NDI-BP ligand) and NiCl{sub 2}. The X-ray powder structure characterization of the title compound suggests a pillared layered organic-inorganic hybrid structure. The distance between the organic and inorganic layers has been found to be 17.8 A. The inorganic layers consist of corner sharing [NiO{sub 5}(H{sub 2}O)] octahedra and they are pillared by the diphosphonate groups. DC and AC magnetic measurements as a function of temperature and field indicate the presence of 2…
Mechanical characterization of bio-based composite/metal laminates for an application in street furniture
2019
In this work, it is proposed to study the influence of three manufacturing parameters in the development of bio-basedcomposite/steel hybrids. These parameters arethe methodof assembly between composite and metal, the distribution of composite and steellayers throughthe thicknessof the hybrid,and the stacking sequence of the composite part of the hybrid. The study was conducted through impact tests at different energies and quasi-static three-point bending tests. For each of these parameters, the influenceon the mechanical properties of the hybrid is evaluated.The results show that these properties depend essentially on the relative distribution of steel and composite through the thickness.