Search results for "Conductor"

Universal soliton pattern formations in passively mode-locked fiber lasers

2011

International audience; We investigate multiple-soliton pattern formations in a figure-of-eight passively mode-locked fiber laser. Operation in the anomalous dispersion regime with a double-clad fiber amplifier allows generation of up to several hundreds of solitons per round trip. We report the observation of remarkable soliton distributions: soliton gas, soliton liquid, soliton polycrystal, and soliton crystal, thus indicating the universality of such complexes.

Les matériaux pour capteurs chimiques

2002

National audience; A chemical sensor is composed of one part supplying chemical reco gnition coupled to one transducingsystem. At the recognition origin, interaction with the target chemical species is oftwo types, either electronicexchange, or ionic exchange. Two large classes of materials that can supply recognition proceed: metals andsemiconductors giving rise to electronic exchange and ionic conducting materials giving rise to ionic exchan-ge. This paper is structured in tw o large parts, emphasizing on materi als inducing specific interactions:semiconductor materials (metallic oxides and molecular semiconductors) and ionic conductor materials.In each part will be presented nature of ma…

High sensing potentialities of tetra-tert-butyl-metallophthalocyaninesbased acoustic microsensors for xylenes measurement in air at room temperature

2022

International audience; Xylenes, classified as Volatil Organic Compounds, is a very harmful pollutant for human health that can be absorbed into the body via all exposures routes: inhalation, ingestion, or dermal. As defined by the US Environmental Protection Agency, the occupational exposure limi-tes are set to 100 ppm while the guidelines in non-occupational context are fixed to 50 ppm. For the concentration measurements in the at-mosphere, authorities commonly used sampling methods with post-exposure chemical titration or chromatography. A strong interest remains on the development of low cost, low power consumption and easy implemented microsensors able to deliver real-time indicative m…

Time-dependent screening explains the ultrafast excitonic signal rise in 2D semiconductors

2020

We calculate the time evolution of the transient reflection signal in an MoS$_2$ monolayer on a SiO$_2$/Si substrate using first-principles out-of-equilibrium real-time methods. Our simulations provide a simple and intuitive physical picture for the delayed, yet ultrafast, evolution of the signal whose rise time depends on the excess energy of the pump laser: at laser energies above the A- and B-exciton, the pump pulse excites electrons and holes far away from the K valleys in the first Brillouin zone. Electron-phonon and hole-phonon scattering lead to a gradual relaxation of the carriers towards small $\textit{Active Excitonic Regions}$ around K, enhancing the dielectric screening. The acc…

Semiconductor-photocatalyzed sulfoxidation of alkanes.

2008

Preparation and characterisation of optical and optoelectronic devices based in two-dimensional semiconductors

2020

In the Materials Science field, two-dimensional materials have gained the scientific community attention in recent years. The change and the appearance of novel properties when their thickness is reduced to nanometric scale has special interest for its fundamental properties study for, from this base, the design and its implementation in devices. The wide variety of materials with the possibility of being exfoliated at the two-dimensional level opens the field to different applications, from optoelectronic devices, detection and sensing, energy storage, catalysis, medical applications and quantum information technologies, among others. This thesis gathers results in both directions: a funda…

Conductive and Capacitive Properties of the Bipolar Membrane Junction Studied by AC Impedance Spectroscopy

2001

The complete ac impedance spectrum of four bipolar membranes is analyzed both theoretically and experimentally taking into account both ionic transport and water dissociation together with the structural aspects of the bipolar junction. A theoretical model based on the Nernst-Planck and Poisson equations for the conductive and capacitive properties of the junction provides a qualitative description of the bipolar membranes for a broad range of electric currents and temperatures. Special attention is paid to the characteristics of the bipolar junction structure and the contact region between the two ion-exchange layers. It is observed that the effective area of this region increases with the…

Quantum wells within quantum dots, a CdS/HgS nanoheterostructure with global and local confinement

1998

Semiconductor nanocrystals prepared by methods of wet chemistry are similar to MBE grown quantum dots where the mobility of the charge carriers is reduced to zero dimensionality. In this paper we summarize the physics of a unique system in which the charge carriers are locally confined within a heterogeneous quantum dot. With high resolution electron microscopy we will show that epitaxial growth ot atomic layer precision is possible by methods of solution chemistry leading to CdS quantum dots with embedded HgS quantum wells (QDQWs). The photophysics of this system is investigated by time-correlated single photon counting, transient differential absorption and fluorescence line narrowing spe…

Co-adsorption processes, kinetics and quantum mechanical modelling of nanofilm semiconductor gas sensors

2010

A quantum mechanical model of co-adsorption on semiconductor surfaces is developed and successfully adopted towards exposure to several gases. It is related to nanofilms and thus allows the application of electric fields altering the electronic surface properties of adsorption centres (electro-adsorptive effect, EAE). The model is matched against experimental data with O 2 , NO 2 and CO measurements under the hypothesis of no direct interaction among the species. However the sequence of adsorption plays an important role where the adsorption of one gas species is opening up other sites that are filled by another sort of impinging molecules. Quantum mechanical modelling of co-adsorption: (a)…

Interligand Electron Transfer Determines Triplet Excited State Electron Injection in RuN3−Sensitized TiO2 Films

2004

Electron injection from the transition metal complex Ru(dcbpy)(2)(NCS)(2) (dcbpy = 2,2'-bipyridine-4,4'-dicarboxylate) into a titanium dioxide nanoparticle film occurs along two pathways. The dominating part of the electron injection proceeds from the initially excited singlet state of the sensitizer into the conduction band of the semiconductor on the sub-hundred-femtosecond time scale. The slower part of the injection occurs from the thermalized triplet excited state on the picosecond time scale in a nonexponential fashion, as was shown in a previous study (Benko, G.; et al. J. Am. Chem. Soc. 2002, 124, 489). Here we show that the slower channel of injection is the result of the excited s…