Search results for "Configuration"
showing 10 items of 601 documents
Exploring the Relationship between Information Technology Infrastructure Library and Process Management: Theory Development and Empirical Testing
2014
This paper investigates whether information technology (IT) departments that implement the IT Infrastructure Library (ITIL) processes also employ process management. This is a pertinent issue, as ITIL not only implies a time-limited program for redesigning vital IT processes according to best practices but a complete transformation to ITIL also implies that processes are managed on a daily basis. Without process management, ITIL will not be a success beyond its initial implementation. A survey of 444 Nordic ITIL experts was conducted to examine if there is a correlation between the implementation of ITIL processes and process management. The results are unambiguous and promising for sustain…
Regional Susceptibility in VCD Spectra to Dynamic Molecular Motions
2018
Experimental and theoretical studies of the vibrational circular dichroism (VCD) spectrum of 3-methyl-1-(methyldiphenlsilyl)-1-phenylbutan-1-ol, whose absolute configuration is key to elucidating the Brook rearrangement of tertiary benzylic α-hydroxylsilanes, are presented. It is found that the entire OH-bending region in this spectrum—a region that provides important marker bands—cannot be reproduced at all by standard theoretical approaches even though other regions are well described. Using a novel approach to disentangle contributions to the rotational strength of these bands, internal coordinates are identified that critically influence the appearance of this part of the spectrum. We s…
Kristall‐ und Molekülstruktur sowie absolute Konfiguration des (+)‐Benzylmethyl‐α‐naphthylphenylphosphonium‐bromids
1975
(+)-Benzylmethyl-α-naphthylphenylphosphonium-bromid kristallisiert in der Raumgruppe P212121 mit den Gitterkonstanten a = 22.12 A, b = 9.89 A,c = 9.49A und mit vier Molekulen in der Elementarzelle. Die Struktur wurde nach der Schweratommethode aufgeklart und bis zu einem R-Wert von 5.8% verfeinert. Unter Berucksichtigung der anomalen Dispersion konnte die absolute Konfiguration ermittelt werden, es liegt R-Konfiguration vor. Crystal- and Molecular Structure of (+)-Benzylmethyl-α-naphthylphenylphosphonium Bromide (+)-Benzylmethyl-α-naphthylphenylphosphonium bromide crystallizes in the space group P212121 with four molecules in the unit cell of dimensions a = 22.12 A, b = 9.89 A, c = 9.49 A. …
syn ‐[2.2](1,3)Cyclophane durch doppelte Photocyclodimerisierung
1988
Durch doppelte Cyclodimerisierung wird in einer Photolyse in Losung aus dem 1,3-disubstituierten Benzol 3 das syn[2.2](1,3)Cyclophan 4 erhalten. Eine kombinierte Belichtung Festkorper/Losung ergibt bei 5 das analoge System 6 mit Estergruppen. Beide Reaktionen erfolgen streng regiospezifisch durch Kopf-Kopf-Verknupfung und stereospezifisch bezuglich der syn-Geometrie im Cyclophan und der trans-Konfiguration der Vierringsubstituenten. Die einzige stereochemische Freiheit besteht in der Anordnung der Vierringe, wobei die Isomeren 4/6a,b,c, den drei moglichen Rotameren in 3 und 5 entsprechen. Wahrend das Gerust von 4 starr ist, zeigt 6 bei Raumtemp. eine langsame Inversion des zentralen 10-Ring…
The Role of C–H···H–B Interactions in Establishing Rotamer Configurations in Metallabis(dicarbollide) Systems
2010
The aim of this work is to explore the self-interaction capability of the anion [3,3′-Co(1,2-C2B9H11)2]– through Ccluster–H···H–B (Cc–H···H–B) dihydrogen bonds. A set of theoretical and empirical data aiming to establish the main rules that account for the binding mode between the negatively charged borane framework made by [3,3′-Co(1,2-C2B9H11)2]– and the [NMe4]+ ions have been compiled. The interaction between cation and anion is mainly electrostatic but the covalent contribution is also proven and quantified. The existing intermolecular H···H short contacts have been studied and are compared with available data from the Cambridge Structural Database. The results show that the electronic …
Reconfigurable electrical interconnection strategies for photovoltaic arrays: A review
2014
Non-uniform irradiance significantly decreases the power delivered by solar photovoltaic arrays. A promising technique for compensating these power losses relies on dynamically reconfiguring the electrical connections between photovoltaic modules. This paper presents the current state-of-the-art strategies for photovoltaic array reconfiguration in order to increase the power output under partial shading and mismatch conditions. The different approaches have been compared in terms of effectiveness of the control algorithms, monitored electrical and environmental variables, overall hardware complexity and specific features of each solution. Finally, the most challenging aspects of the reconfi…
Distributed estimation and control of water distribution networks by logical consensus
2014
In this study we present a methodology for backflow detec- tion through the interpretation of results from a network of Automatic Meter Reading. The approach is based on the so– called logical consensus theory and consists of a distributed failure detection and system reconfiguration. The effective- ness of the proposed method is showed through simulation within a prototypical water distribution network.
Secoiridoids and Iridoids from Morinda asteroscepa
2020
The new 2,3-secoiridoids morisecoiridoic acids A (1) and B (2), the new iridoid 8-acetoxyepishanzilactone (3), and four additional known iridoids (4–7) were isolated from the leaf and stem bark methanol extracts of Morinda asteroscepa using chromatographic methods. The structure of shanzilactone (4) was revised. The purified metabolites were identified using NMR spectroscopic and mass spectrometric techniques, with the absolute configuration of 1 having been established by single-crystal X-ray diffraction analysis. The crude leaf extract (10 μg/mL) and compounds 1–3 and 5 (10 μM) showed mild antiplasmodial activities against the chloroquine-sensitive malaria parasite Plasmodium falciparum (…
Establishing a Reference Baseline for Midday Stem Water Potential in Olive and Its Use for Plant-Based Irrigation Management
2021
12 páginas.- 7 figuras.- 4 tablas.- 55 referencias.-