Search results for "Confined"
showing 10 items of 65 documents
Stress-Strain Law for Confined Concrete with Hardening or Softening Behavior
2013
This paper provides a new general stress-strain law for concrete confined by steel, fiber reinforced polymer (FRP), or fiber reinforced cementitious matrix (FRCM), obtained by a suitable modification of the well-known Sargin’s curve for steel confined concrete. The proposed law is able to reproduce stress-strain curve of any shape, having both hardening or softening behavior, by using a single closed-form simple algebraic expression with constant coefficients. The coefficients are defined on the basis of the stress and the tangent modulus of the confined concrete in three characteristic points of the curve, thus being related to physical meaningful parameters. It will be shown that if the v…
Bacteria and free-living amoeba in the Lascaux Cave.
2008
3 pages, 1 table, 18 references. The collaboration of the Lascaux restoration team is highly appreciated. We thank Marisa Chelius for valuable comments on the manuscript.
Angle Factors and Projected Area Factors for Comfort Analysis of Subjects in Complex Confined Enclosures: Analytical Relations and Experimental Resul…
2008
This paper addresses an important problem in the evaluation of the thermal comfort of people living or working in the sort of confined spaces typical of current architecture. In the details, a new algorithm is proposed for the evaluation of the angle factors of people within rooms characterized by complex shapes, where the envelope components are not always mutually orthogonal. The algorithm is based on field data obtained by means of an experimental photographic apparatus which allows measurements of projected area factors of seated or standing people in such complex confined environments.
Fine-tuning of the confined space in microporous metal–organic frameworks for efficient mercury removal
2017
Offsetting the impact of human activities on the biogeochemical cycle of mercury has become necessary for a sustainable planet. Herein, we report the development of a water-stable and eco-friendly metal–organic framework, which has the formula {Cu4II[(S,S)-methox]2}·5H2O (1), where methox is bis[(S)-methionine]oxalyl diamide. Its features include narrow functional channels decorated with thioalkyl chains, which are able to capture HgCl2 from aqueous media in an efficient, selective, and rapid manner. The conscious design effort in terms of size, shape, and reactivity of the channels results in extremely efficient immobilization of HgCl2 guest species in a very stable conformation, similar t…
Hysteresis in the temperature dependence of the IR bending vibration of deeply cooled confined water.
2019
Using Fourier Transform Infrared (FTIR) spectroscopy, we investigate the temperature dependence of the bending vibrations of water confined in the pores of a silica hydrogel in the temperature interval of 270-180 K. We also investigate the presence of thermal hysteresis by cooling and reheating temperature scans. The results clearly show the presence, at about 230 K, of a crossover in the temperature dependence of the IR spectra; moreover, the presence of hysteresis is clearly demonstrated. By comparing FTIR data with neutron diffraction data and previous calorimetric data on the same samples, we conclude that the crossover and the hysteretical behavior do not involve a water glass transiti…
Metal-Organic Frameworks as Chemical Nanoreactors: Synthesis and Stabilization of Catalytically Active Metal Species in Confined Spaces
2020
ConspectusSince the advent of the first metal-organic frameworks (MOFs), we have witnessed an explosion of captivating architectures with exciting physicochemical properties and applications in a wide range of fields. This, in part, can be understood under the light of their rich host-guest chemistry and the possibility to use single-crystal X-ray diffraction (SC-XRD) as a basic characterization tool. Moreover, chemistry on preformed MOFs, applying recent developments in template-directed synthesis and postsynthetic methodologies (PSMs), has shown to be a powerful synthetic tool to (i) tailor MOFs channels of known topology via single-crystal to single-crystal (SC-SC) processes, (ii) impart…
Structure and dynamics of water confined in silica hydrogels: X-ray scattering and dielectric spectroscopy studies.
2003
We have used a sol-gel technique to obtain optically transparent hydrogels in which water is confined within a 3D silica matrix. In this work we report X-ray scattering and dielectric spectroscopy measurements on samples having different aging times and compare them with previously obtained results with near-infrared (NIR) absorption spectroscopy. X-ray scattering at room temperature enables to characterize the structure and size of the matrix pores and the non-uniform distribution of water inside the hydrogel. Broad band dielectric spectroscopy in the temperature range 130-280 K enables to study water dynamics. In aged hydrogels two relaxations are clearly evident and show characteristic t…
Synthesis of yttrium aluminum garnet nanoparticles in confined environment III: Cerium doping effect
2018
Abstract Cerium yttrium aluminum garnet (Ce:YAG, CexY3-xAl5O12) nanoparticles doped with different cerium amount were obtained by calcining the precursors synthesized via co-precipitation in w/o microemulsion for 1 h at 900 °C. The structural and morphological properties were investigated by using X-ray Diffraction (XRD), Infrared Spectroscopy (IR) and Transmission Electron Microscopy (TEM) coupled with Energy Dispersive X-ray Spectroscopy (EDS) in order to investigate the effect of doping level on formation and microstructure of obtained nanoparticles. It was found that the composition of the final products strongly depends on the concentration of cerium. The formation of single YAG phase …
Behavior of fiber-reinforced concrete columns under axially and eccentrically compressive loads
2010
An experimental investigation into the behavior of 16 short, confined, reinforced concrete columns with and without steel fibers was carried out. The columns with square sections had a concrete core 165 x 165 mm (6.49 x 6.49 in.) at the midsection and were hunched at the ends to apply eccentric loading and prevent boundary effects. The specimens were tested to failure at different strain rates under two loading schemes: concentric compression and eccentric compression with a constant eccentricity. The axial load and axial strains were obtained to evaluate the effects of the presence of steel fibers, the thickness of the cover concrete, and the eccentricity of the applied axial load. The com…
A strategy for the finite element modeling of FRP-confined concrete columns subjected to preload
2018
Abstract Compressive behavior of columns strengthened by means of an outer elastic confinement provided e.g. by fiber-reinforced polymer (FRP) jackets has become a main topic in the field of structural retrofitting. In details, the problem of the response assessment of strengthened columns is still under study. Many analytical formulations have been proposed to describe the compressive behavior of confined concrete under both monotonic and cyclic loads. However, the effect of a stress/strain level in the columns already present prior to apply the confinement has been generally neglected until now, also because of the lack of well defined strategies of modeling. In this frame, here, (1) a FE…