Search results for "Coupling"
showing 10 items of 1862 documents
Determination of the g-Factor of Single Hydrogen-Like Ions by Mode Coupling in a Penning Trap
2004
A method has been developed and applied for the determination of the electronic g-factor of single hydrogen-like ions stored in a Penning trap. The method is based on mode coupling of the ion trapping motions and is conceptionally advantageous as compared to previously used methods. It has been applied to hydrogen-like oxygen 16O7+ and yields a value for the gJ-factor which is in agreement with previously determined values. Experimental requirements and possibilities of the new method are discussed.
Get into flow: Design of experiments as a key technique in the optimization of anodic dehydrogenative C,C cross-coupling reaction of phenols in flow …
2021
Abstract The optimization of electro-organic reactions poses a challenge due to the various parameters involved. Quite often those parameters are not independent from each other, leading the experimental scientist using linear approaches into an optimization loophole. We report a strategy for the optimization of the anodic oxidative dehydrogenative C,C cross-coupling reactions for the synthesis of biphenols based on Design of Experiments (DoE), which overcomes the drawbacks of linear optimization approaches. Using a fractional design, we increased the yield of a long-time investigated example reaction from 44% up to 85% and point out different suitable reaction conditions through to linear …
High Electromechanical Coupling in Relaxor Pb(Sc<sub>1/2</sub>Nb<sub>1/2</sub>) O<sub>3</sub> - PbTiO<sub>3…
1997
On-Surfaces Synthesis on Insulating Substrates
2016
On-surface synthesis has attracted great attention in recent years due to its promising potential for creating functional structures on surfaces. An important aspect of on-surface synthesis is the capability to arrive at covalently linked thermally stable structures that offer the possibility for application even in harsh environments outside ultra-high vacuum conditions. Additionally, covalent linking allows for fabricating conjugated structures with superior electron transport properties. Especially, the latter is of tremendous interest when considering future applications in the field of molecular electronics. Having molecular electronics applications in mind explains the need for decoup…
Strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye
2011
We demonstrate a strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye molecules. Dispersion curves for surface plasmon polaritons on samples with a thin layer of silver covered with Sulforhodamine 101 molecules embedded in SU-8 polymer are obtained experimentally by reflectometry measurements and compared to the dispersion of samples without molecules. Clear Rabi splittings, with energies up to 360 and 190 meV, are observed at the positions of the dye absorption maxima. The split energies are dependent on the number of Sulforhodamine 101 molecules involved in the coupling process. Transfer matrix and coupled oscillator methods are used to model the studied multilaye…
On the Use of L-shaped Granular Chains for the Assessment of Thermal Stress in Slender Structures
2014
Slender beams subjected to compressive load are common in civil engineering. The rapid in-situ measurement of this stress may help preventing structural anomalies. In this article, we describe the coupling mechanism between highly nonlinear solitary waves (HNSWs) propagating along an L- shaped granular system and a beam in contact with the gran- ular medium. We evaluate the use of these waves to measure stress in thermally loaded structures and to estimate the neutral temperature, i.e. the temperature at which the stress is null. We investigate numerically and experimentally one and two L- shaped chains of spherical particles in contact with a prismatic beam subjected to heat. We find that …
Improved All-Fiber Acousto-Optic Tunable Bandpass Filter
2017
An all-fiber acousto-optic tunable bandpass filter based on a 1.185-mm long coreless core mode blocker is reported. Experimental results demonstrate a minimal insertion loss of 1.2 dB at the optical resonant wavelength of 1527.7 nm with 3-dB optical bandwidth of 0.83 nm. The optimization of the device takes into account the attenuation of the acoustic wave and leads to an asymmetric configuration in which the coupling section is shorter than the recoupling part. Under the effect of a standing flexural wave the device can be operated as a bandpass modulator. The device exhibits a maximum modulation depth of 28%, 4 dB of insertion loss and 0.97 nm of optical bandwidth at 4.774 MHz.
Exciton-Phonon Coupling in the Ultraviolet Absorption and Emission Spectra of Bulk Hexagonal Boron Nitride
2018
We present an \textit{ab initio} method to calculate phonon-assisted absorption and emission spectra in the presence of strong excitonic effects. We apply the method to bulk hexagonal BN which has an indirect band gap and is known for its strong luminescence in the UV range. We first analyse the excitons at the wave vector $\overline{q}$ of the indirect gap. The coupling of these excitons with the various phonon modes at $\overline{q}$ is expressed in terms of a product of the mean square displacement of the atoms and the second derivative of the optical response function with respect to atomic displacement along the phonon eigenvectors. The derivatives are calculated numerically with a fin…
Tunable phonon-cavity coupling in graphene membranes
2016
A major achievement of the past decade has been the realization of macroscopic quantum systems by exploiting the interactions between optical cavities and mechanical resonators. In these systems, phonons are coherently annihilated or created in exchange for photons. Similar phenomena have recently been observed through phonon-cavity coupling - energy exchange between the modes of a single system mediated by intrinsic material nonlinearity. This has so far been demonstrated primarily for bulk crystalline, high-quality-factor (Q > 105) mechanical systems operated at cryogenic temperatures. Here, we propose graphene as an ideal candidate for the study of such nonlinear mechanics. The large …