Search results for "Cyclic compound"

showing 10 items of 819 documents

DHFR Inhibitors: Reading the Past for Discovering Novel Anticancer Agents.

2019

Dihydrofolate reductase inhibitors are an important class of drugs, as evidenced by their use as antibacterial, antimalarial, antifungal, and anticancer agents. Progress in understanding the biochemical basis of mechanisms responsible for enzyme selectivity and antiproliferative effects has renewed the interest in antifolates for cancer chemotherapy and prompted the medicinal chemistry community to develop novel and selective human DHFR inhibitors, thus leading to a new generation of DHFR inhibitors. This work summarizes the mechanism of action, chemical, and anticancer profile of the DHFR inhibitors discovered in the last six years. New strategies in DHFR drug discovery are also provided, …

AntifungalCancer chemotherapymedicine.drug_classDrug Evaluation Preclinicaldihydrofolate reductase (DHFR) enzymePharmaceutical ScienceAntineoplastic AgentsComputational biologyReview01 natural scienceshybrid compoundsAnalytical Chemistrylcsh:QD241-44103 medical and health sciencesStructure-Activity RelationshipFolic Acidlcsh:Organic chemistryheterocyclic compoundsNeoplasmsDihydrofolate reductaseparasitic diseasesDrug DiscoverymedicineAnimalsHumansPhysical and Theoretical Chemistry030304 developmental biology0303 health sciencesHeterocyclic compoundbiology010405 organic chemistryDrug discoveryOrganic ChemistryDHFR inhibitors as anticancer agentSettore CHIM/08 - Chimica Farmaceutica0104 chemical sciencesDHFR drug discoveryTetrahydrofolate DehydrogenaseMechanism of actionChemistry (miscellaneous)Settore CHIM/03 - Chimica Generale E InorganicaDHFR inhibitors as anticancer agentsbiology.proteinMolecular MedicineFolic Acid Antagonistsmedicine.symptomMolecules (Basel, Switzerland)
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In Vitro Phytotoxicity and Antioxidant Activity of Selected Flavonoids

2012

Made available in DSpace on 2013-09-27T14:54:27Z (GMT). No. of bitstreams: 1 WOS000306186200008.pdf: 228949 bytes, checksum: 818c9c7c18b61f5827cc5873d4eed670 (MD5) Previous issue date: 2012-05-01 Made available in DSpace on 2013-09-30T18:36:37Z (GMT). No. of bitstreams: 1 WOS000306186200008.pdf: 228949 bytes, checksum: 818c9c7c18b61f5827cc5873d4eed670 (MD5) Previous issue date: 2012-05-01 Submitted by Vitor Silverio Rodrigues (vitorsrodrigues@reitoria.unesp.br) on 2014-05-20T13:48:50Z No. of bitstreams: 1 WOS000306186200008.pdf: 228949 bytes, checksum: 818c9c7c18b61f5827cc5873d4eed670 (MD5) Made available in DSpace on 2014-05-20T13:48:50Z (GMT). No. of bitstreams: 1 WOS000306186200008.pdf: …

AntioxidantDPPHmedicine.medical_treatmentantioxidant activityMorinflavonoids; germination; radical elongation; antioxidant activity; structure/activityBiologyArticlestructure/activityAntioxidantsLepidium sativumCatalysisRaphanusInorganic Chemistrychemistry.chemical_compoundPicratesBotanymedicineheterocyclic compoundsFood sciencePhysical and Theoretical ChemistryMolecular BiologySpectroscopyFlavonoidsBiphenyl CompoundsfungiOrganic Chemistryfood and beveragesBiological activityCatechinGeneral MedicineComputer Science Applicationsradical elongationBiphenyl compoundgerminationchemistryflavonoidsQuercetinLuteolinInternational Journal of Molecular Sciences
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Citrus flavonoids: Molecular structure, biological activity and nutritional properties: A review

2007

Abstract Epidemiological studies have shown an inverse relationship between dietary flavonoid intakes and cardiovascular diseases. Citrus fruits are the main winter fruits consumed in the Mediterranean diet, so they are the main source of dietary flavonoids. The possible beneficial effects are due, not only to the high amounts of vitamins and minerals, but also to the antioxidant properties of their flavonoids. Dietary flavonoids may help to supplement the body antioxidant defences against free radicals. These compounds’ possible beneficial effects are due to their antioxidant activity, which is related to the development of atherosclerosis and cancer, and to anti-inflammatory and antimicro…

AntioxidantMediterranean dietmedicine.medical_treatmentFlavonoidBiologyAnalytical Chemistrymedicineheterocyclic compoundsFood scienceBeneficial effectsCancerchemistry.chemical_classificationfungifood and beveragesBiological activityGeneral MedicineAntimicrobialcarbohydrates (lipids)BiochemistrychemistryPolyphenolAtherosclerosiFlavonoidAntioxidantCitrus fruitFood ScienceCitrus fruitFood Chemistry
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Stability and bioaccessibility of EGCG within edible micro-hydrogels. Chitosan vs. gelatin, a comparative study

2016

Micro-hydrogels are very promising systems for the protection and controlled delivery of sensitive bioactives, but limited knowledge exists regarding the impact of this encapsulation on their bioaccessibility. In this work, two different hydrogel-forming biopolymers (gelatin and chitosan) were compared as wall materials for the microencapsulation of a model flavonoid, (−)-epigallocatechin gallate (EGCG). Results showed that gelatin was more adequate as wall material for the encapsulation of EGCG than chitosan, achieving higher encapsulation efficiencies (95% ± 6%), being more effective in delaying EGCG release and degradation in aqueous solution and exhibiting a 7 times higher bioaccessibil…

Antioxidantfood.ingredientGeneral Chemical Engineeringmedicine.medical_treatmentFlavonoidBioaccessibility02 engineering and technologycomplex mixturesGelatinChitosanchemistry.chemical_compound0404 agricultural biotechnologyfoodmedicineOrganic chemistryheterocyclic compoundsFood scienceMicroencapsulationFlavonoidschemistry.chemical_classificationChitosanAqueous solutionChemistrytechnology industry and agriculturefood and beverages04 agricultural and veterinary sciencesGeneral Chemistry021001 nanoscience & nanotechnology040401 food scienceBioactive compoundBioavailabilitySelf-healing hydrogelsGelatin0210 nano-technologyEGCGFood ScienceFood Hydrocolloids
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Anti-inflammatory activity of erycristagallin, a pterocarpene from Erythrina mildbraedii.

2003

Erycristagallin, a pterocarpene isolated from Erythrina mildbraedii, was tested in vitro for its antioxidant properties on the stable 2,2-diphenyl-1-pycryl-hydrazyl (DPPH) free radical and on the arachidonic acid metabolism. In addition, erycristagallin was tested on different experimental models of inflammation, such as the acute and chronic inflammation induced by the application of 12-O-tetradecanoylphorbol 13-acetate (TPA) on mice and the phospholipase A(2)-induced mouse paw oedema test. In the carrageenan-induced mouse paw oedema test, the ethyl acetate extract obtained from E. mildbraedii showed anti-inflammatory activity, and erycristagallin was isolated as the active principle. In v…

Antioxidantmedicine.drug_classDPPHmedicine.medical_treatmentAnti-Inflammatory AgentsInflammationPharmacologyCarrageenanHeterocyclic Compounds 4 or More RingsLeukotriene B4Anti-inflammatoryAntioxidantsPhospholipases Achemistry.chemical_compoundMicePicratesIn vivomedicineAnimalsEdemaRats WistarErythrinaPharmacologyPhospholipase AArachidonic AcidPlant ExtractsBiphenyl CompoundsEarFree Radical ScavengersIsoflavonesIn vitroHindlimbRatsBiphenyl compoundchemistryBiochemistryFemalemedicine.symptomEuropean journal of pharmacology
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Synthesis and antiproliferative activity of a natural like glucosyl polycyclic compound

2014

A new polycylic compound was synthesized and evaluated for its antiproliferative activity against the NCI panel of human tumoral cell lines showing IC50 values in the range 0.47-5.43 µM. The compound induced a decrease of the level of cyclin B1, whereas increased the level of the inhibitor p21 WAF1

Antiproliferative activity polycyclic compoundSettore BIO/10 - BiochimicaSettore CHIM/08 - Chimica Farmaceutica
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A Trisialoganglioside Containing a Sialyl α2-6 N-Acetylgalactosamine Residue Is a Cholinergic-Specific Antigen, Chol-1α1

1992

Cholinergic-specific antigens termed the Chol-1 family have been suggested to be of a ganglioside nature by Richardson et al. (J. Neurochem. 38, 1605-1614, 1982). Two molecular species of polysialogangliosides among bovine brain gangliosides were found to react with anti-Chol-1 alpha antiserum. One of them, Chol-1 alpha-a, was isolated and characterized as a trisialoganglioside containing the gangliotetraose backbone in which 1 mol of sialic acid was attached to each of the reducing end galactose, N-acetylgalactosamine and internal galactose residues, respectively. The chemical structure of Chol-1 alpha-a was determined for the first time, being as follows: IV3NeuAc III6NeuAc II3NeuAc-GgOse…

AntiserumGangliosidetechnology industry and agricultureGeneral MedicineBiologyBiochemistryN-AcetylgalactosamineSialic acidchemistry.chemical_compoundResidue (chemistry)chemistryAntigenBiochemistryGalactosepolycyclic compoundsCholinergiclipids (amino acids peptides and proteins)Molecular BiologyThe Journal of Biochemistry
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Pyrrolo[2,1-d][1,2,3,5]tetrazinones deaza analogues of temozolomide with potent antitumor activity

2000

The title compounds, that hold the deaza skeleton of temozolomide, exhibited potent in vitro antiproliferative activity. An evaluation of such a biological activity indicates that the mode of action of these compounds differs from that of temozolomide and is also mechanistically unrelated to that of any known antitumor drug.

Antitumor activityDrugTemozolomideChemistryStereochemistrymedia_common.quotation_subjectPharmaceutical ScienceBiological activityPharmacologyHeterocyclic Compounds 2-RingIn vitroD-1DacarbazineDrug DiscoveryTemozolomidemedicineAntineoplastic Agents Alkylatingmedicine.drugmedia_commonIl Farmaco
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Vascular effects of diet supplementation with plant sterols.

2008

Objectives The purpose of this study was to evaluate vascular effects of diet supplementation with plant sterol esters (PSE). Background Plant sterol esters are used as food supplements to reduce cholesterol levels. Their effects on endothelial function, stroke, or atherogenesis are not known. Methods In mice, plasma sterol concentrations were correlated with endothelial function, cerebral lesion size, and atherosclerosis. Plasma and tissue sterol concentrations were measured by gas-liquid chromatography-mass spectrometry in 82 consecutive patients with aortic stenosis. Results Compared with those fed with normal chow (NC), wild-type mice fed with NC supplemented with 2% PSE showed increase…

Apolipoprotein EAortic valveMalemedicine.medical_specialtyDiet therapyArteriosclerosisCardiovascular SystemBrain Ischemiachemistry.chemical_compoundMiceEzetimibeRisk FactorsInternal medicinepolycyclic compoundsmedicineAnimalsHumansEndotheliumAgedCholesterolbusiness.industryPhytosterolsSterolMice Inbred C57BLEndocrinologymedicine.anatomical_structurechemistryCirculatory systemDietary Supplementslipids (amino acids peptides and proteins)FemalePlant PreparationsCardiology and Cardiovascular MedicinebusinessBlood vesselmedicine.drugJournal of the American College of Cardiology
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Haptoglobin interacts with apolipoprotein E and beta-amyloid and influences their crosstalk.

2014

Beta-amyloid accumulation in brain is a driving force for Alzheimer's disease pathogenesis. Apolipoprotein E (ApoE) represents a critical player in beta-amyloid homeostasis, but its role in disease progression is controversial. We previously reported that the acute-phase protein haptoglobin binds ApoE and impairs its function in cholesterol homeostasis. The major aims of this study were to characterize the binding of haptoglobin to beta-amyloid, and to evaluate whether haptoglobin affects ApoE binding to beta-amyloid. Haptoglobin is here reported to form a complex with beta-amyloid as shown by immunoblotting experiments with purified proteins, or by its immunoprecipitation in brain tissues …

Apolipoprotein EMalePhysiologyDiseaseBeta-amyloidBiochemistryAmyloid beta-Protein PrecursorAlzheimer' diseasepolycyclic compoundsskin and connective tissue diseasesapolipoprotein EbiologyChemistryMedicine (all)Haptoglobinfood and beveragesBrainApoE/A? complexGeneral MedicineMiddle AgedhaptoglobinCrosstalk (biology)ApoE/Aβ complexSettore MED/26 - Neurologialipids (amino acids peptides and proteins)FemaleAlzheimer's diseaseProtein BindingAdultmedicine.medical_specialtyImmunoprecipitationCognitive NeuroscienceEnzyme-Linked Immunosorbent AssayCHO CellsTransfectionAlzheimer' disease; ApoE/Aβ complex; Apolipoprotein E; Beta-amyloid; Haptoglobin; Human brain tissue; Adult; Aged; Alzheimer Disease; Amyloid beta-Peptides; Amyloid beta-Protein Precursor; Analysis of Variance; Animals; Apolipoproteins E; Brain; CHO Cells; Cricetulus; Enzyme-Linked Immunosorbent Assay; Female; Haptoglobins; Humans; Immunoprecipitation; Male; Middle Aged; Mutation; Protein Binding; Transfection; Biochemistry; Cell Biology; Physiology; Cognitive Neuroscience; Medicine (all)NOApolipoproteins ECricetulusAlzheimer DiseaseInternal medicinemental disordersmedicineAnimalsHumansImmunoprecipitationAgedAnalysis of VarianceAmyloid beta-PeptidesHaptoglobinsNeurotoxicityAlzheimer’diseaseCell Biologymedicine.diseasehuman brain tissueEndocrinologyMutationbiology.proteinAlzheimer'diseaseHomeostasisACS chemical neuroscience
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