Search results for "DECOMPOSITION"

Multidomain boundary integral formulation for piezoelectric materials fracture mechanics

2001

Abstract A boundary element method and its numerical implementation for the analysis of piezoelectric materials are presented with the aim to exploit their features in linear electroelastic fracture mechanics. The problem is formulated employing generalized displacements, that is displacements and electric potential, and generalized tractions, that is tractions and electric displacement. The generalized displacements boundary integral equation is obtained by using the closed form of the piezoelasticity fundamental solutions. These are derived through a displacement based modified Lekhnitskii’s functions approach. The multidomain boundary element technique is implemented to achieve the numer…

Numerical Algorithms Based on Characteristic Domain Decomposition for Obstacle Problems

1997

A new numerical solution algorithm for obstacle problems is proposed, where the characteristic domain decomposition into active and inactive subdomains separated by the free boundary is approximated by a Schwarz method. Such an approach gives an opportunity to apply fast linear system solvers to genuinely non-linear obstacle problems. Other solution algorithms, like projected relaxation methods and active set strategies, are compared to the new solution algorithm. Numerical experiments related to the elastoplastic torsion problem are included showing the efficiency of the new approach.

Science Advances

2019

River ecosystems receive and process vast quantities of terrestrial organic carbon, the fate of which depends strongly on microbial activity. Variation in and controls of processing rates, however, are poorly characterized at the global scale. In response, we used a peer-sourced research network and a highly standardized carbon processing assay to conduct a global-scale field experiment in greater than 1000 river and riparian sites. We found that Earth’s biomes have distinct carbon processing signatures. Slow processing is evident across latitudes, whereas rapid rates are restricted to lower latitudes. Both the mean rate and variability decline with latitude, suggesting temperature constrai…

Influence of Phase Modifiers on the Degradation of Tri-n-octylamine/dodecane Extracting Mixture by an Acidic Solution of Vanadium (V)

2012

The kinetics of degradation of a mixture of tri-n-octylamine (extractant) and various alcoholic phase modifiers in n-dodecane in contact with acidic aqueous sulfate solutions containing vanadium (V) has been investigated. The nature of the modifier influences the kinetics of degradation and an improvement of the resistance against the chemical degradation is obtained when secondary alcohol (2-nonanol) or tertiary alcohols such as 9-octyl-9-heptadecanol are used as phase modifiers instead of 1-tridecanol. For instance, the kinetic constant of degradation is divided by one half when 9-octyl-9-heptadecanol is used as phase modifier instead of 1-tridecanol. On the contrary, the alcohols contain…

A new approach to the growth of ZnO by vapour transport

2005

The crystal growth of ZnO by vapour transport is classically made in presence of additional species which enhance the growth process. Usually, additional species have been considered as chemical transport agents that promote a typical CVT (Chemical Vapour Transport) process. Recently, we have proposed a new interpretation of the chemical role of some of these species. This new interpretation considers that, in some cases, the additional species promote a partial consumption of the O2 provided by the ZnO decomposition and, consequently, a Zn excess is generated. This excess of Zn pressure activates the ZnO decomposition and the growth rate is enhanced. Among those species, carbon shows an ad…

Comparative study of three satellite image time-series decomposition methods for vegetation change detection

2018

International audience; Satellite image time-series (SITS) methods have contributed notably to detection of global change over the last decades, for instance by tracking vegetation changes. Compared with multi-temporal change detection methods, temporally highly resolved SITS methods provide more information in a single analysis, for instance on the type and consistency of change. In particular, SITS decomposition methods show a great potential in extracting various components from non-stationary time series, which allows for an improved interpretation of the temporal variability. Even though many case studies have applied SITS decomposition methods, a systematic comparison of common algori…

2016

Abstract. We found that ambient and laboratory-generated secondary organic aerosols (SOA) form substantial amounts of OH radicals upon interaction with liquid water, which can be explained by the decomposition of organic hydroperoxides. The molar OH yield from SOA formed by ozonolysis of terpenes (α-pinene, β-pinene, limonene) is  ∼  0.1 % upon extraction with pure water and increases to  ∼  1.5 % in the presence of Fe2+ ions due to Fenton-like reactions. Upon extraction of SOA samples from OH photooxidation of isoprene, we also detected OH yields of around  ∼  0.1 %, which increases upon addition of Fe2+. Our findings imply that the chemical reactivity and aging of SOA particles is strongl…

Sea-surface temperature co-variability in the Southern Atlantic and Indian Oceans and its connections with the atmospheric circulation in the Souther…

2003

The relationship between sea-surface temperature (SST) inter-annual variability at the subtropical and midlatitudes of the southern Atlantic and Indian Oceans and its links with the atmospheric circulation in the Southern Hemisphere are investigated over the 1950–1999 period. Exploratory analysis using singular value decomposition and further investigations based on simple indices show that a large part of regional SST variability is common between the southwestern parts of both basins at subtropical and midlatitudes during the austral summer. Interestingly, these areas are also significantly associated with the far southwestern Pacific (Tasman Sea area). The patterns and time series of co-…

Investigation by raman spectroscopy of the decomposition process of HKUST-1 upon exposure to air

2016

We report an experimental investigation by Raman spectroscopy of the decomposition process of Metal-Organic Framework (MOF) HKUST-1 upon exposure to air moisture (T=300 K, 70% relative humidity). The data collected here are compared with the indications obtained from a model of the process of decomposition of this material proposed in literature. In agreement with that model, the reported Raman measurements indicate that for exposure times longer than 20 days relevant irreversible processes take place, which are related to the occurrence of the hydrolysis of Cu-O bonds. These processes induce small but detectable variations of the peak positions and intensities of the main Raman bands of th…

The CCSD(T) model with Cholesky decomposition of orbital energy denominators

2010

A new implementation of the coupled cluster singles and doubles with approximate triples correction method [CCSD(T)] using Cholesky decomposition of the orbital energy denominators is described. The new algorithm reduces the scaling of CCSD(T) from N-7 to N-6, where N is the number of orbitals. The Cholesky decomposition is carried out using simple analytical expressions that allow us to evaluate a priori the order in which the decomposition should be carried out and to obtain the relevant parts of the vectors whenever needed in the calculation. Several benchmarks have been carried out comparing the performance of the conventional and Cholesky CCSD(T) implementations. The Cholesky implement…