Search results for "Deposit"
showing 10 items of 1447 documents
ChemInform Abstract: Hybrid Organic-Inorganic Light-Emitting Diodes
2011
The demonstration of colour tunability and high efficiency has brought organic light-emitting diodes (OLEDs) into the displays and lighting market. However, high production costs due to expensive deposition techniques and the use of reactive materials still limit their market entry, highlighting the need for novel concepts. This has driven the research towards the integration of both organic and inorganic materials into devices that benefit from their respective peculiar properties. The most representative example of this tendency is the application of metal oxides in organic optoelectronics. Metal oxides combine properties such as high transparency, good electrical conductivities, tuneable…
The functionalization of nanodiamonds (diamondoids) as a key parameter of their easily controlled self-assembly in micro- and nanocrystals from the v…
2014
We detail herein readily accessible processes to control previously unobserved robust self-assemblies of nanodiamonds (diamondoids) in micro- and nanocrystals from their mild vapor deposition. The chemical functionalization of uniform and discernible nanodiamonds was found to be a key parameter, and depending on the type of functional group (hydroxy, fluorine, etc.) and its position on the diamondoid, the structure of the discrete deposits can vary dramatically. Thus, well-defined anisotropic structures such as rod, needle, triangle or truncated octahedron shapes can be obtained, and self-assembled edifices of sizes ranging from 20 nm to several hundred micrometers formed with conservation …
A tungsten oxide–lutetium bisphthalocyanine n–p–n heterojunction: from nanomaterials to a new transducer for chemo-sensing
2019
We report on a new hybrid heterojunction gas-sensitive device by combining a molecular material with a metal oxide. WO3 was synthesised via an aerosol-assisted chemical vapour deposition technique from a tungsten hexacarbonyl precursor. Onto an inorganic film, LuPc2 was vacuum evaporated. The morphology of the WO3–LuPc2 hybrid films is dominated by the morphological features of the tungsten oxide film, as shown by scanning electron microscopy and atomic force microscopy. Raman spectroscopy of the device confirms the presence of both materials. The non-linear I–V characteristics demonstrate the existence of an energy barrier at the interface between the inorganic and molecular materials. The…
Atomic layer deposition of WO3 thin films using W(CO)6 and O3 precursors
2012
Here we report a new atomic layer deposition (ALD) process for WO3 thin films based on W(CO)6 as a tungsten source and ozone as a source of oxygen. A narrow ALD temperature window is found at 195–205 °C for WO3 with a deposition rate of 0.23 A per cycle. As-deposited films are partially crystalline with root mean square (rms) roughness values of 4.7 nm for 90 nm thick films; annealing the films at 600–1000 °C under oxygen or nitrogen atmospheres enhances the degree of crystallinity considerably. Our results show that the straightforward ALD chemistry of carbonyl compounds and ozone is applicable to the deposition of WO3 thin films.
Subglacial to proglacial depositional environments in an Ordovician glacial tunnel valley, Alnif, Morocco
2013
Abstract This paper presents the sedimentary analysis of an exceptional Ordovician glacial tunnel valley in the eastern part of the Anti-Atlas. The valley infill comprises two major glacial erosion surfaces (striated pavements) each overlain by a fining-upward glacial unit. These units are composed of five distinct facies associations, recording the evolution from subglacial to proglacial environments, and an additional sixth facies association, overtopping the tunnel valley infill, and associated with post-glacial environments. The tunnel valley infill also records a transitional environment between the subglacial and proglacial settings, which is compared with the Antarctic ice-sheet marg…
Environmental and depositional controls on laminated freshwater carbonates: An example from the Roman aqueduct of Patara, Turkey
2013
Carbonate deposits in aqueducts are a new high-resolution data source for environmental changes during the time of the Roman Empire, notably in the fields of palaeoclimate and spring hydrology. In order to distinguish environmental effects from those related to depositional setting, laminated carbonate deposits were compared along the entire length of an ancient aqueduct channel at Patara, Turkey. The carbonate deposits, up to 80mm in thickness, are composed of lamina couplets up to 1mm thick of alternating porous microspar and dense, columnar sparite. The former formed in the dry, warm season and the latter in the wet, cool season. The presence of biofilms seems to play a role in the devel…
Continuous monitoring of an intentionally-manufactured crack using an automated welding and in-process inspection system
2020
Abstract Automated weld deposition coupled with the real-time robotic Non-Destructive Evaluation (NDE) is used in this paper. For performance verification of the in-process inspection system, an intentionally embedded defect, a tungsten rod, is introduced into the multi-pass weld. A partially-filled groove (staircase) sample is also manufactured and ultrasonically tested to calibrate the real-time inspection implemented on all seven layers of the weld which are deposited progressively. The tungsten rod is successfully detected in the real-time NDE of the deposited position. The same robotic inspection system was then used to continuously monitor an intentionally-manufactured crack for 20 h.…
Definition of analytical cleaning procedures for archaeological pottery from underwater environments: The case study of samples from Baia (Naples, So…
2021
Abstract This work is focused on a multidisciplinary study of 13 pottery fragments collected in the submerged archaeological site of Baia (Naples, Italy). Founded by the Romans in the 1st century B.C., this archaeological area represents one of the greatest evidences of Roman architecture and it includes ancient ruins whose structures range from maritime villas and imperial buildings. Several diagnostic tests were carried out in order to characterize the archaeological materials, their structure and properties, as well as the alteration and degradation products. Degradation forms in seawater imply not only a variation in the physico-mechanical and chemical properties of the material but als…
A facies distribution model controlled by a tectonically inherited sea bottom topography in the carbonate rimmed shelf of the Upper Tithonian–Valangi…
2016
The Upper Tithonian–Valanginian shallow-water carbonates outcropping in the Palermo Mts (NW Sicily) consist of several facies associations reflecting different depositional environments of a carbonate rimmed shelf, pertaining to the Southern Tethyan continental margin. The reconstructed depositional model, based on the sedimentological features, cyclic facies arrangement and biota distribution, shows that a wide protected lagoon, dominated by algae, molluscs and scattered patch reefs, was bordered landward by a tidal flat, where stromatolitic algal mats were cyclically subaerial exposed, and seaward by a marine sand belt and reef complex. Oolitic packstone-grainstone lithofacies, cyclically…
Atmospheric dry deposition processes of particles on urban and suburban surfaces: Modelling and validation works
2019
Abstract Dry deposition process is one of the important pathways for the removal of particles from atmosphere. It is the result of a combination of different environmental and physical factors as atmospheric conditions, particle properties, characteristics of the canopy. For this latter factor, urban canopy represents unevenly combinations of different types of surface elements that increases the complexity of deposition process phenomena. Therefore, particle dry deposition on urban surfaces is not easy to configure and, although empirical or semi-empirical models in literature have been developed to address this aspect, there is not standardized and commonly accepted criteria, especially f…