Search results for "Deposit"
showing 10 items of 1447 documents
Aluminum tri-isopropoxide as an alternative precursor for atomic layer deposition of aluminum oxide thin films
2019
Due to the safety challenges associated with the use of trimethylaluminum as a metal precursor for the deposition of alumina, different chemicals have been investigated over the years to replace it. The authors have investigated the use of aluminum tri-isopropoxide (TIPA) as an alternative alkoxide precursor for the safe and cost-effective deposition of alumina. In this work, TIPA is used as a stable Al source for atomic layer deposition (ALD) of Al2O3 when different oxidizing agents including water, oxygen plasma, water plasma, and ozone are employed. The authors have explored the deposition of Al2O3 using TIPA in ALD systems operating in vacuum and atmospheric pressure conditions. For the…
Chemical and isotopic characterization of rainwater in volcanic, urban and industrial areas of Sicily (Italy)
2021
The chemical composition of rainwater depends on (i) the dissolution of gases and particulate matter emitted by different sources, (ii) the chemical and physical reactions occurring during local and regional scale transport, and (iii) removal processes. The source of major and trace elements dissolved in rainwater can be both natural (e.g. sea salts, volcanic emissions, geogenic dust, biogenic material) and anthropogenic (e.g. industrial plants, vehicular traffic, domestic heating, vessel traffic). A group of trace elements has been recently brought to attention, especially for their possible environmental impacts, the Technology-critical elements (TCEs): Ga, Ge, In, Te, Nb, Ta, Tl, the Pla…
Potential-assisted deposition of mixed alkanethiol self-assembled monolayers
2010
Abstract Preparation of self-assembled monolayers (SAMs) usually involves passive incubation. The recently developed potential-assisted deposition is indeed more selective as well as 100-fold faster than passive adsorption, thereby enhancing the reproducibility of the monolayer deposition. This article aims to identify the electrodeposition conditions necessary to prepare mixed alkanethiol SAMs on gold surface. Parameters such as concentrations in solution, electrode polarization and deposition time were examined for two chain lengths, C 3 (mercaptopropionic acid, MPA) and C 18 (octadecanethiol, ODT). The kinetics and composition of the SAMs were systematically characterized by reductive st…
Investigation of a Gravel-Bed River’s Pattern Changes: Insights from Satellite Images
2021
Changes in river pattern have been documented in the literature. The recognition of islands and vegetated patches, which is indicative of the evolution processes, requires simultaneous information at different points and at different times and field studies are still difficult and scarce. The present work, focusing the attention on a gravel-bed river, explores the possibility to conduct a first-step pattern changes analysis by identifying the evolution of the morphological features and taking information of islands and vegetated patches from satellite images easily available from Google Earth. The study is conducted by combining the information taken from both the satellite images and the f…
Nasium : Sondage archéologique à Saint-Amand-sur-Ornain " Le Cul de Breuil "
2010
Ce rapport de fouille présente les résultats d'un sondage archéologique mené au cœur du site de Nasium, à l'interface entre l'oppidum celtique et l'agglomération antique. Le système de voirie qui relie ces deux , dans le prolongement d'une des portes principales de l'oppidum, a été ainsi révélé, associé à des structures à caractère funéraire ou rituel. La chronologie de ces vestiges, centrée sur les dernières décennies du Ier siècle avant J.-C., correspond à la période durant laquelle l'oppidum est abandonné au profit de la plaine alluviale de l'Ornain. Par ailleurs, la découverte de plusieurs centaines de clous de chaussure militaires et de céramiques d'origine italique pose la question du…
Carbon stocks in a 50‑year‑oldEucalyptus camaldulensisstand in Sicily, Italy
2015
Eucalyptus stands in semi-arid areas may contribute to enhance carbon (C) stocks in both biomass and soil. However, the limited information available is mainly focused on short-rotation plantations. In this study, the above- and below-ground C pools in five 50-year-old Eucalyptus camaldulensis Dehnh. stands planted on Miocenic evaporitic deposits in Sicily, Italy, with a xeric and thermic pedoclimate, were measured. Above-ground biomass was determined by partitioning and weighing branches, stem and leaves. Below-ground C pools included the determination of litter, root biomass, and soil organic and inorganic C. In terms of the above-ground biomass, the E. camaldulensis stand accumulated on …
Fosildiagénesis del anélido Rotularia spirulaea (Lamarck, 1818) (Polychaeta, Serpulidae) en el Eoceno del dominio pirenaico occidental
2018
The presence of the fossil polychaete Rotularia spirulaea (Lamarck, 1818) in Eocene deposits (middle Lutecian – upper Bartonian and (?) Priabonian) belonging to the western Pyrenean Domain is verified. In this paper, a fossildiagenetic study has been carried out. Fossils from three areas, corresponding to diff erent depositional settings, have been analysed. In area 1, sediments of the Ardanatz Sandstone and Ilundain Marls formations [Pamplona Basin and adjoining areas (Navarre)], were sampled. Here, the specimens of R. spirulaea were not substantially affected by taphonomic reworking and the original microstructure of the carbonate tube is preserved. The test consists of a thick external …
Fabrication of 3-D phononic crystals for thermal transport management
2016
Thermal transport is an important physical phenomenon, and it has recently become even more relevant for the reduction of energy losses and the increase of efficiency in novel devices based on thermoelectricity [1]. Significant reduction of thermal conduction was recently achieved by coherent modification of phonon modes [2], with the help of periodic phononic crystal structures. However, currently the experimental studies have only been performed for two-dimensional (2-D) nanostructures. Theoretically, the magnitude of control of thermal transport should be even stronger in three-dimensional (3-D) phononic crystal structures. For that reason, the question arises how to fabricate the desire…
Review article: recommended reading list of early publications on atomic layer deposition - outcome of the "virtual Project on the History of ALD"
2017
Atomic layer deposition (ALD), a gas-phase thin film deposition technique based on repeated, self-terminating gas-solid reactions, has become the method of choice in semiconductor manufacturing and many other technological areas for depositing thin conformal inorganic material layers for various applications. ALD has been discovered and developed independently, at least twice, under different names: atomic layer epitaxy (ALE) and molecular layering. ALE, dating back to 1974 in Finland, has been commonly known as the origin of ALD, while work done since the 1960s in the Soviet Union under the name "molecular layering" (and sometimes other names) has remained much less known. The virtual proj…