Search results for "Deposition"
showing 10 items of 1324 documents
Influence of melt flow and temperature on erosion of refractory and deposit formation in aluminium melting furnaces
2002
The deposition and erosion mechanism in induction-channel furnace for Al melting in alumino-silicate refractory is considered. The possibility of simultaneous erosion and deposition in the same cross-section of the channel is shown. The chemical reaction model causing the erosion of refractory is proposed. The erosion process is described by chemically active aluminium oxides while the deposition is caused by chemically stable aluminium oxides. The variations of erosion and deposition in the same cross-section of the channel are explained by variation of the thickness of laminar sub-layer along the perimeter.
Milankovitch and sub-Milankovitch forcing of the Oxfordian (Late Jurassic) Terres Noires Formation (SE France) and global implications
2010
ABSTRACT High‐resolution analysis (2277 samples) of magnetic susceptibility (MS) was performed on ∼700‐m‐thick Early–Middle Oxfordian marine marls of the Terres Noires Formation, SE France. MS variations within these sediments record sub‐Milankovitch to Milankovitch frequencies with long‐term eccentricity (405 kyr and ∼2 Myr) being the most prominent. The 405 kyr cycle was used as a high‐resolution geochronometer for astronomical calibration of this poorly constrained interval of Late Jurassic time. The estimated duration of this Early–Middle Oxfordian interval concurs with the current International Geologic Time Scale GTS2004 (∼4 Myr), but the estimated durations of the corresponding ammon…
Spatial and temporal distribution of ooids along a Jurassic carbonate ramp: Amellago outcrop transect, High-Atlas, Morocco
2010
Carbonate ramp systems are widespread throughout the geological record, but very few areas have seismic-scale, continuous and structurally undeformed outcrops that allow reliable interpretation of facies distributions and stacking patterns. The Amellago outcrop shows the detailed depositional and stratigraphic relationships of an ooid-dominated ramp system that is almost completely exposed along a dip profile (37 km long and 1000 m thick) in the Lower to Middle Jurassic of the southern High Atlas, Morocco. Ammonite and brachiopod fauna provide excellent biostratigraphic control on small scale stacking patterns. At Amellago, the evolution of depositional environments is evident at different …
Episodic deposition of the Lias in the Medianes nappe (western Switzerland): a record from mineralized ammonite-bearing beds
1992
Abstract Sinemurian and Pliensbachian depositional sequences from the starved distal northern continental margin of the Tethys are preserved in the Medianes Nappe (Western Swiss Prealps). They contain mineralized beds which include a variety of facies. The northern continental margin of the Tethys was broken into blocks, less than 50 km wide, during an extensional phase. The Sinemurian and Pliensbachian sediments in the study are vary in thickness from less than 50 m in the north to more than 200 m in the south. Although the upper Sinemurian to Pliensbachian mineralized beds are thin, between 0.10 and 0.50 m thick, they commonly contain several distinct faunal horizons stacked one upon anot…
Settlement down again patterns of a carbonated platform following up a sedimentary crisis : example of the middle-late Jurassic boundary in the south…
2004
Abstract Following a sedimentary crisis which begins in the late Lower Callovian and spans all the early Oxfordian, the settlement down patterns of a platform with carbonated sedimentation are analysed in a southeastern area of the Paris Basin (fig. 1). Ten lithostratigraphic units (reefal formations, associated bioclastic facies and marly distal lateral facies ; fig. 2) are defined (fig. 3). New ammonite and brachiopod faunas, collected in situ, allow to date accurately the sedimentary units with a precision matching an ammonite subzone of the standard bio-chronostratigraphic scale (fig. 4) of the middle-late Oxfordian (from the Parandieri Subzone, at the base of the Transversarium Zone, t…
Templated growth of smart coatings: Hybrid chemical vapour deposition of vanadyl acetylacetonate with tetraoctyl ammonium bromide
2009
Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition methodology has been utilised to produce thin films of vanadium dioxide from vanadyl acetylacetonate. Tetraoctyl ammonium bromide (TOAB) was used in the aerosol precursor solution. The films were analysed by X-ray diffraction, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy. Their optical and thermochromic behaviour was also determined. It was found that the use of TOAB had a templating effect that led to a halving in the particle size and that this consequently led to a significant decrease in the thermochromic transition temperature of the films to 34 8C.
Templated growth of smart nanocomposite thin films: Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition of vanadyl acetylacet…
2009
Hybrid aerosol assisted and atmospheric pressure chemical vapour deposition methodology has been utilised to produce nanocomposite thin films of gold nanoparticles and vanadium dioxide from vanadyl acetylacetonate and auric acid. The addition of tetraoctyl ammonium bromide (TOAB) to the precursor Solution gave control of the size and distribution of gold nanoparticles in the vanadium oxide matrix. These reactions led to vanadium dioxide films with reduced crystallite sizes and enhanced thermochromic properties. The films were analysed by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. Their optical and thermochromic behaviour was also determined, This h…
Crystallization kinetics of amorphous SiC films: Influence of substrate
2005
Abstract The crystallization kinetics of amorphous silicon carbide films was studied by means of X-ray diffractometry (XRD) and transmission electron microscopy (TEM). The films were deposited by radio frequency (r.f.) magnetron sputtering on glassy carbon and single crystalline silicon substrates, respectively. TEM micrographs and XRD patterns show the formation of nano-crystalline β-SiC with crystallite sizes in the order of 50 nm during annealing at temperatures between 1200 and 1600 °C. A modified Johnson–Mehl–Avrami–Kolmogorov (JMAK) formalism was used to describe the isothermal transformation of amorphous SiC into β-SiC as an interface controlled, three-dimensional growth processes fr…
Amorphous Silicon Nanotubes via Galvanic Displacement Deposition
2013
Amorphous silicon nanotubes were grown in a single step into a polycarbonate membrane by a galvanic displacement reaction conducted in aqueous solution. In order to optimize the process, a specifically designed galvanic cell was used. SEM images, after polycarbonate dissolution, showed interconnected nanotube bundles with an average length of 18 μm and wall thickness of 38 nm.The deposited silicon was revealed by EDS analysis, whilst X-ray diffraction and Raman spectroscopy showed that nanotubes have an amorphous structure. Silicon nanotubes were also characterized by photo-electrochemical measurements that showed n-type conductivity and optical gap of ~1.6 eV. Keywords: Silicon nanotubes, …
Influence of the electro-optical properties of an a-Si:H single layer on the performances of a pin solar cell
2012
We analyze the results of an extensive characterization study involving electrical and optical measurements carried out on hydrogenated amorphous silicon (α-Si:H) thin film materials fabricated under a wide range of deposition conditions. By adjusting the synthesis parameters, we evidenced how conductivity, activation energy, electrical transport and optical absorption of an α-Si:H layer can be modified and optimized. We analyzed the activation energy and the pre-exponential factor of the dark conductivity by varying the dopant-to-silane gas flow ratio. Optical measurements allowed to extract the absorption spectra and the optical bandgap. Additionally, we report on the temperature dependen…