Search results for "Diagram"
showing 10 items of 795 documents
Spontaneous symmetry-breaking pathways: time-resolved study of agarose gelation
1996
Abstract Extensive time-resolved studies of self-assembly of agarose gels, performed with the use of a variety of techniques allowed identification of the initial break of symmetry and the actual path leading to self-assembly at concentrations well below the random percolation threshold. The overall process is seen to occur through the following sequence: (i) break of symmetry in the sol, causing the spontaneous generation of mesoscopic polymer-rich and solvent-rich regions; (ii) percolation, or nearly percolation [see (iv) below], of polymer-rich regions through the sample, still in the sol state; (iii) start of polymer cross-linking within polymer-rich regions; (iv) progress of cross-link…
Simulation of Order-Disorder Phenomena and Diffusion in Metallic Alloys
1991
The application of the Monte Carlo method to lattice-statistics problems in metallurgy is reviewed. Examples are given for the prediction of phase diagrams from simple model assumptions for effective interatomic potentials and for the calculation of parameters describing long- and short-range order, ordering energy, etc., both for face-centered cubic (fcc) and body-centered cubic (bcc) lattices. Applications to real systems such as Cu—Au and Fe—Al alloys are discussed.
Monte Carlo calculation of free energy for a fcc lattice-gas model
1990
A face-centered-cubic Ising lattice-gas model with nearest- and next-nearest-neighbor interactions is studied, and an accurate determination of the transition temperature for the discontinuous order-disorder transition is obtained. This model is of interest in the studies of phase diagrams for metallic alloys. The location of the transition was previously not known accurately, and its estimation has a number of applications. Very accurate absolute free-energy densities for the two coexisting phases have been obtained from a combination of the standard thermodynamic integration method and the method of sampling finite-size dependence. The latent-heat also is calculated with good precision.
Small-Angle Scattering from Phase-Separated Metallic Alloys: From Experiment to Phase Diagrams
1994
In this paper, phase-separated metallic alloys are described in terms of concentration fluctuations. As a consequence, Small Angle Scattering equations which allow to calculate the entire scattering curve by incorporating particle-particle interference effects on the basis of the Percus-Yevick formalism, are obtained. It is shown that, for Aluminium-Lithium alloys, satisfactory fits of the experimental data can be obtained if it is assumed that Li rich elliptical monodisperse precipitate particles approach each other at average distances which are larger than the sum of the hard-sphere particle radii. It is also shown that a possible ambiguity of this model, within the Percus-Yevick formali…
Calculation of phase diagrams for models of metallic alloys
2007
We briefly review a longstanding problem of metallurgy and statistical physics, namely, the prediction of phase diagrams of binary alloys from simple model assumptions on the atomic interactions, such as Ising-type models. Various methods of statistical mechanics which have been applied to this problem are introduced and compared to each other, such as the cluster-variation method and Monte-Carlo simulation. The merits as well as the limitations of these methods are discussed, emphasizing examples of fcc and bcc lattices which are potentially relevant for the problem of short-range order and long-range order in metallic alloys such as Cu−Au, Ni−Cr, and Fe−Al.A brief comparison with correspo…
Sheared colloidal crystals in confined geometry: a real space study on stationary structures under shear.
2003
We constructed an optical plate-plate shear cell suitable for the study of aqueous suspensions of charged colloidal spheres under low electrolyte concentrations (10(-6) M). The variable gap height was adjusted to 30 microm corresponding to 15-30 interparticle distances. The concentration of 300 microm diameter polystyrene spheres was chosen around 1 microm(-1) where previous studies had revealed the equilibrium structure to be fluid or body centred cubic. Under shear, layer structures of hexagonal symmetry form, often coexistent with a fluid phase. We used an adapted high resolution video microscope to perform a detailed study of the structure. The central ray of light was prevented from en…
Chalcogenide glass hollow core photonic crystal fibers
2010
International audience; We report the first hollow core photonic crystal fibers (HC PCF) in chalcogenide glass. To design the required HC PCF profiles for such high index glass, we use both band diagram analysis to define the required photonic bandgap and numerical simulations of finite size HC PCFs to compute the guiding losses. The material losses have also been taken into account to compute the overall losses of the HC PCF profiles. These fibers were fabricated by the stack and draw technique from Te20As30Se50 (TAS) glass. The fibers we drew in this work are composed of six rings of holes and regular microstructures. Two profiles are presented, one is known as a kagome lattice and the ot…
Simulation of FUS protein condensates with an adapted coarse-grained model
2020
AbstractDisordered proteins and nucleic acids can condense into droplets that resemble the membraneless organelles observed in living cells. MD simulations offer a unique tool to characterize the molecular interactions governing the formation of these biomolecular condensates, their physico-chemical properties, and the factors controlling their composition and size. However, biopolymer condensation depends sensitively on the balance between different energetic and entropic contributions. Here, we develop a general strategy to fine-tune the potential energy function for molecular dynamics simulations of biopolymer phase separation. We rebalance protein-protein interactions against solvation …
A teaching proposal for the didactics of Special Relativity: the spacetime globe
2022
Abstract Special Relativity introduces students to Modern Physics, whose importance in the high school is increasing. Nevertheless its teaching and learning is a critical issue. Different solutions have been developed to overcome the encountered difficulties. In this paper we describe the spacetime globe, a mechanical instrument that allows to experience Special Relativity hands-on. We show how it is possible to treat all the main phenomena foreseen by Special Relativity with simple laboratory experiences, using the idea of Minkowski’s spacetime diagrams. The aim is to develop the use of geometrical approach in learning Special Relativity in high schools.
Neural Multimodal Belief Tracker with Adaptive Attention for Dialogue Systems
2019
Multimodal dialogue systems are attracting increasing attention with a more natural and informative way for human-computer interaction. As one of its core components, the belief tracker estimates the user's goal at each step of the dialogue and provides a direct way to validate the ability of dialogue understanding. However, existing studies on belief trackers are largely limited to textual modality, which cannot be easily extended to capture the rich semantics in multimodal systems such as those with product images. For example, in fashion domain, the visual appearance of clothes play a crucial role in understanding the user's intention. In this case, the existing belief trackers may fail …