Search results for "Diffraction"
showing 10 items of 1584 documents
X-ray nanotomography and electron backscatter diffraction demonstrate the crystalline, heterogeneous and impermeable nature of conodont white matter
2021
Conodont elements, microfossil remains of extinct primitive vertebrates, are commonly exploited as mineral archives of ocean chemistry, yielding fundamental insights into the palaeotemperature and chemical composition of past oceans. Geochemical assays have been traditionally focused on the so-called lamellar and white matter crown tissues; however, the porosity and crystallographic nature of the white matter and its inferred permeability are disputed, raising concerns over its suitability as a geochemical archive. Here, we constrain the characteristics of this tissue and address conflicting interpretations using ptychographic X-ray-computed tomography (PXCT), pore network analysis, synchro…
The scattering of 38 MeV α-particles by C, N, 0, F and Kr nuclei
1960
This paper describes observations by a photographic method on the angular distributions of 38 MeV α-particles scattered by light nuclei. Elastically and inelastically scattered particles were distinguished by their range in nuclear emulsion. The observed distributions are compared with the general predictions of the nuclear optical model, of direct interaction theories,and of the inelastic diffraction theory of Blair. In teraction radii are deduced from the angular distributions.
Effect of neutron halos on excited states of nuclei
2011
The differential cross sections of the inelastic scattering leading to the excitation of short-lived states in the stable ${}^{13}$C and ${}^{9}$Be nuclei as well as the radioactive ${}^{11}$Be nucleus have been analyzed. Signatures of neutron halos in the excited states located close to the neutron emission thresholds have been investigated by applying a recently developed modified diffraction model. The abnormally large rms radius was identified for the 3.089-MeV $1/{2}^{+}$ state of ${}^{13}$C. Significantly enlarged diffraction radii were found for the 1.68-MeV $1/{2}^{+}$ and the 3.05-MeV $5/{2}^{+}$ states of ${}^{9}$Be. The analysis of the diffraction radii of the weakly bound radioa…
Molecular origin and hydration dependence of protein anharmonicity: an elastic neutron scattering study.
2010
Two main onsets of anharmonicity are present in protein dynamics. Neutron scattering on protein hydrated powders revealed a first onset at about 150 K and a second one at about 230 K (the so called dynamical transition). In order to assess the molecular origin of protein anharmonicity, we study different homomeric polypeptides by incoherent elastic neutron scattering, thus disentangling the contribution of different molecular groups in proteins. We show that methyl group rotations are the main contributors to the low temperature onset. Concerning the dynamical transition, we show that it also occurs in absence of side chains; however, the presence and mobility of side chains substantially i…
Peculiarities of Phase Formation in Mn-Based Na SuperIonic Conductor (NaSICon) Systems: The Case of Na1+2xMnxTi2–x(PO4)3 (0.0 ≤ x ≤ 1.5)
2021
This project has received funding from the European Regional Development Fund (Project no. 01.2.2-LMT-K-718-02–0005) under grant agreement with the Research Council of Lithuania (LMTLT). We thank the High Performance Computing Center “HPC Saulėtekis” at the Faculty of Physics, Vilnius University, for the use of computational resources.
Communication modes in vector diffraction
2010
The communication modes, which mathematically correspond to singular value decomposition, have proven a useful concept in optical scalar-field diffraction, with applications in resolution studies, image synthesis, and wave propagation. For optical near-field geometries the communication modes have to be extended to electromagnetic field accounting for the polarization properties. In this paper we present the vector-valued communication modes method based on the rigorous electric-field diffraction integral. As a special case the transverse-electric scalar field modes are obtained. The intensity and polarization properties of the leading electromagnetic communication modes in near-field arran…
Computation of the field diffracted by a local surface defect: application to tip–sample interaction in the photon scanning tunneling microscope
1996
We use a method based on the Fourier transform of the electromagnetic field to compute the field diffracted by a local deformation of a plane boundary surface. We give a complete development of each step of the technique. To show the interaction that exists between the probe of a near-field optical microscope and the observed sample, we use the model of a truncated cone-shaped tip above a rectangular surface defect. We compute the electrical intensity along a line located between the tip and the local surface defect. We show the influence of the polarization of the incident wave and the effect of the position of the tip with respect to the position of the surface defect.
Transmission electron microscopy in molecular structural biology: A historical survey.
2015
In this personal, historic account of macromolecular transmission electron microscopy (TEM), published data from the 1940s through to recent times is surveyed, within the context of the remarkable progress that has been achieved during this time period. The evolution of present day molecular structural biology is described in relation to the associated biological disciplines. The contribution of numerous electron microscope pioneers to the development of the subject is discussed. The principal techniques for TEM specimen preparation, thin sectioning, metal shadowing, negative staining and plunge-freezing (vitrification) of thin aqueous samples are described, with a selection of published im…
The hydration shell of myoglobin.
1992
The space in the unit cell of a metmyoglobin crystal not occupied by myoglobin atoms was filled with water using Monte Carlo calculations. Independent calculations with different amounts of water have been performed. Structure factors were calculated using the water coordinates thus obtained and the known coordinates of the myoglobin atoms. A comparison with experimental structure factors showed that both the low and the high resolution regime could be well reproduced with 814 Monte Carlo water molecules per unit cell with a B-value of 50 A2. The Monte Carlo water molecules yield a smaller standard R-value (0.166) than using a homogeneous electron density for the simulation of the crystal w…
Frontispiece: A Novel High‐Pressure Tin Oxynitride Sn 2 N 2 O
2020
Chemistry - a European journal 26(10), 2187-2194 (2020). doi:10.1002/chem.202081063