Search results for "Diffraction"
showing 10 items of 1584 documents
Multiple-plane image formation by Walsh zone plates.
2018
[EN] A radial Walsh filter is a phase binary diffractive optical element characterized by a set of concentric rings that take the phase values 0 or ¿, corresponding to the values + 1 or ¿1 of a given radial Walsh function. Therefore, a Walsh filter can be re-interpreted as an aperiodic multifocal zone plate, capable to produce images of multiple planes simultaneously in a single output plane of an image forming system. In this paper, we experimentally demonstrate for the first time the focusing capabilities of these structures. Additionally, we report the first achievement of images of multiple-plane objects in a single image plane with these aperiodic diffractive lenses.
Experimental and Theoretical Electron Density Determination for Two Norbornene Derivatives: Topological Analysis Provides Insights on Reactivity
2016
The electron density distribution of two substituted norbornene derivatives (cis-5-norbornene-endo-2,3-dicarboxylic anhydride (1) and 7-oxabicylo[2.2.1]hept-5-ene-exo-2,3-dicarboxylic anhydride (2) has been determined from low-temperature (20 K) X-ray diffraction data and from DFT calculations with periodic boundary conditions. Topological analysis of the electron density is discussed with respect to exo-selective additions, the partial retro-Diels-Alder (rDA) character of the ground state, and intermolecular interaction energies.
Denaturing for Nanoarchitectonics: Local and Periodic UV-Laser Photodeactivation of Protein Biolayers to Create Functional Patterns for Biosensing
2022
[EN] The nanostructuration of biolayers has become a paradigm for exploiting nanoscopic light-matter phenomena for biosensing, among other biomedical purposes. In this work, we present a photopatterning method to create periodic structures of biomacromolecules based on a local and periodic mild denaturation of protein biolayers mediated by UV-laser irradiation. These nanostructures are constituted by a periodic modulation of the protein activity, so they are free of topographic and compositional changes along the pattern. Herein, we introduce the approach, explore the patterning parameters, characterize the resulting structures, and assess their overall homogeneity. This UV-based patterning…
Influence of irradiation on the switching behavior in PZT thin films
2005
Spatially nonuniform imprint behavior induced by X-ray synchrotron, electron and neutron irradiation has been investigated in sol–gel Pb(Zr,Ti)O3 thin films. The analysis of the switching current data reveals the strong influence of irradiation on the switching current shape. The obtained effects have been explained as a result of acceleration of the bulk screening process induced by irradiation. It was shown that the spatial distribution of the internal bias field is determined by the domain structure existing during irradiation. The changes in the structural characteristics during fatigue cycling have been reveled by high resolution synchrotron X-ray diffraction experiments on (1 1 1)-ori…
In situ synchrotron radiation monitoring of phase transitions during microwave heating of Al–Cu–Fe alloys
2008
The effect of rapid microwave heating has so far been evaluated mainly by comparing the state of materials before and after microwave exposure. Yet, further progress critically depends on the ability to follow the evolution of materials during ultrafast heating in real time. We describe the first in situ time-resolved monitoring of solid-state phase transitions during microwave heating of metallic powders using wide-angle synchrotron radiation diffraction. Single-phase Al–Cu–Fe quasicrystal powders were obtained by microwave heating of nanocrystalline alloy precursors at 650 °C in <20 s.
Neutron Diffraction Study of the in Situ Oxidation of UO2
2009
This paper discusses uranium oxide crystal structure modifications that are observed during the low-temperature oxidation which transforms UO(2) into U(3)O(8). The symmetries and the structural parameters of UO(2), beta-U(4)O(9), beta-U(3)O(7), and U(3)O(8) were determined by refining neutron diffraction patterns on pure single-phase samples. Neutron diffraction patterns were also collected during the in situ oxidation of powder samples at 483 K. The lattice parameters and relative ratios of the four pure phases were measured during the progression of the isothermal oxidation. The transformation of UO(2) into U(3)O(8) involves a complex modification of the oxygen sublattice and the onset of…
In-situ high-pressure x-ray diffraction study of zinc ferrite nanoparticles
2016
We have studied the high-pressure structural behavior of zinc ferrite (ZnFe2O4) nanoparticles by powder X-ray diffraction measurements up to 47 GPa. We found that the cubic spinel structure of ZnFe2O4 remains up to 33 GPa and a phase transition is induced beyond this pressure. The high-pressure phase is indexed to an orthorhombic CaMn2O4-type structure. Upon decompression the low- and high-pressure phases coexist. The compressibility of both structures was also investigated. We have observed that the lattice parameters of the high-pressure phase behave anisotropically upon compression. Further, we predict possible phase transition around 55 GPa. For comparison, we also studied the compressi…
A new cell for the study of in situ chemical reactions using X-ray absorption spectroscopy
2005
An in situ cell for reductive and oxidative treatments at different temperatures that allows the possibility of recording data as a function of temperature has been designed and constructed for X-ray absorption experiments at the GILDA beamline BM08 of ESRF. The cell is linked to a mass quadrupole spectrometer providing control of the reaction gases and monitoring of the products. The apparatus allows measurements to be performed both in transmission and fluorescence geometry. The cell was tested by studying the CO oxidation reaction promoted by a Pt/ceria-zirconia-supported catalyst. The CO(2) yield is correlated with the structural results confirming the existence of a strong metal-suppor…
Structural variations as a function of surface adsorption in nanostructured particles
2004
Macroscopic (adsorption isotherm and micro-calorimetry measurement) and microscopic (in situ X-ray diffraction and IR spectroscopy) approaches were used to study the influence of water adsorption on γ-Fe 2 O 3 nanoparticles. A nonmonotonic variation of γ-Fe 2 O 3 lattice parameter is revealed when the relative water pressure (p/p 0 ) increases from 0.03 to 0.96 with a maximum deviation for p/p 0 0.1. With IR spectroscopy, similar results were observed since a modification of γ-Fe 2 O 3 structural bands has been shown. In situ investigations as well as thermodynamics considerations lead to one important conclusion: the variation of the lattice parameter is in relation with the strains induce…
ChemInform Abstract: Neutron Diffraction Study of the in situ Oxidation of UO2.
2009
This paper discusses uranium oxide crystal structure modifications that are observed during the low-temperature oxidation which transforms UO2 into U3O8. The symmetries and the structural parameters of UO2, β-U4O9, β-U3O7, and U3O8 were determined by refining neutron diffraction patterns on pure single-phase samples. Neutron diffraction patterns were also collected during the in situ oxidation of powder samples at 483 K. The lattice parameters and relative ratios of the four pure phases were measured during the progression of the isothermal oxidation. The transformation of UO2 into U3O8 involves a complex modification of the oxygen sublattice and the onset of complex superstructures for U4O…