Search results for "Diffusion"

Intervention publique et déploiement la télémédecine : une analyse par les théories de l'innovation

2019

Telemedicine is a health sector innovation which implies remote management of patient, future will tell if this innovation is a revolution for geographical healthcare access. In this perspective but despite or because of spontaneous telemedicine uses which have not spread, public authorities launched in France, in 2011, a national strategy to support the spread of telemedicine. In this context, this thesis analyzes complex interactions between public intervention and the diffusion process of telemedicine by using the theories of innovation diffusion. We built a framework for innovation diffusion of complex innovations such as telemedicine and identify three levers for diffusion that public …

Numerical simulations of air pollutant dispersion in a stratified planetary boundary layer

1978

Abstract A numerical model is described for computing pollutant concentration distributions downwind from a source. It is based on the three-dimensional dispersion equation governing the time-dependent advective and diffusive transport of air pollutants and is solved numerically by a mixed Lagrangian-Eulerian finite-difference scheme. The model includes the vertical wind shear, the turning of the actual wind, and vertical variations of the vertical eddy diffusivity. In this paper the model is used to simulate the pollutant dispersion process in a stratified planetary boundary layer. The vertical profiles of horizontal mean wind and vertical eddy diffusivities are calculated numerically from…

Validation of a Microscale Pollution Dispersal Model

1996

The three-dimensional numerical model MISCAM (Micro Scale Air Pollution Model) has been developed to study wind flow and pollutant dispersal in densely built-up urban areas (Eichhorn, 1989). The model has been successfully applied for planning purposes by a variety of institutions in Germany. MISCAM consists of the non-hydrostatic Eulerian equations of motion and a transport equation for pollutants. Turbulence closure is carried out by means of a k-e-model. To reduce numerical diffusion errors, Smolarkiewicz and Grabowski’s (1989) scheme may be used for the calculation of advective transport. Additionally, sedimentation and dry deposition of pollutants may be taken into account.

Novel poly (ionic liquid)-based anion exchange membranes for efficient and rapid acid recovery from industrial waste

2020

Abstract Owing to the less energy consumption, positive impact on the environment, and prospect of providing clean water resources, anion exchange membranes (AEMs) are promising materials for acid recovery from various industrial wastewater/effluent. Based on the diffusion dialysis process, AEMs selectively allow rapid proton permeation while efficiently retaining metal ions. To enhance the efficiency of the acid recovery process, precise control of macromolecular architecture and chemical composition that enables high hydrophilicity, proton conductivity through the membrane, and ion exchange capacity is required. In this direction, we report on the one-step fabrication of novel poly (ionic…

Development of polymer-based nanoparticles for Zileuton delivery to the lung : PMeOx and PMeOzi surface chemistry reduces interactions with mucins

2021

In this paper, two amphiphilic graft copolymers were synthesized by grafting polylactic acid (PLA) as hydrophobic chain and poly(2-methyl-2-oxazoline) (PMeOx) or poly(2-methyl-2-oxazine) (PMeOzi) as hydrophilic chain, respectively, to a backbone of α,β-poly(N-2-hydroxyethyl)-D,L-aspartamide (PHEA). These original graft copolymers were used to prepare nanoparticles delivering Zileuton in inhalation therapy. Among various tested methods, direct nanoprecipitation proved to be the best technique to prepare nanoparticles with the smallest dimensions, the narrowest dimensional distribution and a spherical shape. To overcome the size limitations for administration by inhalation, the nano-into-micr…

Extracting parameters from semi-log plots of polycrystalline silicon PV modules outdoor I–V data: Double-exponential model revisited

2010

This paper presents a method for extracting physically meaningful parameters from measured I–V curves of PV modules. The 7-parameter double-exponential model is applied in the modeling. The method is based on linear fitting of semi-logarithmic plots. The paper demonstrates a new technique to estimate the series resistance of a module with high accuracy from such plots. As a result, also the reverse saturation current and the quality factor of the diffusion diode can be determined. The method is applied to outdoor I–V data from a test station with three similar, but not identical, polycrystalline-Si modules. The values of the series resistances found with this method deviate somewhat from th…

Relaxation of self-entangled many-arm star polymers

1989

We present a description of the relaxation of star polymers based on the conformational scaling properties predicted by Daoud and Cotton and confirmed in our recent simulations. We identify three typical relaxation mechanisms. The first describes elastic deformation of the overall shape. Its relaxation time is nearly independent off. A second type of relaxation occurs via rotational diffusion. We predict that the relaxation time should scale with Nwlfz-v where Y is the correlation length exponent. A third relaxation process is the disentanglement of two or more arms. Here the longest relaxation time should increase exponentially with f llz. We measure various relaxation processes by molecul…

1997

We have determined by forced Rayleigh scattering the diffusion coefficients of photo-labeled polystyrene micronetwork spheres (radii ≤ 10 nm) in melts of linear polyvinylmethylether (M W ≤ 40000 g/mol) at temperatures of 20-80°C. An expected slippage of the spheres through the meshes of the entanglement network appears possible but is still within the experimental uncertainty of our results.

Probing Poly(n-butyl-methacrylate) Latex Film via Diffusion of Hydrophilic and Hydrophobic Dye Molecules

2003

In the study of holographic grating relaxation (forced Rayleigh scattering, FRS) in nascent latex films we examined poly(n-butyl methacrylate) films using two complementary diffusing probes:  a hyd...

Introduction into the study of translational diffusion by laser techniques

1988

Breve description de la technique du reseau holographique pour mesurer les coefficients de diffusion de traceurs dans des polymeres et de la technique de spectrometrie de correlation de photon pour la mesure des coefficients de diffusions mutuelle dans des melanges de polymeres