Search results for "Diss"
showing 10 items of 2500 documents
An intercultural approach to music education: Intercultural proposals for primary education
2011
Este artículo pretende mostrar una aproximación a la educación intercultural mediante el proceso de enseñanza musical porque ésta es una parte de la cultura que nos habla del hombre y de su relación con el mundo. Se intenta responder a las nuevas exigencias derivadas de los procesos migratorios con actividades abiertas y flexibles, con las que los docentes adquieran un nuevo protagonismo como profesionales. Éstos necesitan nuevas competencias para desenvolverse adecuadamente en tales contextos complejos, con el trabajo en equipo como principal estrategia ante posibles problemas derivados del diseño curricular y con la integración de las nuevas tecnologías de la información y la comunicación…
Dynamique induite par champ laser femtoseconde intense : alignement moléculaire en milieu gazeux dense et effet Kerr
2011
This thesis is devoted to the study of dynamics induced by intense femtoseconds lasers pulses. The first studied dynamics deals with molecular alignment of CO2-X mixtures (X=CO2, Ar, N2), in dense gases (up to 20 bar). Up to now, this regime has never been studied experimentally. In the field-free regime (after laser/matter interaction), molecular alignment exhibits two components : a permanent alignment and a transient one. The influence of collisions appears through population transfers between rotational states, which leads to a decrease of these two contributions. Permanent alignment relaxation time is only tied to inelastics collisions whereas transient alignment relaxation time is tie…
Ocean acidification affects fish spawning but not paternity at CO2 seeps
2016
Fish exhibit impaired sensory function and altered behaviour at levels of ocean acidification expected to occur owing to anthropogenic carbon dioxide emissions during this century. We provide the first evidence of the effects of ocean acidification on reproductive behaviour of fish in the wild. Satellite and sneaker male ocellated wrasse (Symphodus ocellatus) compete to fertilize eggs guarded by dominant nesting males. Key mating behaviours such as dominant male courtship and nest defence did not differ between sites with ambient versus elevated CO2 concentrations. Dominant males did, however, experience significantly lower rates of pair spawning at elevated CO2 levels. Despite the higher r…
Effects of nitrogen enrichment on zooplankton biomass and N:P recycling ratios across a DOC gradient in northern-latitude lakes
2021
AbstractWe used data from whole-lake studies to assess how changes in food quantity (phytoplankton biomass) and quality (phytoplankton community composition, seston C:P and N:P) with N fertilization affect zooplankton biomass, community composition and C:N:P stoichiometry, and their N:P recycling ratio along a gradient in lake DOC concentrations. We found that despite major differences in phytoplankton biomass with DOC (unimodal distributions, especially with N fertilization), no major differences in zooplankton biomass were detectable. Instead, phytoplankton to zooplankton biomass ratios were high, especially at intermediate DOC and after N fertilization, implying low trophic transfer effi…
Unified understanding of intrinsic and extrinsic controls of dissolved organic carbon reactivity in aquatic ecosystems
2022
Despite our growing understanding of the global carbon cycle, scientific consensus on the drivers and mechanisms that control dissolved organic carbon (DOC) turnover in aquatic systems is lacking, hampered by the mismatch between research that approaches DOC reactivity from either intrinsic (inherent chemical properties) or extrinsic (environmental context) perspectives. Here we propose a conceptual view of DOC reactivity in which the combination of intrinsic and extrinsic factors controls turnover rates and determines which reactions will occur. We review three major types of reactions (biological, photochemical, and flocculation) from an intrinsic chemical perspective and further define t…
Influence of protecting devices on the optimal design of elastic plastic structures
2008
The paper concerns the minimum volume design of structures constituted by elastic perfectly plastic material. The relevant optimal design problem is formulated on the grounds of a statical approach and two different resistance limits are considered: in particular, it is required that the optimal structure satisfies the elastic shakedown limit and the instantaneous collapse limit, imposing for each different condition a suitably chosen safety factor. For sake of generality, the structure is thought as discretized into compatible finite elements and subjected to loads quasi-statically acting as well as to dynamic (seismic) loads. The effects of the dynamic actions are studied on the grounds o…
Nonlocal properties of dynamical three-body Casimir-Polder forces
2005
We consider the three-body Casimir-Polder interaction between three atoms during their dynamical self-dressing. We show that the time-dependent three-body Casimir-Polder interaction energy displays nonlocal features related to quantum properties of the electromagnetic field and to the nonlocality of spatial field correlations. We discuss the measurability of this intriguing phenomenon and its relation with the usual concept of stationary three-body forces.
Dissimilar joining of copper to stainless steel and TA6V to stainless steel by high power beams : understanding and modeling of physicochemical pheno…
2010
The present study is dedicated to the comprehension of the mechanism of materials mixing during dissimilar welding by high power beam sources. We have been interested in joining of two couples of metallic materials which present different metallurgical problems: •copper- stainless steel (miscibility gap, important difference in physical properties);•TA6V- stainless steel (oxidation on air, formation of intermetallic phases which made the joint brittle).For the first couple of materials, continuous laser Nd:YAG welding and electron beam welding have been applied. The experimental study of morphology evolution, composition, microstructure and mechanical properties has allowed establishing the…
Carbonyl compounds of Rh, Ir, and Mt: electronic structure, bonding and volatility
2020
With the aim to render assistance to future experiments on the production and investigation of chemical properties of carbonyl compounds of element 109, Mt, calculations of the molecular properties of M(CO)4 and MH(CO)4, where M = Rh, Ir, and Mt, and of the products of their decomposition, M(CO)3 and MH(CO)3, were performed using relativistic Density Functional Theory and Coupled-Cluster methods implemented in the ADF, ReSpect and DIRAC software suites. According to the results, MH(CO)4 should be formed at experimental conditions from the M atom with a mixture of CO and He gases. The calculated first M–CO bond dissociation energies (FBDE) of Mt(CO)4 and MtH(CO)4 turned out to be significant…
Theoretical Study of the 15- and 17-Electron Structures of Cyclopentadienylchromium(III) and Cyclopentadienylmolybdenum(III) Complexes. Dichloride an…
1997
International audience; The structure and the energetics of the model systems CpMX2(PH3) + PH3 ⇄ CpMX2(PH3)2 (Cp = cyclopentadienyl; M = Cr, Mo; X = Cl, CH3) are studied by performing Møller−Plesset second order (MP2) and density functional theory (DFT) calculations. Extended basis sets are employed in the geometry optimizations. The results indicate that the structural preference can be traced back to the competition between electron pairing stabilization and M−P bond dissociation energy along the spin doublet surface. At all levels of calculation, the energy splitting, a measure of the cost of pairing the electron during the promotion process from the quartet ground state to the excited d…