Search results for "Diterpenoid"

showing 10 items of 22 documents

Biological Profiling of Semisynthetic C19-Functionalized Ferruginol and Sugiol Analogues

2021

[EN] The abietane-type diterpenoids are significant bioactive compounds exhibiting a varied range of pharmacological properties. In this study, the first synthesis and biological investigation of the new abietane-diterpenoid (+)-4-epi-liquiditerpenoid acid (8a) together with several of its analogs are reported. The compounds were generated from the readily available methyl callitrisate (7), which was obtained from callitrisic acid present in Moroccan Sandarac resin. A biological evaluation was conducted to determine the effects of the different functional groups present in these molecules, providing basic structure-activity relationship (SAR) elements. In particular, the ferruginol and sugi…

Microbiology (medical)Pharmacology.KetoneStereochemistryCarboxylic acidFarmacología.Antiproliferative activity01 natural sciencesBiochemistryMicrobiologyArticleAntimalarial activityHeLachemistry.chemical_compoundDiterpenoidMoiety03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edadesPharmacology (medical)General Pharmacology Toxicology and PharmaceuticsAbietanechemistry.chemical_classificationMalaria - Chemotherapy.biology010405 organic chemistryChemistrylcsh:RM1-950Sandaracbiology.organism_classificationGABA<sub>A</sub> receptor modulatorsTerpenoidCallitrisic acid0104 chemical sciencesFerruginol010404 medicinal & biomolecular chemistrylcsh:Therapeutics. PharmacologyInfectious DiseasesPaludismo - Farmacoterapia.AbietaneGABAA receptor modulators
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Neo-clerodane diterpenoids from Teucrium sandrasicum

1997

WOS: A1997XM24100019

Neo-Clerodane DiterpenoidsbiologyStereochemistryPlant ScienceGeneral MedicineLabiataeTeusandrins A-FHorticultureTeucrium Sandiasicumbiology.organism_classificationBiochemistryTeucriumchemistry.chemical_compoundOxetane DerivativeschemistryDiterpeneMolecular BiologyDerivative (chemistry)Phytochemistry
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Euphosantianane E–G: Three New Premyrsinane Type Diterpenoids from Euphorbia sanctae-catharinae with Contribution to Chemotaxonomy

2019

Euphorbia species were widely used in traditional medicines for the treatment of several diseases. From the aerial parts of Egyptian endemic plant, Euphorbia sanctae-catharinae, three new premyrsinane diterpenoids, namely, euphosantianane E&ndash

Pharmaceutical ScienceAgglomerative hierarchical clustering01 natural sciencesArticlepremyrsinane diterpenoidsAnalytical Chemistrylcsh:QD241-441TerpeneType (biology)lcsh:Organic chemistryEuphorbiaDrug DiscoveryPhysical and Theoretical ChemistryEuphorbiaMolecular StructurebiologyTraditional medicinePlant Extracts010405 organic chemistryOrganic ChemistryeuphorbiaceaeEuphorbiaceaeEuphorbia sanctae-catharinaePlant Components Aerialendemic plantchemotaxonomic significancebiology.organism_classificationAntineoplastic Agents Phytogenic0104 chemical sciences010404 medicinal & biomolecular chemistryChemistry (miscellaneous)Chemotaxonomyeuphosantianane E–G<i>Euphorbia sanctae-catharinae</i>Molecular MedicineEgyptDiterpenesDrug Screening Assays AntitumorMolecules
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The Diterpenoids from the Genus Hyptis (Lamiaceae)

2009

The genus Hyptis (family Lamiaceae) is known mainly for the essential oils isolated from the aerial parts of several species. Less known are the diterpenoids, extracted from a limited number of species. In consideration of the interest for the structures of this class of compounds, largely occurring in the whole Lamiaceae family, the present paper means to review and update their chemistry. Also the use of many species of Hyptis in folk-medicine is reported.

PharmacologyFamily LamiaceaebiologyHyptisOrganic ChemistrySettore CHIM/06 - Chimica Organicabiology.organism_classificationTerpenoidAnalytical ChemistryLabdanechemistry.chemical_compoundchemistryHyptis Lamiaceae diterpenoidsGenusBotanyLamiaceaeAbietaneHETEROCYCLES
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Advances on the chemistry of furano-diterpenoids from Teucrium genus

2005

This paper updates the previous reviews, reporting the results published in the last six years on the chemistry of these diterpenoids.

PharmacologyLamiaceaebiologyStereochemistryChemistryOrganic ChemistryneoclerodanediterpenoidGeneral Medicinefuroclerodanebiology.organism_classificationAnalytical ChemistryTeucriumTeucriumTerpeneGenusBotanyLamiaceae
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Cytotoxic properties of Marrubium globosum ssp. libanoticum and its bioactive components

2013

Marrubium globosum Montbr. et Auch. ex Benth. ssp. libanoticum Boiss. (Lamiaceae) is a medicinal plant used in Lebanon for the treatment of inflammatory diseases, asthma, coughs and other pulmonary and urinary problems. The goal of our study was to assess the biological activity of M. globosum by testing different extracts of the aerial parts for their antiproliferative activity against human melanoma cells using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. The chloroform fraction showed the greatest activity. The compounds isolated from the extracts were also tested: the mixture of (13 S)-9α,13α-epoxylabda-6β(19),16(15)-diol dilactone and (13 R)-9α,13α-epo…

PharmacologybiologyTraditional medicineChemistryCytotoxicityPlant ScienceGeneral MedicineSettore CHIM/06 - Chimica OrganicaMarrubium globosum Lebanon antiproliferative activitybiology.organism_classificationLabdane diterpenoidPhenolic compoundsComplementary and alternative medicineDrug DiscoveryMarrubium globosum libanoticumCytotoxic T cellSettore BIO/15 - Biologia FarmaceuticaMelanomaMarrubium
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Enzyme-catalysed transformations of ent-kaurane diterpenoids

2005

Several acetyl derivatives of linearol, atractyligenin and atractylitriol were obtained through enzyme-catalysed acetylation and deacetylation reactions. In most reactions lipases showed regio- and stereoselective behaviour, allowing a family of novel compounds to be prepared. Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos en Química Orgánica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Unidad de Microanálisis y Métodos Físicos en Química Orgánica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y …

Química OrgánicaACETYLATIONENZYME CATALYSISChemistryStereochemistryDEACETYLATIONOrganic ChemistryENT-KAURANESCiencias QuímicasDITERPENOIDSPhysical and Theoretical ChemistryEnt kauraneCIENCIAS NATURALES Y EXACTAS
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Cytotoxic activity of diterpenoids isolated from the aerial parts of Elaeoselinum asclepium subsp. meoides.

2008

The phytochemical investigation of the acetone extract of the aerial parts of Elaeoselinum asclepium (L.) Bertol. subsp. meoides (Desf.) Fiori afforded several known diterpenoids as well as meoidic acid ( 5), new in the literature. The cytotoxic activities of elasclepic acid ( 1), ENT-atis-16-en-19-oic acid ( 2), ent-beyer-15-en-19-oic acid ( 3), ent-kaur-16-en-19-oic acid ( 4) and meoidic acid ( 5) were investigated on rat glioma C6 cells by evaluation of cell growth inhibition.

StereochemistryElaeoselinum asclepium subsp. meoides Umbelliferae diterpenoids meoidic acid cytotoxic activityPharmaceutical ScienceBiologyPharmacognosyAnalytical Chemistrychemistry.chemical_compoundCell Line TumorDrug Discoveryotorhinolaryngologic diseasesAcetoneCytotoxic T cellAnimalsCytotoxicityCell ProliferationPharmacologyMolecular StructureOrganic ChemistrySettore CHIM/06 - Chimica OrganicaElaeoselinum asclepium subsp. meoidesAntineoplastic Agents PhytogenicTerpenoidRatsComplementary and alternative medicinechemistryPhytochemicalMolecular MedicineDiterpeneDiterpenesApiaceaePlanta medica
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Clerodane diterpenoids from Salvia splendens.

2006

Four new clerodane diterpenoids, salvisplendins A-D (1-4), have been isolated from an acetone extract of the flowers of SalVia splendens, together with an artifact (5), arising from salvisplendin D (4) by addition of diazomethane, and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and, in the case of salvisplendin A (1), by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6), not published hitherto, are also reported.

StereochemistryPharmaceutical ScienceFlowersSalviaAnalytical ChemistryDiterpenes Clerodanechemistry.chemical_compoundFour new clerodane diterpenoids salvisplendins A-D (1-4) have been isolated from an acetone extract of the flowers of SalVia splendens together with an artifact (5) arising from salvisplendin D (4) by addition of diazomethane and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and in the case of salvisplendin A (1) by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6) not published hitherto are also reportedDrug DiscoveryOrganic chemistrySalviaNuclear Magnetic Resonance BiomolecularPharmacologychemistry.chemical_classificationPlants MedicinalbiologyMolecular StructureChemistryDiazomethaneOrganic ChemistryCarbon-13 NMRbiology.organism_classificationChemical correlationTerpenoidComplementary and alternative medicineItalyMolecular MedicineDiterpeneTwo-dimensional nuclear magnetic resonance spectroscopyLactoneJournal of natural products
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An ent-kaurane from Sideritis huber-morathii

1996

WOS: A1996VW86500030

biologyStereochemistryS-CaesareaPlant ScienceGeneral MedicineHorticultureLabiataebiology.organism_classificationBiochemistryTerpenoidchemistry.chemical_compoundchemistrySideritis Huber-MorathiiSideritis3718-Triacetyl-FoliolDiterpeneMolecular BiologyEnt kauraneEnt-Kaurane Diterpenoids
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