Search results for "Eating"
showing 10 items of 1247 documents
Ligand substitution reactions of the [ReX6]2− (X=Cl, Br) anions. Synthesis and crystal structure of novel oxalato complexes of rhenium(IV)
2006
Abstract The reaction of K2[ReX6] (X = Cl, Br) with oxalic acid and triethylamine in dimethylformamide solution yields the substituted complexes [ReX4(ox)]2− and cis-[ReX2(ox)2]2−, which can be obtained separately depending on the amount of added amine. The crystal structures of (PPh4)2[ReBr4(ox)], cis-(PPh4)2[ReBr2(ox)2] and cis-(AsPh4)2[ReCl2(ox)2] have been determined by single-crystal X-ray diffraction. The anionic complexes are octahedral with only slight distortions. The direct isolation of the pure complexes as well as the formation of only the cis isomers – without the presence of trans isomers and/or [Re(ox)3]2− – is probably due to the kinetic inertness of Re(IV)–X bonds, which in…
Polyaza[n](1,4)naphthalenophanes and polyaza[n](9,10)anthracenophanes
2002
Abstract A series of polyaza[n](1,4)naphthalenophanes and polyaza[n](9,10)anthracenophanes have been prepared by using the Fukuyama's protecting group (2- or 4-nitrophenyl sulfonyl) in a one-pot cyclization–deprotection reaction. Global yields for the purified products are comparable with those obtained for other polyazacyclophanes using the tosyl group as the amine protecting group. Their structural study has been carried-out by NMR showing a high rigidity for the smaller cycles and a more dynamic behaviour for the largest member of the series. The free energy barrier for the rotational equilibrium for compound 25 is about 3 kcal/mol lower than that calculated for analogous N-tosylated mac…
Metastability and hysteresis of the vortex states in rotating superfluid3He-B
1996
We have investigated the vortex core transition in 3He-B by measuring the associated changes in mutual friction dissipation within the superfluid. If rotation is continuously stopped and restarted while cooling or warming then the transition occurs at a clearly defined temperature, but temperature sweeps during continuous rotation show substantial supercooling and superheating. Moreover, the high temperature vortex shows a continuum of metastable states when supercooled to a constant, arbitrary low temperature, the mutual friction dissipaton depending on the temperature at which rotation was started. Our current interpretation is that the high temperature vortex state is a temperature-depen…
Computer simulation of disordering and premelting of low-index faces of copper.
1992
Molecular dynamics and the effective-medium theory have been applied to investigate the structure and dynamics of (110), (100), and (111) faces of copper in the whole temperature range from 0 K up to the bulk melting point, which has been determined to be 1240\ifmmode\pm\else\textpm\fi{}25 K. The observed order in the surface stability follows the order in the packing density. (110) disorders first via anharmonic effects (up to 700 K), then by vacancy-adatom formation and finally by premelting of the surface at about 1200 K. The (110) solid-melt interface is anisotropic and broadened, having a tendency to form small fluctuating (111) facets in equilibrium, which is suggested to be the atomi…
Application of Thermographic Techniques for the Detection of Failures on Photovoltaic Modules
2019
The paper focuses on thermography as a useful investigation tool for diagnosis, detection and prevention of failures of photovoltaic modules. The paper describes the faults detectable by thermographic investigations and how to conduct these investigantions. Then the results of some analyses conducted on a photovoltaic field are presented. The investigations made possible to identify faulty modules with hot spots by measuring localized superheat due to the presence of concentrated deposits on the exposed surface of the module and the superheating due to the presence of sand/dust deposits distributed on a significant portion of the module surface. The thermographic investigations can be used …
Compréhension des processus cognitifs de traitement de l’information alimentaire chez des individus normo-pondéraux, en surpoids et en obésité : infl…
2020
Obesity has a multifactorial origin that implies biological, social, psychological, and environmental factors. Previous studies have shown that particular cognitive processing of food stimuli could contribute to the maintenance and development of obesity. This vulnerability was characterized by attentional biases (i.e. the tendency to automatically orient one’s attention) and a decreased inhibitory control (i.e. difficulties to control one’s cognitive processes) toward foods. This phenomenon may be reinforced by the obesogenic environment: an environment abundant in food and with a lack of options for physical exercise. Among the five studies presented in this work, we characterized olfacto…
Sustainable and cost-efficient energy supply and utilisation through innovative concepts and technologies at regional, urban and single-user scales
2019
Abstract The environmental impact of the energy sector and the security and economics of energy supply and utilisation have been raising increasing concerns, stimulating the search for innovative solutions for a sustainable use of resources. This article provides an overview of published research in this area, with a focus on papers contributed in special issues of leading journals dedicated to the series of Conferences on Sustainable Development of Energy, Water and Environment Systems (SDEWES), including the articles in the current special issue. Based on this review, research trends are identified and achievements supporting the energy transition are highlighted. The studies that focused…
Relationships between early flavor exposure, and food acceptability and neophobia
2016
Revue; In the first section of this chapter, an overview of what is known about early flavor exposure, distinguishing between taste and flavor (aroma) exposure is provided. In the second section, we will describe what has been researched regarding the influence of early flavor exposure on the development of food preference, looking at prenatal exposure, exposure received in the context of milk feeding and exposure received in the context of complementary feeding. The third section is a description of what has been shown regarding the relationships between early flavor exposure and food neophobia. The chapter ended with a comment on likely future trends, and by a description of sources of fu…
Overview of first Wendelstein 7-X high-performance operation
2019
Abstract The optimized superconducting stellarator device Wendelstein 7-X (with major radius , minor radius , and plasma volume) restarted operation after the assembly of a graphite heat shield and 10 inertially cooled island divertor modules. This paper reports on the results from the first high-performance plasma operation. Glow discharge conditioning and ECRH conditioning discharges in helium turned out to be important for density and edge radiation control. Plasma densities of with central electron temperatures were routinely achieved with hydrogen gas fueling, frequently terminated by a radiative collapse. In a first stage, plasma densities up to were reached with hydrogen pellet injec…
Ferrocene containing chelating ligands 3. Synthesis, spectroscopic characterization, electrochemical behaviour and interaction with metal ions of new…
1995
Abstract Ferrocenecarboxaldehyde reacts with 2-amino-benzoic acid, 2-amino-5-methyl-benzoic acid or 3-amino-2-naphthoic acid to give the corresponding Schiff-base derivatives 2-ferrocenylmethylidenimino-benzoic acid (1), 2-ferrocenylmethylidenimino-5-methyl-benzoic acid (2) and 3-ferrocenylmethylidenimino-2-naphthoic acid (3). 1, 2 and 3 are stable in the solid state but easily hydrolyze in solution. This hydrolysis has been studied kinetically in a methanol-water medium. In order to increase the stability in solution to use these compounds as ligands, the imino group from 1, 2 and 3 was reduced by NaBH4 to give the amino derivatives 2-ferrocenylmethylamino-benzoic acid (4), 2-ferrocenylmet…