Search results for "Engineering sciences"

NaCl induced corrosion of Ti-6Al-4V alloy at high temperature

2016

International audience; This paper presents a study on the Ti-6Al-4V behaviour in presence of NaCl deposit under dry and moistair environments at 560◦C. The results evidence a detrimental effect of the NaCl deposit with a synergisticeffect in presence of moist air environment. Treatments under dry and moist air with NaCl deposit for600 h, lead respectively to weight gains per unit area 5 and 15 times higher than observed under classicoxidation in dry air. Enhancement of the corrosion phenomenon is attributed to the presence of gaseousmetal chlorides, leading to the establishment of an active corrosion process.

Glovebox atmosphere detritiation process using gas separation membranes.

2003

Abstract The use of gas separation membranes in atmospheric detritiation systems has been studied. The main advantage of this new process is to reduce the number and/or the size of the equipment in comparison to conventional tritium removal systems. Owing to the constraints linked to tritium handling, the separation performances of several commercial hollow fiber organic membranes have been analyzed, under various operating conditions, with hydrogen/nitrogen or deuterium/nitrogen mixtures. The experiments are performed with small quantities of hydrogen or deuterium (5000 ppm). The experimental results allow to evaluate the separation efficiency of these membranes and to determine the approp…

Modulation of the organic heterojunction behavior, from electrografting to enhanced sensing properties

2019

International audience; The energy barrier of an organic heterojunction built on ITO electrodes and made from a low conductive sublayer (Cu(F16Pc)) covered by a highly conductive semiconductor (LuPc2) is modulated by electrografting of organic layers before depositing the sublayer. Impedance spectroscopy clearly demonstrates the increase of the energy barrier at the ITO – sublayer interface. Additionally, the electrografting is a versatile and promising method for the tuning of heterojunctions. The I(V) characteristics of the heterojunctions are highly modified by the electrografting. The same electromodifications of electrodes carried out on LuPc2 resistors lead to a modification of their …

Wood fiber orientation assessment based on punctual laser beam excitation: A preliminary study

2016

International audience; The EU imposes standards for the use of wood in structural applications. Local singularities such as knots affect the wood mechanical properties. They can be revealed by looking at the wood fiber orientation. For this reason, many methods were proposed to estimate the orientation of wood fiber using optical means, X-rays, or scattering measurement techniques. In this paper, an approach to assess the wood fiber orientation based on thermal ellipsometry is developed. The wood part is punctually heated with a Nd-YAG Laser and the thermal response is acquired by an infrared camera. The thermal response is elliptical due to the propagation of the heat through and along th…

Interdependence of structural and electrical properties in tantalum/tantalum oxide multilayers

2013

International audience; Dc reactive sputtering was used to deposit tantalum metal/oxide periodic nanometric multilayers using the innovative technique namely, the reactive gas pulsing process (RGPP). Different pulsing periods were used for each deposition to produce metal-oxide periodic alternations included between 5 and 80 nm. Structure, crystallinity and chemical composition of these films were systematically investigated by Transmission Electron Microscopy (TEM) and Energy-dispersive X-ray (EDX) spectroscopy techniques. Moreover, electrical properties were also studied by the Van der Pauw technique.

Structural and electrical properties in tungsten/tungsten oxide multilayers

2014

International audience; Tungsten and tungsten oxide periodic nanometric multilayers have been deposited by DC reactive sputtering using the reactive gas pulsing process. Different pulsing periods have been used for each deposition to produce metal-oxide periodic alternations ranging from 3.3 to 71.5 nm. The morphology, crystallinity and chemical composition of these films have been investigated by transmission electron microscopy and energy-dispersive X-ray spectroscopy techniques. The produced multilayers exhibited an amorphous structure and the composition stability of WO3 sub-layers has been pointed out. Moreover, electrical properties have also been studied by the van der Pauw technique…

Interface thermodynamic model for low pressure evaporation

1979

Evaluation of interfacial stress transfer efficiency by coating fragmentation test

2007

Probabilistic model of coating fragmentation under uniaxial tensile loading is developed. Analytical expressions of the crack spacing evolution are obtained for small-strain and large-strain fragmentation regimes. The model is applied for coating and interface property identification of several thin brittle coating/polymer substrate systems. An estimate of the stress transfer length, derived from the fragmentation data, is found to correlate with the interfacial shear strength thus suggesting that both parameters reflect an intrinsic property related to the mechanical efficiency of coating/substrate interface.

Nanophase Segregation of Self-Assembled Monolayers on Gold Nanoparticles

2017

International audience; Nanophase segregation of a bi-component thiol self-assembled monolayer is predicted using atomistic molecular dynamics simulations and experimentally confirmed. The simulations suggest the formation of domains rich in acid-terminated chains, on one hand, and of domains rich in amide-functionalized ethylene glycol oligomers, on the other hand. In particular, within the amide-ethylene glycol oligomers region, a key role is played by the formation of inter-chain hydrogen bonds. The predicted phase segregation is experimentally confirmed by the synthesis of 35 and 15 nm gold nanoparticles functionalized with several binary mixtures of ligands. An extensive study by trans…

Kerr beam self-cleaning in the telecom band

2019

Multimode graded index (GRIN) fibers received a renewed interest in recent years, in particular for the development of new laser sources [1]. In many cases, the use of GRIN fibers is limited by multimodal propagation, leading to a spatially modulated intensity distribution (speckles) at the fiber output. Recent studies have found that quasi-single mode propagation can be recovered in GRIN fibers by the so-called Kerr self-cleaning effect [2]. It consists in the spontaneous recovery of the spatial beam quality, without any frequency shift [2] (as opposed to, e.g., Raman beam self-cleaning [3]). This nonlinear process was only observed so far at laser wavelengths around 1 μm, for peak power l…