Search results for "Environmental Monitoring"

Fragmentations and reactions of the organophosphate insecticide Diazinon and its oxygen analog Diazoxon studied by electrospray ionization ion trap m…

2005

The fragmentations and reactions of Diazinon and related compounds have been studied by electrospray ionization ion trap mass spectrometry. Several novel fragmentation and rearrangements have been observed, including an intramolecular thiono-thiolo rearrangement. The stability, in the gas-phase, of the protomers of 2-isopropyl-4-methyl-6-pyrimidinol has been demonstrated. The complexity of the gas phase ion processes observed suggest that, at present, caution Should be exercised in using this approach for the analysis of environmental and other samples until our understanding of these processes increases considerably. (J Am Soc Mass Spectrom 2005, 16, 515-523) (c) 2005 American Society for …

Dispersive magnetic immunoaffinity extraction. Anatoxin-a determination.

2017

Specific monoclonal antibodies were coupled with magnetic Sepharose-based beads and used, for the first time. The methodology was applied to preconcentrate anatoxin-a from water and the later determination by ion mobility spectrometry (IMS). Dispersive magnetic immunoaffinity (d-MagIA) extraction methodology provided a limit of detection of 0.02μgL-1 and a satisfactory precision with a relative standard deviation lower than 15%. Recoveries were evaluated at 0.5, 1.0 and 5.0μgL-1 anatoxin-a with quantitative values from 91 to 115%. Additionally, isobaric interferences with phenylalanine were completely avoided by the use of the developed d-MagIA extraction coupled to IMS determinations.

History of bioavailable lead and iron in the Greater North Sea and Iceland during the last millennium – A bivalve sclerochronological reconstruction

2014

We present the first annually resolved record of biologically available Pb and Fe in the Greater North Sea and Iceland during 1040-2004 AD based on shells of the long-lived marine bivalve Arctica islandica. The iron content in pre-industrial shells from the North Sea largely remained below the detection limit. Only since 1830, shell Fe levels rose gradually reflecting the combined effect of increased terrestrial runoff of iron-bearing sediments and eutrophication. Although the lead gasoline peak of the 20th century was well recorded by the shells, bivalves that lived during the medieval heyday of metallurgy showed four-fold higher shell Pb levels than modern specimens. Presumably, pre-indus…

An environmental forensic procedure to analyse anthropogenic pressures of urban origin on surface water of protected coastal agro-environmental wetla…

2013

Detection and spatial distribution of 14 drugs of abuse and 17 pharmaceuticals in surface waters was investigated to determine transport hydrological connectivity between urban, agriculture and natural environments. Solid-phase extraction and liquid chromatography tandem mass spectrometry was applied to all samples. To determine spatial incidence of contaminants, analytical results of target compounds were georeferenced and integrated into a geographical information systems structure together with layers of municipal population, location of sewage water treatment plants and irrigation channels and sectors. The methodology was applied to L'Albufera Natural Park in Valencia (Spain). A total o…

Measurement of high order Kerr refractive index of major air components

2009

International audience; We measure the instantaneous electronic nonlinear refractive index of N2 , O2 , and Ar at room temperature for a 90 fs and 800 nm laser pulse. Measurements are calibrated by post-pulse molecular alignment through a polarization technique. At low intensity, quadratic coefficients n2 are determined. At higher intensities, a strong negative contribution with a higher nonlinearity appears, which leads to an overall negative nonlinear Kerr refractive index in air above 26 TW/cm2 .

Kodolspektroskopijas un beta radiometrijas rezultāti vides monitoringā Salaspils kodolreaktora apkārtnē (1966.g. līdz 1995.g.)

1998

Characterization of the main land processes occurring in Europe (2000-2018) through a MODIS NDVI seasonal parameter-based procedure

2021

Trabajo desarrollado bajo la financiación del proyecto “Soil Hydrology research platform underpinning innovation to manage water scarcity in European and Chinese cropping Systems” (773903), coordinado por José Alfonso Gómez Calero, investigador del Instituto de Agricultura Sostenible (IAS).

Time-domain based feature space at FLUXNET sites for vegetation patterns identification

2019

Monitoring the flux transfer of mass and energy occurring within the soil-plant-atmosphere continuum is a pivotal key for understanding hydrological and vegetation relationships. Average daily values of the Priestley - Taylor (PT) parameter were calculated for 4 eddy covariance (EC) flux tower sites from FLUXNET network, characterized by different vegetation features, over the 2010-12 reference period. Site-by-site feature spaces (built by difference in diurnal and night-time land surface temperature versus enhanced vegetation index, ΔLST-EVI) were obtained by combining satellite data (MODIS) and observed PT parameter (ϕ) retrieved by FLUXNET surface energy balance (SEB) fluxes. The results…

Rare earths, zirconium and hafnium distribution in coastal areas: The example of Sabella spallanzanii (Gmelin, 1791)

2016

The Zr, Hf, Y and lanthanide (REE) distribution in biological tissues of Sabella spallanzanii and Styela plicata species collected from two harbours from the northern Sicily is studied for providing information regarding the Zr, Hf and REE uptake from the environment. Previous studies determined the fractionation of dissolved REE scavenged on binding sites onto biological surfaces. By comparing the recognised shale-normalised REE patterns of studied samples with evidence from reference data, the observed behaviour of these elements in biological tissues of Sabella spallanzanii and Styela plicata is interpreted to result from the preferential uptake of intermediate REE onto carboxylic sites.…

Mercury concentration in lichen, moss and soil samples collected from the forest areas of Praded and Glacensis Euroregions (Poland and Czech Republic)

2011

The concentration of mercury was determined in samples of the lichen Hypogymnia physodes, the moss Pleurozium schreberi, and the soil humus collected in Polish and Czech Euroregions Praded and Glacensis. The sampling sites were located in Bory Stobrawskie, Bory Niemodlińskie and Kotlina Kłodzka in Poland, and in Jeseniki and Gory Orlickie in the Czech Republic. The mean concentrations of mercury accumulated in the lichen (0.129 mg g(-1)), in the moss (0.094 mg g(-1)) and in soil (0.286 mg g(-1)) were fairly close to the corresponding concentrations in other low-industrialized regions. The highest concentrations of mercury were observed in the lichen and the moss samples from Kotlina Kłodzka…