Search results for "Equilibrium"
showing 10 items of 1021 documents
Financial and fiscal shocks in the great recession and recovery of the Spanish economy
2020
In this paper we develop and estimate a new Bayesian DSGE model for the Spanish economy that has been designed to evaluate different structural reforms. The small open economy model incorporates a banking sector, consumers and entrepreneurs who accumulate debt, and a rich fiscal structure and monopolistic competition in products and labor markets, for a country in a currency union, with no independent monetary policy. The model can be used to evaluate ex-ante and ex-post policies and structural reforms and to decompose the evolution of macroeconomic aggregates according to different shocks. In particular, we estimate the contribution of financial and fiscal shocks to both the crisis of the …
A Novel Multi-step Finite-State Automaton for Arbitrarily Deterministic Tsetlin Machine Learning
2020
Due to the high energy consumption and scalability challenges of deep learning, there is a critical need to shift research focus towards dealing with energy consumption constraints. Tsetlin Machines (TMs) are a recent approach to machine learning that has demonstrated significantly reduced energy usage compared to neural networks alike, while performing competitively accuracy-wise on several benchmarks. However, TMs rely heavily on energy-costly random number generation to stochastically guide a team of Tsetlin Automata (TA) to a Nash Equilibrium of the TM game. In this paper, we propose a novel finite-state learning automaton that can replace the TA in TM learning, for increased determinis…
Floquet analysis of excitations in materials
2019
Abstract Controlled excitation of materials can transiently induce changed or novel properties with many fundamental and technological implications. Especially, the concept of Floquet engineering and the manipulation of the electronic structure via dressing with external lasers have attracted some recent interest. Here we review the progress made in defining Floquet material properties and give a special focus on their signatures in experimental observables as well as considering recent experiments realizing Floquet phases in solid state materials. We discuss how a wide range of experiments with non-equilibrium electronic structure can be viewed by employing Floquet theory as an analysis to…
Phonon Driven Floquet Matter.
2018
The effect of electron–phonon coupling in materials can be interpreted as a dressing of the electronic structure by the lattice vibration, leading to vibrational replicas and hybridization of electronic states. In solids, a resonantly excited coherent phonon leads to a periodic oscillation of the atomic lattice in a crystal structure bringing the material into a nonequilibrium electronic configuration. Periodically oscillating quantum systems can be understood in terms of Floquet theory, which has a long tradition in the study of semiclassical light-matter interaction. Here, we show that the concepts of Floquet analysis can be applied to coherent lattice vibrations. This coupling leads to p…
Monitoring Electron-Photon Dressing in WSe 2
2016
Optical pumping of solids creates a non-equilibrium electronic structure where electrons and photons combine to form quasiparticles of dressed electronic states. The resulting shift of electronic levels is known as the optical Stark effect, visible as a red shift in the optical spectrum. Here we show that in a pump-probe setup we can uniquely define a non-equilibrium quasiparticle bandstructure that can be directly measurable with photoelectron spectroscopy. The dynamical photon-dressing (and undressing) of the many-body electronic states can be monitored by pump-probe time and angular resolved photoelectron spectroscopy (tr-ARPES) as the photon-dressed bandstructure evolves in time dependi…
Floquet states in dissipative open quantum systems
2019
Abstract We theoretically investigate basic properties of nonequilibrium steady states of periodically-driven open quantum systems based on the full solution of the Maxwell–Bloch equation. In a resonant driving condition, we find that the transverse relaxation, also known as decoherence, significantly destructs the formation of Floquet states while the longitudinal relaxation does not directly affect it. Furthermore, by evaluating the quasienergy spectrum of the nonequilibrium steady states, we demonstrate that Rabi splitting can be observed as long as the decoherence time is as short as one third of the Rabi-cycle. Moreover, we find that Floquet states can be formed even under significant …
Continuous flow synthesis of amine oxides by oxidation of tertiary amines
2019
The synthesis of N-methylmorpholine N-oxide by oxidation of N-methylmorpholine with hydrogen peroxide was implemented in a microstructured reactor for increased safety and larger-scale applications. The active oxidant, peroxymonocarbonate HCO4− is formed in situ from the equilibrium reaction of hydrogen peroxide and bicarbonate. The bicarbonate can be induced by hydration of carbon dioxide. Elaborate studies on the influence of the catalyst concentration and temperature were carried out and the observed activation energy was determined. Elevated temperatures up to 60 °C and a carbon dioxide concentrations of 1 wt% led to a conversion for N-methylmorpholine of approximately 98% within 13.90 …
Local thermal non-equilibrium effects in the Darcy–Bénard instability of a porous layer heated from below by a uniform flux
2013
Abstract The influence of the lack of thermal equilibrium between the solid phase and the fluid phase on the convective instability in a porous medium is studied. A horizontal layer with parallel and impermeable bounding walls is considered. The lower wall is assumed to be isoflux, and the upper wall isothermal. The basic motionless state is perturbed with small-amplitude disturbances, so that a linear analysis of the instability is carried out with a streamfunction-temperature formulation of the local balance equations. Then, the governing equations are solved for the normal modes, leading to an eigenvalue problem for the neutral stability. This eigenvalue problem is solved analytically, t…
Retention-pH profiles of acids and bases in hydrophilic interaction liquid chromatography
2018
Abstract The high proportion of acetonitrile used in many HILIC mobile phases significantly changes the acid-base properties of pH buffers and analytes foreseen from available data in water. In this paper, the recommended stability pH range for chromatographic columns is examined with various acetonitrile/water mixtures, resulting in a significant broadening in the operational pH window with the content of organic solvent. Additionally, the challenge of buffer selection in HILIC is also addressed. Commonly used ammonium acetate shrinks its pH buffering range in acetonitrile-rich mobile phases due to variations in the dissociation constants of the buffer constituents (acetic acid and ammoniu…
Inter-Element Crack Propagation with High-Order Stress Equilibrium Element
2021
The present contribution proposes a formulation based on the use of hybrid equilibrium elements (HEEs), for the analysis of inter-element delamination and fracture propagation problems. HEEs are defined in terms of quadratic stress fields, which strongly verify both the homogeneous and inter-element equilibrium equations and they are employed with interfaces, initially exhibiting rigid behavior, embedded at the elements’ sides. The interface model is formulated in terms of the same degrees of freedom of the HEE, without any additional burden. The cohesive zone model (CZM) of the extrinsic interface is rigorously developed in the damage mechanics framework, with perfect adhesion at the pre-…