Search results for "FAVO"

showing 10 items of 136 documents

A Theoretical Study of the Favorskii Rearrangement. Calculation of Gas-Phase Reaction Paths and Solvation Effects on the Molecular Mechanism for the …

1997

The molecular mechanism of the α-chlorocyclobutanone transposition to yield cyclopropanecarboxylic acid, as a model of the Favorskii rearrangement, has been theoretically characterized in vacuo by means of ab initio molecular orbital procedures at the Hartree−Fock (HF) level of theory with the 6-31G* and 6-31+G* basis sets. The electron correlation has been estimated at the MP2/6-31G* level and calculations based on density functional theory, BLYP/6-31G*. The solvent effects are included at HF/6-31G* level by means of a polarizable continuum model. The questions related to the two accepted molecular mechanisms, the semibenzilic acid and the cyclopropanone transpositions, as well as the comp…

SolvationAb initioThermodynamicsGeneral ChemistryFavorskii rearrangementBiochemistryPolarizable continuum modelCatalysischemistry.chemical_compoundColloid and Surface ChemistrychemistryComputational chemistryCyclopropanoneMolecular orbitalDensity functional theorySolvent effectsJournal of the American Chemical Society

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Tacitus on Titus? Visit to the Temple of Venus at Paphos

2020

This article deals with Titus? visit to the temple of Venus at Paphos in the second book of Tacitus? Historiae. I argue that apart from its other literary intentions already mentioned by scholars, this digression implicitly connects Titus not only with Aeneas but also with Julius Caesar. Titus? affair with Berenice that recalls Caesar?s affair with Cleopatra, Tacitus? allusions to Lucan?s De Bello Civili where Caesar?s visit to the tomb of Alexander the Great is described, the ?????Motiv and fortuna?s favour that characterise both Roman generals, all contribute to connect Titus with Caesar and allow the reader to view a parallel between the Flavian and the Julio-Claudian dynasty. Furthermor…

Tacitus? allusions to Lucan?s De Bello Civili where Caesar?s visit to the tomb of Alexander the Great is describedall contribute to connect Titus with Caesar and allow the reader to view a parallel between the Flavian and the Julio-Claudian dynasty. FurthermoreUNESCO::CIENCIAS DE LAS ARTES Y LAS LETRASthe ?????Motiv and fortuna?s favour that characterise both Roman generals:CIENCIAS DE LAS ARTES Y LAS LETRAS [UNESCO]1135-9560 8276 Studia philologica valentina 567083 2020 22 7762316 Tacitus on Titus? Visit to the Temple of Venus at Paphos TzounakasSpyridon This article deals with Titus? visit to the temple of Venus at Paphos in the second book of Tacitus? Historiae. I argue that apart from its other literary intentions already mentioned by scholarsthe particular digression allows the historian to present certain aspects of his work and his historiographic practices and to reinforce his credibility. 103 114this digression implicitly connects Titus not only with Aeneas but also with Julius Caesar. Titus? affair with Berenice that recalls Caesar?s affair with Cleopatra

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La stereotomia nella cattedra di Architettura statica di Carlo Giachery

2014

La scuola di architettura di Palermo, sin dalla sua fondazione nel 1779, con la creazione della cattedra di Architettura civile affidata a Giuseppe Venanzio Marvuglia, era divenuta inevitabilmente il luogo di verifica e talvolta di esplorazione dei temi legati alla pratica professionale e, quindi, all’arte del costruire. Giachery, Professore di Architettura statica e civile dal 1837 al 1865, è il primo ad avvertire, da docente, la crisi profonda del sistema didattico della scuola di architettura di Palermo isterilita dalla ricerca di astratte idealità neoclassiche e straniatasi dal processo evolutivo della cultura architettonica europea dopo la morte dei “maestri” Marviglia e Gentile. Secon…

The School of Architecture of Palermo since its founding in 1779 with the creation of the chair of Civil Architecture entrusted to Joseph Venantius Marvuglia has become the place of testing exploration of issues related to professional practice and the art of building. Carlo Giachery Professor of Static and Civil Architecture from 1837 to 1865 is the first to feel the deep crisis of the educational system of the school of architecture of Palermo. For him architecture and applied sciences to architecture found in their stereotomy confirmation of the existence of correspondent relationships in their evolutionary process. The notion of stereotomy taken by Carlo Giachery in teaching reconnects directly to the noble art of coupe des pierres. Taken together the teaching aids used to show a theoretical advance that Giachery inclined in the direction of elasticity of the materials. Noting the outcomes of teaching his students have the clear perception of how the teaching on stereotomy is the compendium of all the French tradition on the subject. With the establishment of the School of Application for Engineers and Architects in 1866 the steretomia seems to gradually lose interest in favor of the prevailing metal construction. All the wisdom of build which for centuries had been linked with art de la coupe des pierres gave way to new construction techniques and new materials.Settore ICAR/14 - Composizione Architettonica E Urbana

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La scoperta, sistemazione e conservazione della grande Iscrizione di Gortina, nell'isola di Creta (1884-1921): la protezione delle testimonianze e le…

2013

La scoperta e la conservazione della Grande Iscrizione di Gortina a Creta, da parte degli studiosi italiani, fra la fine del XIX sec. e i primi decenni del XX sec., rappresentò un grande riconoscimento scientifico-culturale per la giovane nazione italiana. Nel passato, l’isola di Creta era stata legata alla Repubblica di Venezia e anche questo rapporto favorì l’invio a Creta del giovane epigrafista F. Halbherr, il quale fra notevoli peripezie rinvenne, assieme all’epigrafista tedesco E. Fabricius, la famosa l’iscrizione nell’antica città di Gortina. L’iscrizione, fra le più antiche e complete finora conosciute in tutta Europa, conteneva le norme sulla famiglia, l’eredità e in generale i dir…

The discovery and preservation of the Great Inscription of Gortyna in Crete by Italian researchers in the late nineteenth century. and the first decades of the twentieth century. was an important cultural and scientific recognition for the young Italian nation. In the past the island of Crete had been tied to the Republic of Venice and this report also favored sending in Crete the young epigraphist F. Halbherr who among considerable vicissitudes came to together to the epigraphist german E. Fabricius the inclusion of the famous ancient city of Gortyna. The inscription among the oldest and most comprehensive so far known throughout Europe the rules contained on the family's legacy in general and the rights and duties of some of the people of the Minoan civilization (480-450 BC). The inscription was carved on blocks organic limestone a restored ancient building which later in Roman times was turned into odeon. The Laws of Gortyn were engraved on the remains of the wall forming the passageway in front of the steps of the odeon. The essay traces the events that led to the discovery and subsequent storage made by Halbherr especially with the help of archaeologist L. Pernier and finally with the help of architect E. Stefani who designed a modern cover on the top of the ambulatory of the segments containing the inscription. This coverage was made to perform during the First World War on the basis of the Italian project from the Greek Government in order to protect the membership from possible war damage but especially from vandalism. The roof brick clay of the Laws of Gortyna still serves its function and ensures the use of the monument bearing witness to the preservation of Italian culture in Greece and more generally in the world. But in Sicily in the remains of the Villa del Casale in Piazza Armerina (Enna) its elegant protection (built in 1957) is representative of a whole period of culture of the Italian restoration is removed and replaced because it has not been able to make a ongoing maintenance is due. A bad example of conservation and management of a UNESCO monument from which arise after the work for the construction of new roofs an equally insulting to the archaeological heritage and scenic Italian and world.Settore ICAR/19 - Restauro

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Do Children Cooperate Conditionally?:Adapting the Strategy Method for First-Graders

2020

We develop a public goods game (PGG) to measure cooperation and conditional cooperation in young children. Our design addresses several obstacles in adapting simultaneous and sequential PGGs to children who are not yet able to read or write, do not possess advanced abilities to calculate payoffs, and only have a very limited attention span. It features the combination of haptic offline explanation, fully standardized audiovisual instructions, computerized choices based on touchscreens, and a suitable incentive scheme. Applying our experimental protocol to 129 German first-graders, we find that already 6-year-olds cooperate conditionally and that the relative frequency of different cooperati…

Value (ethics)Scheme (programming language)Organizational Behavior and Human Resource ManagementEconomics and EconometricsComputer scienceEconomicsPublic goods gameAttention span050105 experimental psychologyHuman–computer interaction0502 economics and businessPublic goods game0501 psychology and cognitive sciencesIn-group favoritism050207 economicsChildren/dk/atira/pure/core/keywords/557389186computer.programming_languageHaptic technologyProtocol (science)MeasurementGroup Identity05 social sciencesRevealed preferencesIncentiveIngroup biascomputerConditional cooperationStrategy method

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Temas e interpretaciones del derecho sucesorio italiano

2021

El articulo quiere mostrar que las interpretaciones de las instituciones del derecho de sucesiones que consideran el interés familiar, como expresión del principio de solidaridad (cada vez más en una protección patrimonialista de la legitimidad), siempre prevalente sobre todos los demás intereses, ya no pueden ser compartidas, porque la solidaridad no se distingue del personalismo. Modernizar el derecho de sucesiones no significa tener que abdicar en favor del contrato, sino descubrir el valor de la autonomía privada y el potencial del acto de última voluntad. Es la centralidad de la persona humana y no sólo el principio de solidaridad (más aún si se entiende en un sentido patrimonialista) …

Willpor lo tantoacto de última voluntadsino descubrir el valor de la autonomía privada y el potencial del acto de última voluntad. Es la centralidad de la persona humana y no sólo el principio de solidaridad (más aún si se entiende en un sentido patrimonialista) la clave a través de la cual el derecho de sucesión espera una relectura. Esto requiere el reconocimiento de la centralidad de la autonomía privada yTestamento; acto de última voluntad; acto mortis causa; contenido típico y atípico del testamento; legitimarios; legítima derechos fundamentales; dignidad de la persona; principio de solidaridad.siempre prevalente sobre todos los demás interesesporque la solidaridad no se distingue del personalismo. Modernizar el derecho de sucesiones no significa tener que abdicar en favor del contrato2070-8157 22082 Revista Boliviana de Derecho 584568 2021 32 8055226 Temas e interpretaciones del derecho sucesorio italiano BarbaTestamentofundamental rightsdignidad de la personaprincipio de solidaridadact of last willlegítima derechos fundamentales:CIENCIAS JURÍDICAS [UNESCO]ya no pueden ser compartidaslegitimated personscomo expresión del principio de solidaridad (cada vez más en una protección patrimonialista de la legitimidad)principle of solidarity 366 383legitimariosla centralidad del acto de última voluntadtypical and atypical content of the willUNESCO::CIENCIAS JURÍDICASlegitimateVincenzo El articulo quiere mostrar que las interpretaciones de las instituciones del derecho de sucesiones que consideran el interés familiarcomo instrumento para la realización de la dignidad de la persona. Testamentocontenido típico y atípico del testamentoact mortis causaacto mortis causadignity of the person

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L'Espagne des favoris (1598-1645). : Splendeurs et misères du valimiento.

2009

207 pages.; Le XVIIe siècle espagnol se caractérise par l'émergence des favoris, les validos, qui prennent en charge les affaires de la monarchie catholique. Après un XVIe siècle marqué para la consolidation du pouvoir royal et par le gouvernement de souverains à forte personnalité, une série de rois jeunes (Philippe III, Philippe IV et Charles II) dirige l'Espagne en s'appuyant sur des validos dont la légitimité politique repose sur l'amitié et la faveur du Prince. Les premières formulations de cette nouvelle pratique datent des années 1598-1645. C'est au cours de cette période, allant de la mort de Philippe II à celle du comte-duc d'Olivares et de Francisco de Quevedo, que naissent les pr…

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Dans l'intimité du Prince : les fondements de la privanza dans l'Espagne du XVIIe siècle

2012

Cet article aborde l'intimité du roi comme source et fondement de pouvoir. L'étude s'intéresse au ministre favori, figure politique qui apparaît au début du XVIIe siècle dans de nombreuses monarchies européennes. À travers le cas espagnol, sont abordées les pratiques et les représentations qui favorisent, tout en la justifiant, l'émergence du ministre privé. Le pouvoir de celui-ci est, en effet, d'autant plus étendu qu'il n'a d'autre légitimité que celle que lui confère le monopole de l'accès à l'intimité du Prince.

[SHS.LITT] Humanities and Social Sciences/Literaturedix-septième siècleministériat[SHS.LITT]Humanities and Social Sciences/Literatureamitié politiquemonarchie espagnole[ SHS.LITT ] Humanities and Social Sciences/LiteratureFavoripouvoir royal

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"...di anacronismi e favole tra tutti i romanzieri sono il più moderato". Su un romanzo storico di F. Milo Guggino

2007

L’analisi si concentra inizialmente sulle intenzioni programmatiche di F. Milo Guggino, autore di un romanzo storico, Luna e Perollo ovvero il Caso di Sciacca, pubblicato nel 1845. Maria Di Giovanna rintraccia alcune indicazioni di poetica fornite da Milo Guggino nelle quali lo scrittore dà visibilità al suo ‘patto’ con il lettore, chiarendo che, relativamente al rapporto storia-invenzione, egli preferisce restringere in maniera consistente gli spazi della libertà inventiva. L’indagine critica così verifica le concrete applicazioni di quel progetto romanzesco. Tra i vari aspetti del romanzo, studiati dalla Di Giovanna, un rilievo consistente assume poi il rapporto con le fonti storiche: ris…

anacronismi favole romanzieriSettore L-FIL-LET/10 - Letteratura Italiana

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Educación compensatoria : efectos recientes de un estudio clásico (High-Scope)

2014

Este artículo analiza dos estudios que prueban la tesis de que la educación de los desfavorecidos sociales en la edad temprana -3 y 4 años- merece la pena a corto y largo plazo. Para ello se analizan dos estudios preescolares complementarios –Perry y Curriculum -, de la Fundación High/Scope en los 60, evaluados en diversos momentos intermedios, el primero hasta alcanzar los 40 años y el segundo 23. Se describen los estudios y programas educativos, se analizan cuestiones metodológicas ligadas al seguimiento (muestra, validez, variables), se muestran los hallazgos, los tempranos específicamente escolares y otros de naturaleza distinta en la edad adulta. Finalmente se discute la modificabilida…

análisis de costo-beneficioDirect Instruction Nursery SchoolPreschool Curriculum Comparison Studyniño de primera infanciaCompensatory education; Preschool Curriculum Comparison Study; Direct Instruction Nursery School; High/Scope School ;Perry Preschool Study; Longitudi-nal studies; Disadvantaged children; Learning transfer; Cost-benefit analysePerry Preschool Studydesfavorecido socialEducationDisadvantaged childrenCost-benefit analyseCompensatory educationHigh/Scope Schooltransferencia del aprendizajeLearning transferLongitudi-nal studieseducación preescolar

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