Search results for "Ferro"

Syntheses and Structural Study of Novel Tetranuclear Bis(phenoxido)‐Bridged Cu II Metal–Organic Macrocycles

2012

Six new tetranuclear copper(II) complexes were prepared exploiting novel ditopic alkylenediamine-N,N,N′,N′-tetraphenolate ligands. The geometrical parameters of the compounds can be varied by introducing different solvents of crystallization into the lattice. The structures of all six complexes were determined from single-crystal X-ray diffraction analyses and the magnetic properties of the complexes were estimated by computational DFT calculations. The relationship between the magnetic exchange coupling constant (J) and the Cu–O–Cu angle (θ) in these bis(phenoxido)-bridged complexes was investigated and a magnetostructural correlation was established between J and the θ angle. All studied …

A new tetranuclear defective dicubane azide-bridged cobalt(II) complex

2013

Abstract The new tetranuclear cobalt(II) complex with formula [Co4(N3)8(4,5-diazafluoren-9-one)4] (1) is reported. Complex 1 is a cobalt(II) defective dicubane azide-bridged compound showing only azido bridging ligands in the μ1,1– and μ1,1,1– coordination modes. The magnetic properties of 1 are reported. Magnetic susceptibility measurements indicate ferromagnetic coupling. The magnetic data have been fitted to 2 K by considering two different superexchange coupling constants. The out-of-phase signal χM″ displays frequency-dependence below approximately 9 K.

Lateral indirect exchange coupling in a two-dimensional nanostripe array

2002

We observe a lateral indirect exchange coupling in a multistripe system of parallel Fe nanostripes grown by self-organized growth on a vicinal single-crystal W(110) surface. The width and the distance between the stripes of monolayer height were modified via the total amount of deposited Fe. The easy axis of the magnetization lies perpendicular to the stripe edges and in the surface plane, thus resulting in a ferromagnetic dipolar coupling. In addition to the dipolar coupling we observe an antiferromagnetic indirect exchange coupling for the nanostripe system covered by Au. The coupling causes a superferromagnetic phase transition in the nanostripe array.

Thermal gating of magnon exchange in magnetic multilayers with antiferromagnetic spacers

2020

We observe a strong thermally-controlled magnon-mediated interlayer coupling of two ferromagnetic layers via an antiferromagnetic spacer in spin-valve type trilayers. The effect manifests itself as a field-induced coherent switching of the two ferromagnets, which can be controlled by varying temperature and the spacer thickness. We explain the observed behavior as due to a strong hybridization of the ferro- and antiferro-magnetic magnon modes in the trilayer at temperatures just below the N\'eel temperature of the antiferromagnetic spacer.

A Tetrameric Nickel(II) “Chair” with both Antiferromagnetic Internal Coupling and Ferromagnetic Spin Alignment

2001

Spin-Wave Driven Bidirectional Domain Wall Motion in Kagome Antiferromagnets

2021

We predict a mechanism to controllably manipulate domain walls in kagome antiferromagnets via a single linearly polarized spin-wave source. We show by means of atomistic spin dynamics simulations of antiferromagnets with kagome structure that the speed and direction of the domain wall motion can be regulated by only tuning the frequency of the applied spin-wave. Starting from microscopics, we establish an effective action and derive the corresponding equations of motion for the spin-wave-driven domain wall. Our analytical calculations reveal that the coupling of two spin-wave modes inside the domain wall explains the frequency-dependent velocity of the spin texture. Such a highly tunable sp…

Ferromagnetic Coupling through Spin Polarization in a Dinuclear Copper(II) Metallacyclophane.

2001

[DT] Von organischen Radikalen zu Metallkomplexen konnte das bekannte Konzept für Ferroelektrika erfolgreich ausgedehnt werden: Die Abbildung zeigt ein Cyclophan-artiges Molekül mit einem Triplett-Grundzustand, in dem zwei CuII-Zentren von einem doppelten m-Phenylendiamid-Gerüst zusammengehalten werden.

Comparison between bitumen modified with crumb tyre rubber and styrene butadiene styrene

2009

The improvements in terms of mechanical properties due to the use of polymers to modify bitumens in road paving applications have already been widely demonstrated. The aim of this paper is to show how the rheology and the performance of a bituminous binder mixed with crumb rubber recycled from used tyres (CR-MB), could be comparable with a styrene butadiene styrene (SBS-MB) created with the same base binder and currently used for road applications. Physical, chemical and performance characterization followed by rheological and storage stability analyses have been undertaken as the basis for the comparison. The results of the investigation indicate that the blended CR-MB shows large improvem…

Analytical approach for the mix design optimisation of bituminous mixtures with crumb rubber

2018

The present paper provides a basis for defining a mix design method specifically tailored to rubberised asphalt that takes into account the behaviour of crumb rubber. An analytical approach to quantifying the recovered deformation of crumb rubber in the post-compaction phase has been developed in order to adjust the number of gyrations proposed by the Superpave method for compacting specimens of hot mix asphalt using a Superpave gyratory compactor. The maximum allowable amount of rubber has been calculated. Finally, a step-by-step protocol has been proposed in order to fabricate and compact crumb rubber modified mixtures with the gyratory compactor.

Increased Stability of Rubber-Modified Asphalt Mixtures to Swelling, Expansion and Rebound Effect during Post-Compaction

2017

The application of bituminous mixtures modified with rubber from scrap-tires require attention and care during mixing and compaction. Rubber modifies the properties because it reacts in the internal structure of bitumen at high temperatures changing the performance of the mixture (interaction process of solvents with binder-rubber aggregate). The main change is the increasing of the viscosity and elasticity of the binder due to the larger sizes of the rubber particles by dry process but, this positive effect is counteracted by short mixing times, compared to wet technology, and due to the transport processes, curing time and post-compaction of the mixtures. Therefore, negative effects as sw…