Search results for "Frenkel defect"
showing 5 items of 15 documents
Influence of complex impurity centres on radiation damage in wide-gap metal oxides
2016
Different mechanisms of radiation damage of wide-gap metal oxides as well as a dual influence of impurity ions on the efficiency of radiation damage have been considered on the example of binary ionic MgO and complex ionic–covalent $Lu_{3}Al_{5}O_{12}$ single crystals. Particular emphasis has been placed on irradiation with $\sim$2 GeV heavy ions ($^{197}Au, ^{209}Bi, ^{238}U$, fluence of 10$^{12}$ ions/cm$^{2}$) providing extremely high density of electronic excitations within ion tracks. Besides knock-out mechanism for Frenkel pair formation, the additional mechanism through the collapse of mobile discrete breathers at certain lattice places (e.g., complex impurity centres) leads to the c…
The kinetics of defect accumulation under irradiation: many-particle effects
1993
The kinetics of Frenkel defect accumulation under permanent particle source (irradiation) is discussed with special emphasis on many-particle effects. Defect accumulation is restricted by their diffusion and annihilation, A + B → 0, if the relative distance is less than the critical distance r0. A novel formalism of many-point particle densities based on Kirkwood's superposition approximation is developed to take into account aggregation of similar defects (A−A, B−B). The dependence of the saturation concentration after a prolonged irradiation upon spatial dimension ( = 1, 2, 3), defect mobility and the initial correlation within geminate pairs is analyzed. It is shown that the defect conce…
Intrinsic stability of quasicrystals under the generation of Frenkel pairs
2015
Under irradiation metastable quasicrystals undergo a phase transition to an amorphous state. This transition can be reversed by annealing. As in normal crystalline materials the phase transition is considered to be triggered by generation and recombination of vacancies and interstitial atoms (Frenkel pairs). We have classified the possible Frenkel defects in a metastable monatomic quasicrystal with respect to geometric and energetic properties. With numerical simulation we have studied the behaviour of the quasicrystal under a load of Frenkel defects for various defect concentrations. We find three ranges of behaviour: up to 5% defects per atom the structure remains icosahedral, in a middle…
Luminescence of biexcitons in silver halide crystals
1998
Abstract As it is known from Urbach rule, free excitons defining the fundamental absorption edge in AgBr 1 − x Cl x (0 ⩽ x ⩽ 1). The process of primary Frenkel defect creation which involves free exciton states even in AgCl and biexciton creation in AgCl are discussed. The fast luminescence band at ≈3.0 eV observed in AgCl under high-density pulsed electron beam and laser excitation has been studied. It is shown that its intensity is a non-linear function of the excitation density. We suggest that the fast luminescence comes from biexcitons; binding energies of such biexcitons in AgBr 1 − x Cl x (0 ⩽ x ⩽ 1) are estimated.
Luminescent detectors of ionising radiation
2003
Abstract At present in slow neutron imaging an active layer of an imaging plate IP contains a mixture of storage phosphors, usually BaFBr:Eu 2+ used for imaging of X-rays, and a neutron converter material, usually Gd 2 O 3 , LiF. A novel Li-containing luminescent material perspective for a direct neutron conversion and storage is discussed. Irradiation of LiBaF 3 crystals results in generation of Frenkel defect pairs and creation of F-type centres responsible for three absorption bands in UV-and visible spectral region. Because photo-stimulation in each of these absorption bands leads to bleaching of induced absorption, the F-type colour centres are convenient for storage of radiation dose.…