Search results for "GC-MS"

Chemical characterization of organic residues on Late Roman amphorae from shipwrecks off the coast of Marsala (Trapani, Italy)

2021

Abstract Organic residues were extracted from thirty-three different types of Roman and Late Antique amphorae retrieved from underwater contexts in the custody of the Archaeological Museum “Baglio Anselmi” of Marsala in Sicily. The samples were analysed using GC-MS and 1H NMR, finding biomarkers of plant oils (including saturated and unsaturated fatty acids, alcohols and alkanes present in plant waxes) were identified in seven samples. The biomarkers for Pinaceae spp., used for making pitch, were identified in one sample. The results obtained shed light on the function of different types of North African amphorae, traditionally interpreted as containers for olive oil, wine and fish sauce, p…

Chemical and Microbiological Characterization for PDO Labelling of Typical East Piedmont (Italy) Salami

2015

This study is focused on the characterisation of typical salami produced in Alessandria province (North West of Italy). Seventeen small or medium salami producers from this area were involved in the study and provided the samples investigated. The aim is double and consists in obtaining a screening of the characteristics of different products and following their evolution along ripening. The study involved five types of typical salami that were characterised for aroma components and nutritional features. This approach could provide a basis for a possible PDO or PGI label request. Principal Component Analysis and cluster analysis were used as multivariate statistical tools for data treatment…

GENE CLONING AND CHRACTERIZATION OF AN ALKANE HYDROXYLASE SYSTEM IN A LONG CHAIN N.ALKANE. DEGRADER GORDONIA SP.

2008

Volatile components of Centaurea bracteata and C. pannonica subsp. pannonica growing wild in Croatia.

2010

This paper reports on the volatile components of oils from the aerial parts (CBA) and roots (CBR) of Centaurea bracteata Scop. and aerial parts of C. pannonica (Heuffel) Simonkai subsp. pannonica (CPA), two Asteraceae growing wild in Croatia. The volatile components, obtained by hydrodistillation, were determined by GC-MS analysis. The yields (w/w) of the dried oils were 0.10% (CBA), 0.22% (CBR) and 0.09% (CPA), respectively. A total of 91 compounds were identified accounting for 91.1%, 93.3% and 87.9% of the total oil for CBA, CBR and CPA, respectively. All the samples were characterized mainly by hydrocarbons (7.1-34.1%), fatty acids (9.7-45.9%), and oxygenated sesquiterpenes (15.2-16.6%)…

Volatile components from aerial parts of centaurea spinosociliata seenus ssp. Cristata (Bartl.) Dostál and centaurea spinosociliata seenus ssp. spino…

2010

The paper reports on the volatile components oil from aerial parts of two Asteraceae growing wild in Croatia: Centaurea spinosociliata ssp. cristata (syn. Centaurea cristata Bartl. subsp. rabenhorstiana (Sch.Bip.) Nyman) (CSC) and C. spinosociliata ssp. spinosociliata (CSS). The volatile components were obtained by hydrodistillation from selected plants and were determined by the GC-MS system on two fused-silica capillary columns of different polarity. The oil content was 0.08 % (CSC) and 0.07 % (CSS) on a dry weight basis. Altogether 73 compounds were identified accounting for 90.8 % (CSC) and 92.8 % (CSS) of the total oil, that were characterized mainly by hydrocarbons (37.9 %; 30.4 %), s…

Evaluation of the representativeness of the odor of beer extracts prior to analysis by GC eluate sniffing

1993

The importance of obtaining and proving that the odor of an extract is representative of the odor of the original product from which it was obtained, before analysis by GC-FID, GC-MS, or GC sniff, is discussed. The sensory methods, such as triangle tests, matching tests, and quantitative analysis, used to determine the representativeness of the odor of an extract are described. Beer extracts obtained by three methods were used to illustrate the interest of the sensory tests. A method using a mixture of XAD resins was proved by sensory analysis to give some extracts with sensory characteristics representative of the particular beers from which they were obtained

Antiproliferative activity of hexane extract from Tunisian Cistus libanotis, Cistus monspeliensis and Cistus villosus

2013

Abstract Background As a part of our investigation on Tunisian medicinal plants, we have carried out a phytochemical investigation of the hexane extracts from leaves of Cistus libanotis, C. villosus and C. monspeliensis, evualuating also their possible antiproliferative activity in vitro. Results The major compounds of hexane extracts were identified and quantified by GC-MS. The composition of the three species, although belonging to the same genus, is completely different. The antiproliferative activity was evaluated against murine monocyte/macrophages (J774.A1), human melanoma cells (A-375), and human breast cancer cells (MCF-7), showing major activity against the human melanoma cell line…

Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments.

2012

This paper describes a work aimed at improving the conditions of an extraction method, coupling GC-MS determination, for the analysis without cleanup phase, of polycyclic aromatic hydrocarbons (PAHs) from sediment samples. The automatic Soxhlet extraction in warm mode (using Extraction System B-811 Standard, Buchi) has demonstrated advantages for automation, reduced extraction time, and lower solvent use than for conventional Soxhlet extraction. Under these conditions, the recoveries are very good as they resulted greater than 85 % and, in most of the cases, near 100 %. The repeatability is also satisfactory (relative standard deviation less than 15 %). The detection limits are also accepta…

Degradation of long-chain n-alkanes in soil microcosms by two actinobacteria

2012

The ability of two recently isolated actinobacteria, that degrade medium and long chain n-alkanes in laboratory water medium, was investigated in soil microcosms using different standard soils that were artificially contaminated with n-alkanes of different length (C(12)- C(20)- C(24)- C(30)). The two strains, identified as Nocardia sp. SoB and Gordonia sp. SoCp, revealed a similar high HC degradation efficiency with an average of 75% alkane degraded after 28 days incubation. A selectivity of bacteria towards n-alkanes of different length was detected as well as a consistent effect of soil texture and other soil physical chemical characteristics on degradation. It was demonstrated the specif…

Exploring the chemical diversity of essential oils in Armenian markets: a comprehensive analysis of composition profiles

2023

Due to its location at the convergence of multiple biogeographical regions, Armenia experiences significant variations in climate and soil conditions, resulting in a diverse range of plant chemotypes. However, there has been a lack of recent reports on the biological activity of plants found in Armenia's flora. There are few with well-described essential oil profiles, despite the vast biodiversity of Armenian flora. This study aimed to analyse the chemical composition of essential oils used by the population and found in the Armenian market. Unfortunately, only essential oils of foreign origin can be found, like Russia. Three essential oils of Lavandula angustifolia, Abies sibirica, and Ros…