Search results for "Geochemistry"
showing 10 items of 2967 documents
Natural gas hydrate investigations by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM)
2008
[1] We report the 3D microstructure analyses of natural gas hydrates sampled from Gulf of Mexico. The samples were characterized by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM) using the ‘TOMCAT’ beam line at the Swiss Light Source (SLS). The SRXCTM demonstrates its applicability to unlock some microscopic features of the marine hydrates, in particular of crystallite size and grain boundary network. The gas hydrate domains are surrounded by a network of pores of typically a few micrometers, which are largely due to decomposition. Out of the SRXCTM data, the porosity, total volume of the voids, the void surface area and number of the total gas-filled voids have been calcu…
Software development and its description for Geoid determination based on Spherical-Cap-Harmonics Modelling using digital-zenith camera and gravimetr…
2017
Over several years the Institute of Geodesy and Geoinformatics (GGI) was engaged in the design and development of a digital zenith camera. At the moment the camera developments are finished and tests by field measurements are done. In order to check these data and to use them for geoid model determination DFHRS (Digital Finite element Height reference surface (HRS)) v4.3. software is used. It is based on parametric modelling of the HRS as a continous polynomial surface. The HRS, providing the local Geoid height N, is a necessary geodetic infrastructure for a GNSS-based determination of physcial heights H from ellipsoidal GNSS heights h, by H=h-N. The research and this publication is dealing…
Decrespignyite-(Y), a new copper yttrium rare earth carbonate chloride hydrate from Paratoo, South Australia
2002
AbstractDecrespignyite-(Y) is a new copper yttrium rare earth carbonate chloride hydrate from the Paratoo copper mine, near Yunta, Olary district, South Australia. Decrespignyite-(Y) occurs as blue crusts, coatings and fillings in thin fissures on the slatey country rock. Individual pseudohexagonal platelets are typically 10–50 µm in maximum dimension and are often curved. Associated minerals include caysichite-(Y), donnayite-(Y), malachite and kamphaugite-(Y). Electron microprobe and CHN analyses gave: Y2O3 42.2; La2O3 0.1; Pr2O3 0.1; Nd2O3 1.3; Sm2O3 1.0; Gd2O3 4; Tb2O3 0.4; Dy2O3 3.7; Ho2O3 2.6; Er2O3 2.5; CaO 0.5; CuO 10.9; Cl 3.0; CO2 19.8; H2O 10.8, yielding an empirical formula of (Y…
Numerical modelling of magma dynamics coupled to tectonic deformation of lithosphere and crust
2013
Many unresolved questions in geodynamics revolve around the physical behaviour of the two-phase system of a silicate melt percolating through and interacting with a tectonically deforming host rock. Well-accepted equations exist to describe the physics of such systems and several previous studies have successfully implemented various forms of these equations in numerical models. To date, most such models of magma dynamics have focused on mantle flow problems and therefore employed viscous creep rheologies suitable to describe the deformation properties of mantle rock under high temperatures and pressures. However, the use of such rheologies is not appropriate to model melt extraction above …
Implementation of a comprehensive ice crystal formation parameterization for cirrus and mixed-phase clouds in the EMAC model (based on MESSy 2.53)
2018
A comprehensive ice nucleation parameterization has been implemented in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations (ICNCs). The parameterization of Barahona and Nenes (2009, hereafter BN09) allows for the treatment of ice nucleation taking into account the competition for water vapour between homogeneous and heterogeneous nucleation in cirrus clouds. Furthermore, the influence of chemically heterogeneous, polydisperse aerosols is considered by applying one of the multiple ice nucleating particle parameterizations which are included in BN09 to compute the heterogeneously formed ice crystals. BN09 has been modified in order to co…
Aseismic strain episodes at Campi Flegrei Caldera, Italy
2021
Since 2004 a research project has been developed to monitor subsurface deformation of Italian volcanoes using borehole strainmeters and long-baseline tiltmeters. Six Sacks-Evertson dilatometers were installed around Campi Flegrei caldera and Vesuvius during 2004–2005 (Scarpa et al., 2007), and in 2008 these instruments were supplemented by two arrays of 28–280 m long water-tube tiltmeters in underground tunnels. Relevant strainmeter and tiltmeter data have been collected and analysed from the instruments installed near Campi Flegrei caldera during the recent unrest episodes. In the period 2004–2005 strain, tilt and GPS data from Campi Flegrei indicate the onset of surface deformation that a…
Effect of the Ordovician paleogeography on the (in)stability of the climate.
2014
The Ordovician Period (485–443 Ma) is characterized by abundant evidence for continental-sized ice sheets. Modeling studies published so far require a sharp CO2 drawdown to initiate this glaciation. They mostly used non-dynamic slab mixed-layer ocean models. Here, we use a general circulation model with coupled components for ocean, atmosphere, and sea ice to examine the response of Ordovician climate to changes in CO2 and paleogeography. We conduct experiments for a wide range of CO2 (from 16 to 2 times the preindustrial atmospheric CO2 level (PAL)) and for two continental configurations (at 470 and at 450 Ma) mimicking the Middle and the Late Ordovician conditions. We find that the temper…
Holocene climate variability in north-eastern Italy: potential influence of the NAO and solar activity recorded by speleothem data
2012
Abstract. Here we present high-resolution stable isotope and lamina thickness profiles as well as radiocarbon data for the Holocene stalagmite ER 76 from Grotta di Ernesto (north-eastern Italy), which was dated by combined U-series dating and lamina counting. ER 76 grew between 8 ka (thousands of years before 2000 AD) and today, with a hiatus from 2.6 to 0.4 ka. Data from nine meteorological stations in Trentino show a significant influence of the North Atlantic Oscillation (NAO) on winter temperature and precipitation in the cave region. Spectral analysis of the stable isotope signals of ER 76 reveals significant peaks at periods of 110, 60–70, 40–50, 32–37 and around 25 a. Except for the …
Thermal and structural modeling of the Scillato wedge-top basin source-to-sink system. Insights into the Sicilian fold-and-thrust belt evolution (Ita…
2019
AbstractTemperature-dependent clay mineral assemblages, vitrinite reflectance, and one-dimensional (1-D) thermal and three-dimensional (3-D) geological modeling of a Neogene wedge-top basin in the Sicilian fold-and-thrust belt and its pre-orogenic substratum allowed us to: (1) define the burial history of the sedimentary succession filling the wedge-top basin and its substratum, (2) reconstruct the wedge-top basin geometry, depocenter migration, and sediment provenance through time in the framework of a source-to-sink system, and (3) shed new light into the kinematic evolution of the Apennine-Maghrebian fold-and-thrust belt.The pre-orogenic substratum of the Scillato basin shows an increase…
Phase equilibrium constraints on pre-eruptive conditions of recent felsic explosive volcanism at Pantelleria Island, Italy.
2010
International audience; We present experimental phase equilibria carried out on a pantelleritic bulk-rock composition with a peralkalinity index [PI = molar (Na2O + K2O)/Al2O3] = 1*4, which is representative of the most energetic pumice fall eruption of the resurgent post-caldera volcanism on Pantelleria island. For the explored conditions (P = 25-150 MPa; T = 680-800°C; H2Omelt up to 6 wt %; fO2 ≤ NNO, where NNO is nickel-nickel oxide buffer) clinopyroxene is the liquidus phase followed by alkali feldspar and then quartz. The crystallization of amphibole is limited to temperatures below 700°C. Aenigmatite crystallizes near the liquidus for P ≥ 100 MPa. When clinopyroxene is the sole liquid…