Search results for "Glass"
showing 10 items of 1153 documents
The Ultimate Fate of Supercooled Liquids
2010
In recent years it has become widely accepted that a dynamical length scale {\xi}_{\alpha} plays an important role in supercooled liquids near the glass transition. We examine the implications of the interplay between the growing {\xi}_{\alpha} and the size of the crystal nucleus, {\xi}_M, which shrinks on cooling. We argue that at low temperatures where {\xi}_{\alpha} > {\xi}_M a new crystallization mechanism emerges enabling rapid development of a large scale web of sparsely connected crystallinity. Though we predict this web percolates the system at too low a temperature to be easily seen in the laboratory, there are noticeable residual effects near the glass transition that can account …
Heterogeneity at the glass transition: what do we know?
2002
We critically discuss the information that can be obtained from experiments with respect to the existence, the life time, and the length scale of dynamical heterogeneity in glass-forming liquids. The ability to select a dynamically distinguishable subensemble and observe its return to the full equilibrium ensemble is illustrated by examples from multi-dimensional NMR. We also discuss non-resonant hole burning spectroscopy as an example for which two separate time scales are involved.
Nanoscale heterogeneity if glass-forming liquids: experimental advances
1998
Abstract Recent evidence indicates that in supercooled liquids the cooperativity of molecular motion extends over certain temporal and spatial ranges. A key advance is the experimental and theoretical exploration of higher-order correlation functions that can track the molecular coordinates for more than just two points in time or space. Uncontested experimental determinations of the heterogeneity length scale at the glass transition remain a major goal.
Spatial correlations of mobility and immobility in a glass-forming Lennard-Jones liquid
1998
Using extensive molecular dynamics simulations of an equilibrium, glass-forming Lennard-Jones mixture, we characterize in detail the local atomic motions. We show that spatial correlations exist among particles undergoing extremely large (``mobile'') or extremely small (``immobile'') displacements over a suitably chosen time interval. The immobile particles form the cores of relatively compact clusters, while the mobile particles move cooperatively and form quasi-one-dimensional, stringlike clusters. The strength and length scale of the correlations between mobile particles are found to grow strongly with decreasing temperature, and the mean cluster size appears to diverge near the mode-cou…
Dynamical phase transitions and their relation to structural and thermodynamic aspects of glass physics.
2020
We review recent developments in structural–dynamical phase transitions in trajectory space based on dynamic facilitation theory. An open question is how the dynamic facilitation perspective on the glass transition may be reconciled with thermodynamic theories that posit collective reorganization accompanied by a growing static length scale and, eventually, a vanishing configurational entropy. In contrast, dynamic facilitation theory invokes a dynamical phase transition between an active phase (close to the normal liquid) and an inactive phase, which is glassy and whose order parameter is either a time-averaged dynamic or structural quantity. In particular, the dynamical phase transition in…
Microwave surface impedance of proximity-coupled superconducting (Nb)/spin-glass (CuMn) bilayers
1998
The surface impedance of Nb/CuMn (superconducting/spin-glass) bilayers has been measured at 10 GHz with the parallel plate resonator technique to obtain information about the exotic behavior of the order parameter in superconducting/magnetic proximity systems. The data strongly differs from the superconducting/normal-metal case, showing the magnetic nature of the CuMn layer, which acts as a weak ferromagnet. The results are described in the framework of two models for the electrodynamics of superconducting/ferromagnetic (S/M) bilayers characterized by a proximity-coupling length scale which is independent of temperature.
Residual Stresses in Glasses
2013
The history dependence of the glasses formed from flow-melted steady states by a sudden cessation of the shear rate $\dot\gamma$ is studied in colloidal suspensions, by molecular dynamics simulations, and mode-coupling theory. In an ideal glass, stresses relax only partially, leaving behind a finite persistent residual stress. For intermediate times, relaxation curves scale as a function of $\dot\gamma t$, even though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this history dependence of glasses sharing the same thermodynamic state variables, but differi…
Short-term occupations at high elevation during the Middle Paleolithic at Kalavan 2 (Republic of Armenia).
2021
The Armenian highlands encompasses rugged and environmentally diverse landscapes and is characterized by a mosaic of distinct ecological niches and large temperature gradients. Strong seasonal fluctuations in resource availability along topographic gradients likely prompted Pleistocene hominin groups to adapt by adjusting their mobility strategies. However, the role that elevated landscapes played in hunter-gatherer settlement systems during the Late Pleistocene (Middle Palaeolithic [MP]) remains poorly understood. At 1640 m above sea level, the MP site of Kalavan 2 (Armenia) is ideally positioned for testing hypotheses involving elevation-dependent seasonal mobility and subsistence strateg…
Conectando testamentos: Números como tipo en Biblia Pauperum y Speculum Humanae Salvationis
2020
ABSTRACT: In the close typological relationship established in the Middle Ages between the Old and New Testaments, the Book of Numbers becomes an exemplary Christological and Mariological prefigurative example. The episodes of the Murmuring of Miriam and Aaron, the Spies from Canaan, the Rebellion of Korah, Dathan, and Abiram, the Brazen Serpent, the Budding of Aaron’s Rod and the Prophecy of Balaam, constitute types of New Testament passages collected in the Biblia Pauperum and the Speculum Humanae Salvationis, whose repercussion will be felt in Medieval and Modern Art as a theological visual synthesis present in stained glass windows, sculptures of portals, tapestries, goldsmith works and…
Cubic and rhombohedral Ba4Lu3F17:Er3+ in transparent glass ceramics: Crystallization and upconversion luminescence
2018
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