Search results for "Glycerol"

showing 10 items of 283 documents

The Lsm1-7/Pat1 complex binds to stress-activated mRNAs and modulates the response to hyperosmotic shock.

2018

RNA-binding proteins (RBPs) establish the cellular fate of a transcript, but an understanding of these processes has been limited by a lack of identified specific interactions between RNA and protein molecules. Using MS2 RNA tagging, we have purified proteins associated with individual mRNA species induced by osmotic stress, STL1 and GPD1. We found members of the Lsm1-7/Pat1 RBP complex to preferentially bind these mRNAs, relative to the non-stress induced mRNAs, HYP2 and ASH1. To assess the functional importance, we mutated components of the Lsm1-7/Pat1 RBP complex and analyzed the impact on expression of osmostress gene products. We observed a defect in global translation inhibition under…

Saccharomyces cerevisiae Proteinslcsh:QH426-470Gene ExpressionSaccharomyces cerevisiaeBiochemistryOsmotic PressureOsmotic ShockGeneticsRNA MessengerCellular Stress ResponsesGlycerol-3-Phosphate Dehydrogenase (NAD+)Biology and life sciencesMessenger RNAMembrane Transport ProteinsRNA-Binding ProteinsProteinsCell BiologyRepressor ProteinsNucleic acidslcsh:GeneticsRibonucleoproteinsRNA Cap-Binding ProteinsCell ProcessesProtein BiosynthesisPolyribosomesRNAProtein TranslationCellular Structures and OrganellesRibosomesProtein BindingResearch ArticlePLoS genetics
researchProduct

Partial photocatalytic oxidation of glycerol in TiO2 water suspensions

2010

2nd European Conference on Environmental Applications of Advanced Oxidation Processes -- SEP 09-11, 2009 -- Nicosia, CYPRUS

Settore ING-IND/24 - Principi Di Ingegneria ChimicaAnataseTitanium DioxideAqueous solutionFormic acidElectrospray ionizationGlycerol partial oxidation Selective photocatalytic oxidation Titanium dioxide Reaction pathwaysInorganic chemistryAqueous two-phase systemGeneral ChemistryCatalysischemistry.chemical_compoundchemistryGlyceraldehydeTitanium dioxideGlycerolSettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelective Photocatalytic OxidationGlycerol Partial OxidationReaction Pathways
researchProduct

A facile way to synthesize noble metal free TiO2 based catalysts for glycerol photoreforming

2023

In this work anaerobic heterogeneous photocatalytic solar/UV light reforming of glycerol in aqueous media was performed with Pt-photodeposition and noble metal free modified TiO2 photocatalysts prepared through ball milling, a very simple and cheap coupled catalyst preparation method. Different amounts of Cu2O or 3% CuO were loaded on TiO2 using ball milling and during each run glycerol conversion, hydrogen and CO2 formed in the gas phase and 1,3-dihydroxyacetone (DHA) and glyceraldehyde (GA) in the liquid phase were determined. The results were compared with the aim to verify the effectiveness of Cu2O in replacing Pt. Using noble metal free photocatalysts, 33% glycerol conversion, 10.3% an…

Settore ING-IND/24 - Principi Di Ingegneria ChimicaSettore ING-IND/23 - Chimica Fisica ApplicataHigh added value chemicalsGeneral Chemical EngineeringBall milling heterostructure formationTiO2Settore CHIM/07 - Fondamenti Chimici Delle TecnologieH2 productionPhotocatalytic glycerol partial oxidation
researchProduct

A way to follow the viability of encapsulated Bifidobacterium bifidum subjected to a freeze-drying process in order to target the colon: Interest of …

2012

The aim of this work was to apply flow cytometry in order to assess and compare the viability of freeze-dried entrapped bacteria with an usual technique by quantification by plate count techniques. It also aimed at studying the effect of various cryoprotectants on the viability of an entrapped Bifidobacterium bifidum subjected to freeze-drying to check their ability to be delivered all along the gastro-intestinal tract. The alginate-pectinate beads were chosen as the encapsulation matrix added with different protectants. The beads were characterized by scanning electron microscopy and the viability was checked by both methods. The best combination to improve viability of entrapped bacteria …

Sodium ascorbateCryoprotectantAlginatesColonved/biology.organism_classification_rank.speciesPharmaceutical ScienceFlow cytometryFreeze-dryingchemistry.chemical_compoundCryoprotective AgentsGlucuronic AcidmedicineGlycerolViability assayBifidobacteriumMicrobial ViabilityBifidobacterium bifidumChromatographybiologymedicine.diagnostic_testved/biologyHexuronic AcidsFlow Cytometrybiology.organism_classificationMolecular biologyBacterial LoadFreeze DryingchemistryPectinsBifidobacteriumEuropean Journal of Pharmaceutical Sciences
researchProduct

Determination of aerobic-anaerobic metabolism-related compounds in aChaoborus flavicans population by infusion ion trap mass spectrometry of extracts…

2006

In a daily migration, the aquatic larvae of Chaoborus flavicans (a phantom midge) alternate oxygen-saturated and anoxic lake strata. To investigate this cycle, larvae were collected at a natural environment, and acetate, propionate, pyruvate, lactate, glycerol, phosphate, maleate, succinate, glucose and citrate were determined. Each larva was homogenized with 200 microL water and deproteinized with a spin-filter; 50 microL aliquots were mixed with 50 microL of a buffer containing 80 mM propylamine, 20 mM HCl and 0.06 mM 2,4-dihydroxybenzoic acid (internal standard) in methanol. The extracts were infused in an electrospray ionization ion-trap mass spectrometer. The limits of detection for th…

Spectrometry Mass Electrospray IonizationElectrospray ionizationPopulationCeratopogonidaeMass spectrometryModels BiologicalAnalytical Chemistrychemistry.chemical_compoundFumaratesChaoborus flavicansGlycerolAnimalsAnaerobiosiseducationSpectroscopychemistry.chemical_classificationeducation.field_of_studyChromatographyOrganic ChemistryDiscriminant AnalysisMetabolismAerobiosischemistryLarvaPropionateAmmonium acetateRapid Communications in Mass Spectrometry
researchProduct

The mechanism of aquaporin inhibition by gold compounds elucidated by biophysical and computational methods

2017

The inhibition of water and glycerol permeation via human aquaglyceroporin-3 (AQP3) by gold(iii) complexes has been studied by stopped-flow spectroscopy and, for the first time, its mechanism has been described using molecular dynamics (MD), combined with density functional theory (DFT) and electrochemical studies. The obtained MD results showed that the most effective gold-based inhibitor, anchored to Cys40 in AQP3, is able to induce shrinkage of pores preventing glycerol and water permeation. Moreover, the good correlation between the affinity of the Au(iii) complex to Cys binding and AQP3 inhibition effects was highlighted, while no influence of the different oxidative character of the c…

Surfaces Coatings and FilmAquaporinCeramics and CompositeOxidative phosphorylationMolecular Dynamics Simulation010402 general chemistryElectrochemistry01 natural sciencesCatalysisCatalysiMolecular dynamicschemistry.chemical_compoundGold CompoundsJournal ArticleMaterials ChemistryGlycerolHumansOrganic chemistryAquaporin 3Molecular Structure010405 organic chemistryChemistryElectronic Optical and Magnetic MaterialChemistry (all)Metals and AlloysGeneral ChemistryPermeation0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSettore CHIM/03 - Chimica Generale E InorganicaCeramics and CompositesBiophysicsQuantum TheoryDensity functional theoryOrganogold CompoundsChemical Communications
researchProduct

Diacylglycerol-containing oleic acid induces increases in [Ca(2+)](i) via TRPC3/6 channels in human T-cells.

2011

Though most of the studies have focused on the effects of free fatty acids on T-cell activation, fatty acids incorporated into plasma membrane phospholipids may also affect cell signaling via diacylglycerol (DAG), generally produced by phospholipid hydrolysis. In the present study, we have synthesized a DAG-containing oleic acid and studied its implication in the modulation of calcium signaling in human Jurkat T-cells. 1-palmitoyl-2-oleoyl-sn-glycerol (POG) induced a dose-dependent increase in [Ca(2+)](i). This effect was due to the presence of oleic acid at the sn-2 position as no differences were observed between POG and 1-stearoly-2-oleoyl-sn-glycerol (SOG). However, the substitution of …

T-LymphocytesPhospholipidGene ExpressionBiologyCaveolaeDiglycerideschemistry.chemical_compoundJurkat CellsTRPC3Membrane MicrodomainsTRPC6 Cation ChannelHumansCalcium SignalingMolecular BiologyLipid raftCalcium signalingDiacylglycerol kinaseTRPC Cation ChannelsIon TransportVoltage-dependent calcium channelDose-Response Relationship DrugReverse Transcriptase Polymerase Chain Reactionbeta-CyclodextrinsCell BiologyOleic acidchemistryBiochemistryMicroscopy Fluorescencelipids (amino acids peptides and proteins)Arachidonic acidCalciumRNA InterferenceBiochimica et biophysica acta
researchProduct

Glycerol selective oxidation to lactic acid over AuPt nanoparticles; Enhancing reaction selectivity and understanding by support modification

2020

2 Schemes, 3 Tables, 5 Figures.

Tartronic acidGlycerolDehydration010405 organic chemistryChemistryOrganic ChemistryPrimary alcohol010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesLactic acidCatalysisInorganic ChemistryReaction ratechemistry.chemical_compoundChemical engineeringAerobic oxidationLewis acids and basesNanocastingLactic AcidPhysical and Theoretical ChemistrySelectivityMesoporous material
researchProduct

The Effect of Long-Term Storage on the Biological and Histological Properties of Cryopreserved Amniotic Membrane

2011

Cryopreserved amniotic membrane (AM) is widely used in ophthalmology because of its anti-angiogenic, anti-inflammatory, and wound healing promoting capabilities. A common method to conserve the tissue is the storage in cryo-medium containing 50% glycerol at -80°C. The aim of this study was to examine the influence of storage time on the sterility as well as the histological and biological properties of cryopreserved AM.Amniotic membrane from different donors was stored in cell culture media containing 50% glycerol for different time periods, on average 4 months (group 1), 15 months (group 2), and 24 months (group 3), at -80°C. Samples of the tissue and cryo-medium were examined for bacteria…

Time FactorsSterilityBlotting WesternOrgan Preservation SolutionsMedizinTissue BanksBiologyCryopreservationAndrologyCellular and Molecular Neurosciencechemistry.chemical_compoundGlycerolHumansAmnionPolyacrylamide gel electrophoresisCryopreservationExtracellular Matrix ProteinsBacteriaBiological DressingsFungiOrgan PreservationSensory SystemsCulture MediaBlotOphthalmologyMembranechemistryTissue bankImmunologyCytokinesElectrophoresis Polyacrylamide GelWound healingBiomarkersCurrent Eye Research
researchProduct

Lipid and fatty acid variations inCiona intestinalis ovary after tri-n-butyltin(IV)chloride exposure

2005

Reduction of total lipids (TL) content and significant variations of triglyceride (TG) and phospholipid (PL) fractions were observed as a consequence of exposure of Ciona intestinalis ovaries to tributyltin chloride (TBTCL) solutions. In particular, an evident TG decrease and a PL increase were observed, which probably provoked an increment in membrane fluidity, because of the high concentration of long chain fatty acids and, as a consequence, PL. This could be a cell adaptive standing mechanism towards the pollutants, as observed in Saccharomyces cerevisiae. Also the increase in the content of the polyunsaturated fatty acids (PUFA), important in the synthesis of compounds such as prostagla…

Total lipidsCiona intestinaliChlorideFluiditytributyltinstresschemistry.chemical_compoundSettore BIO/10 - BiochimicaMembrane fluiditychemistry.chemical_classificationbiologymembrane fluidityarticlepolyunsaturated fatty acidBiological membranemedicine.anatomical_structureBiochemistrySettore CHIM/03 - Chimica Generale E InorganicaSynthesis (chemical)pollutantprostaglandintriacylglyceroladaptive behaviorPolyunsaturated fatty acidmedicine.drugSettore BIO/07 - EcologiaPhospholipidOvarylipid compositionSaccharomyces cerevisiaelong chain fatty acidOvarieInorganic ChemistrylipidmedicineCiona intestinalisdefense mechanismPolyunsaturated fatty acids (PUFA)TriglyceridesphospholipidnonhumanTriglycerideProstaglandineOvaryFatty acidGeneral ChemistryTBTClFatty acidbiology.organism_classificationprostaglandin synthesichemistryCellApplied Organometallic Chemistry
researchProduct