Search results for "Grain boundary"
showing 10 items of 143 documents
Structural defects in Hg1−xCdxI2 layers grown on CdTe substrates by vapor phase epitaxy
1997
Hg1−xCdxI2 20–25-μm-thick layers with a uniform composition in the range of x = 0.1–0.2 were grown on CdTe substrates by vapor phase epitaxy (VPE). The growth was carried out using an α-HgI2 polycrystalline source at 200 °C and in the time range of 30–100 h. The layers were studied by scanning electron microscopy (SEM) and high resolution synchrotron x-ray topography (SXRT). The SEM and SXRT images of Hg1−xCdxI2 VPE layers allow one to identify the defects affecting the layer structure. The two main types of structural defects in the layers are subgrain boundaries and densely spaced striations similar to those referred generally to as vapor grown HgI2 bulk crystals. The effect of the growth…
Effect of silicon on corrosion resistance of Ti–Si alloys
2011
Abstract The corrosion resistance of Ti–Si alloys has been studied in acid solutions and the alloys exhibit a high resistance to corrosion. SEM examinations combined with EDAX allowed to conclude that the passive films on Ti–Si alloys are mainly composed of TiO 2 /SiO 2 oxides. XPS analysis indicated the formation of Si–O and Si–O–Ti bonds in the passive film, respectively corresponding to SiO 2 and Si-doping TiO 2 . The effect of silicon on the corrosion was correlated to the formation of a stable SiO 2 film, Si-doping on TiO 2 and the extended lattice imperfections formed along TiO 2 /SiO 2 grain boundaries and phase-boundaries. The calculated donor densities based on the point defect mod…
Scanning electron microscopy analysis of defect clusters in multicrystalline solar grade silicon solar cells
2014
Solar cells from an identical commercial manufacturing unit have been investigated by electroluminescence to first detect the defect clusters. A further analysis has been done by scanning electron microscopy in secondary electron imaging mode to understand the propagation mechanism of defects. It appears that defect cluster boundaries can be very sharp or spread in the bulk with little apparent effect on the overall cell efficiency. And it is shown that grain boundaries act clearly as arrests to further propagation of these defects.
PLZT—Synthesis, sintering and ceramics microstructure
2006
Abstract Producing of PLZT powders by original two-stage co-precipitation method from mixed solution of inorganic salts ZrOCl 2 ·8H 2 O, TiCl 4 , La(NO 3 ) 3 ·6H 2 O, Pb(NO 3 ) 2 , was carried out. The sequence of phases formed during PLZT synthesis has been studied by X-ray and DTA analysis. Ceramic samples were prepared by two-stage hot-pressing technology. Dielectric, ferroelectric and optical properties have been measured. Ceramic microstructures were studied by SEM with energy dispersive analytical capability (EDX). The fine-grained microstructure was quite uniform with the average grain size of 5–7 μm, without internal or grain boundary porosity. The optical transmittance of ceramic p…
Microstructure-oxidation resistance relationship in Ti3AlC2 MAX phase
2020
International audience; Spark Plasma Sintering and Hot Isostatic Pressing were used to synthesize coarse-grained and fine-grained Ti3AlC2 specimens. Moreover, Spark Plasma Sintering processing parameters were modified in order to vary the TiC, Al2O3 and TixAly impurity and the porosity contents in the fine-grained samples. The influence of the Ti3AlC2 microstructure on the oxidation resistance was assesed. It is demonstrated that the grain size can drastically modify the oxidation resistance. The higher density of grain boundaries, in fine-grained specimens, increases the number of Al diffusion paths and leads to the formation of a protective alumina scale. In coarse-grained sample, Al diff…
Real-Time Monitoring of Intergranular Corrosion Damage on AA2024
2017
The total porosity induced by the intergranular corrosion was selected as a monitoring parameter to follow in real-time the defect propagation of AA2024. The pertinence of eddy current (EC) probing has been tested on very thin foils of AA2024 (30 μm in thickness) in immersion conditions under potentiostatic control and in atmospheric conditions simulated by controlled salt spray experiments. Combining this nondestructive evaluation technique with a direct optical interrogation of the backside of the test specimen (derived from the foil penetration technique) allows one to discuss the contribution of both the dissolution in the depth and along the grain boundaries to the total porosity. In i…
Influence of Post-machining Thermal Treatment on the Corrosion Behaviour of Copper
2014
Abstract In this paper, the influence of a post-machining thermal treatment (PMTT) on the corrosion behaviour of copper was investigated in a salt fog atmosphere. The corrosion behaviour was affected by the presence of a high density of grain boundaries generated during machining or dislocations formed during PMTT under certain conditions. The obtained results showed that it is possible to find PMTT conditions to cancel changes induced by machining and that the critical factor leading to a sharp increase of the percentage of oxidized surface seems to be the density of dislocations near the machined surface.
Formation of surface roughness on nanocrystalline aluminum samples under straining by molecular dynamics studies
2006
International audience; The surface roughening of nanocrystalline aluminum samples was investigated by molecular dynamics simulations. Attention was focused on the fact that roughness increases with the grain size and the strain. The elastic-plastic transition was found at around 3.5% strain and a reverse Hall-Petch effect was observed under straining conditions. Then, different strain distributions in grains and grain boundaries at the samples surface was highlighted, yielding to the formation of local roughness. Finally, a linear relationship between the magnitude of roughness and the out-of-plane strain component was found.
Micro-cracking of brittle polycrystalline materials with initial damage
2016
In this paper, the effect of pre-existing damage on brittle micro-cracking of polycrystalline materials is explored. The behaviour of single and multiple cracks randomly distributed within a grain scale polycrystalline aggregate is investigated using a recently developed grain boundary 3D computational framework. Each grain is modelled as a single crystal anisotropic domain. Opening, sliding and/or contact at grain boundaries are modelled using nonlinear cohesive-frictional laws. The polycrystalline micro-morphologies are generated using Voronoi tessellation algorithms in combination with a regularisation scheme to avoid the presence of unnecessary small geometrical entities (edges and face…
New method of grain-boundary extraction by directional optimal filtering: application to estimating creep in metals
2002
It is economically important for manufacturers of high- temperature machines to be able to measure creep so they can predict residual service life more accurately. This paper describes and refines an image analysis method for evaluating creep in laboratory test pieces. It is a preliminary study of how to extract relevant information for creep mea- surement by counting cavities. Sample preparation for quantification by image analysis is an important step determining the further development of the image analysis technique. Grain-boundary extraction, which in- volves directional information, is the major problem to be solved before measurement can be automated. The search for a crest-line extr…