Search results for "HIF"
showing 10 items of 1515 documents
Sensitivity of noble gas NMR parameters to the heterocyclic ring proximity. Density functional theory studies of Ne–furan and Ar–furan complexes
2014
Theoretical modeling of noble gas interaction with furan as a simple heterocyclic ring was performed. The structures of neon–furan and argon–furan complexes were calculated at the MP2, M06-2X, CAM-B3LYP, APFD, and VSXC levels of theory using 6-311++G** basis set. The predicted 21Ne and 39Ar NMR chemical shifts for the Ne–furan and Ar–furan complexes calculated with pcS-3 and aug-pcS-3 basis sets were sensitive to the presence of the aromatic furan ring. Our results indicate a higher sensitivity of the neon and argon NMR probes than the previously reported 3He NMR spectroscopic parameters in studies of small heterocyclic rings containing the oxygen atom.
Mononuclear and tetranuclear Fe(III) complexes with two different types of N, O donor Schiff base ligands
2013
Abstract A mononuclear Fe(III) complex of a tetradentate N 2 O 2 donor Schiff base ligand derived from 3-ethoxysalicaldehyde and ethylenediamine has been reported. In addition two tetranuclear Fe(III) complexes with discrete Fe 4 III (μ 4 -O) cores have been synthesized and characterized using two Schiff base ligands (H 2 L 1–2 ) derived from two different aromatic acid hydrazides and diacetyl monoxime. The mononuclear Fe(III) and one of the tetranuclear Fe(III) complexes have been structurally characterized by single-crystal X-ray crystallography. The mononuclear complex has a highly distorted octahedral geometry. The tetranuclear Fe(III) complexes are found to be rare examples with discre…
Phosphine-diène and Salicylamidines ligands : coordination chemistry, catalysis and therapy
2017
The subject of this thesis concerns the development of new ligands, their coordination chemistry, and the synthesis of the corresponding metal complexes for catalysis and therapy.The first part of this work relates to the synthesis of diene-phosphine ligands, their saturated analogs, and the corresponding arene-ruthenium complexes. Arene decoordination allows the formation of a cationic bimetallic complex where the ligand is diène-η4/κ-P coordinated to the ruthenium. These complexes have been applied to atom transfer radical addition (ATRA) of CCl4 to styrene. When harsh reaction conditions are used, the superiority of the “diene” complexes is highlighted comparing to saturated analogs.The …
Robust Neutrino Constraints by Combining Low Redshift Observations with the CMB
2009
We illustrate how recently improved low-redshift cosmological measurements can tighten constraints on neutrino properties. In particular we examine the impact of the assumed cosmological model on the constraints. We first consider the new HST H-0 = 74.2 +/- 3.6 measurement by Riess et al. (2009) and the sigma(8)(Omega(m)/0.25)(0.41) = 0.832 +/- 0.033 constraint from Rozo et al. (2009) derived from the SDSS maxBCG Cluster Catalog. In a ACDM model and when combined with WMAP5 constraints, these low-redshift measurements constrain Sigma m(v) < 0.4 eV at the 95% confidence level. This bound does not relax when allowing for the running of the spectral index or for primordial tensor perturbations…
The clustering of galaxies in the SDSS-III Baryon Oscillation Spectroscopic Survey: Baryon Acoustic Oscillations in the Data Release 10 and 11 galaxy…
2014
We present a one per cent measurement of the cosmic distance scale from the detections of the baryon acoustic oscillations in the clustering of galaxies from the Baryon Oscillation Spectroscopic Survey (BOSS), which is part of the Sloan Digital Sky Survey III (SDSS-III). Our results come from the Data Release 11 (DR11) sample, containing nearly one million galaxies and covering approximately $8\,500$ square degrees and the redshift range $0.2<z<0.7$. We also compare these results with those from the publicly released DR9 and DR10 samples. Assuming a concordance $\Lambda$CDM cosmological model, the DR11 sample covers a volume of 13\,Gpc${}^3$ and is the largest region of the Universe ever su…
Non-linear evolution of the cosmic neutrino background
2012
We investigate the non-linear evolution of the relic cosmic neutrino background by running large box-size, high resolution N-body simulations which incorporate cold dark matter (CDM) and neutrinos as independent particle species. Our set of simulations explore the properties of neutrinos in a reference Lambda CDM model with total neutrino masses between 0.05-0.60 eV in cold dark matter haloes of mass 10(11) – 10(15) h(-1) M-circle dot, over a redshift range z = 0 – 2. We compute the halo mass function and show that it is reasonably well fitted by the Sheth-Tormen formula, once the neutrino contribution to the total matter is removed. More importantly, we focus on the CDM and neutrino proper…
Constraints on dark matter annihilation from CMB observations before Planck
2013
We compute the bounds on the dark matter (DM) annihilation cross section using the most recent Cosmic Microwave Background measurements from WMAP9, SPT'11 and ACT'10. We consider DM with mass in the MeV-TeV range annihilating 100% into either an e(+)e(-) or a mu(+)mu(-) pair. We consider a realistic energy deposition model, which includes the dependence on the redshift, DM mass and annihilation channel. We exclude the canonical thermal relic abundance cross section ( = 3 x 10(-26) cm(3)s(-1)) for DM masses below 30 GeV and 15 GeV for the e(+)e(-) and mu(+)mu(-) channels, respectively. A priori, DM annihilating in halos could also modify the reionization history of the Universe at late times…
Cosmological parameters degeneracies and non-Gaussian halo bias
2010
We study the impact of the cosmological parameters uncertainties on the measurements of primordial non-Gaussianity through the large-scale non-Gaussian halo bias effect. While this is not expected to be an issue for the standard Lambda CDM model, it may not be the case for more general models that modify the large-scale shape of the power spectrum. We consider the so-called local non-Gaussianity model, parametrized by the f(NL) non-Gaussianity parameter which is zero for a Gaussian case, and make forecasts on f(NL) from planned surveys, alone and combined with a Planck CMB prior. In particular, we consider EUCLID- and LSST-like surveys and forecast the correlations among f(NL) and the runni…
First search for neutrinos in correlation with gamma-ray bursts with the ANTARES neutrino telescope
2013
A search for neutrino-induced muons in correlation with a selection of 40 gamma-ray bursts that occurred in 2007 has been performed with the ANTARES neutrino telescope. During that period, the detector consisted of 5 detection lines. The ANTARES neutrino telescope is sensitive to TeV-PeV neutrinos that are predicted from gamma-ray bursts. No events were found in correlation with the prompt photon emission of the gamma-ray bursts and upper limits have been placed on the flux and fluence of neutrinos for different models.
A Standard Siren Measurement of the Hubble Constant from GW170817 without the Electromagnetic Counterpart
2019
We perform a statistical standard siren analysis of GW170817. Our analysis does not utilize knowledge of NGC 4993 as the unique host galaxy of the optical counterpart to GW170817. Instead, we consider each galaxy within the GW170817 localization region as a potential host; combining the redshift from each galaxy with the distance estimate from GW170817 provides an estimate of the Hubble constant, $H_0$. We then combine the $H_0$ values from all the galaxies to provide a final measurement of $H_0$. We explore the dependence of our results on the thresholds by which galaxies are included in our sample, as well as the impact of weighting the galaxies by stellar mass and star-formation rate. Co…