Search results for "HYPERFINE"

showing 10 items of 428 documents

Fifty Years of Mössbauer Spectroscopy in Solid State Research - Remarkable Achievements, Future Perspectives

2011

Mossbauer spectroscopy was founded more than fifty years ago based on an outstanding discovery by the young German physicist Rudolf Ludwig Mossbauer while working on his Ph.D. thesis. He discovered the recoilless nuclear resonance fluorescence of gamma radiation and was awarded the Nobel Prize in Physics in 1961 as one of the youngest recipients of this most prestigious award. His discovery led to the development of a new technique for measurements of hyperfine interactions between nuclear moments and electromagnetic fields. This method, with highest sharpness of tuning of 10–13, yields information on valence state, symmetry, magnetic behavior, phase transition, lattice dynamics and other s…

Inorganic ChemistryNuclear physicsPhysicsLattice dynamicsPhysics::Popular PhysicsNuclear magnetic resonanceMössbauer effectMössbauer spectroscopySolid-stateNuclear resonance fluorescenceGerman physicistHyperfine structurePhysics::History of PhysicsZeitschrift für anorganische und allgemeine Chemie
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CRIS: A new method in isomeric beam production

2013

The Collinear Resonance Ionization Spectroscopy (CRIS) experiment at ISOLDE, CERN, uses laser radiation to stepwise excite and ionize an atomic beam for the purpose of ultra-sensitive detection of rare isotopes, and hyperfine-structure measurements. The technique also offers the ability to purify an ion beam that is heavily contaminated with radioactive isobars, including the ground state of an isotope from its isomer, allowing decay spectroscopy on nuclear isomeric states to be performed. The isomeric ion beam is selected by resonantly exciting one of its hyperfine structure levels, and subsequently ionizing it. This selectively ionized beam is deflected to a decay spectroscopy station (DS…

Ion beamRadioactive decay spectroscopyPhysicsQC1-999chemistry.chemical_elementIon beam purificationFranciumSemiconductor detectorIsotope shiftchemistryIonizationPhysics::Atomic and Molecular ClustersPhysics::Accelerator PhysicsNeutronHyperfine structurePhysics::Atomic PhysicsAtomic physicsLaser spectroscopySpectroscopyNuclear ExperimentBeam (structure)Radioactive decay
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Lambda-doublet specificity in the low-temperature capture of NO(X Π21/2) in low rotational states by C+ ions

2009

Following our general approach to Lambda-doubling specificity in the capture of dipolar molecules by ions [M. Auzinsh et al., J. Chem. Phys. 128, 184304 (2008)], we calculate the rate coefficients for the title process in the temperature range 10(-4)<T<10(2) K. Three regimes considered are as follows: (i) nonadiabatic capture in the regime of high-field Stark effect with respect to the Lambda-doubling components, (10(-1)<T<10(2) K), (ii) adiabatic capture in the regime of intermediate Stark effect (10(-3)<T<10(-1) K), and (iii) adiabatic capture in the limit of very low temperatures (T<<10(-3) K) in the regime of quadratic Stark effect with respect to the Lambda-doubling and hyperfine compo…

IonsRotationElectron captureChemistryGeneral Physics and AstronomyAtmospheric temperature rangeNitric OxideLambdaCarbonIonCold TemperatureKineticsDipolesymbols.namesakeStark effectsymbolsPhysical and Theoretical ChemistryAtomic physicsAdiabatic processHyperfine structureThe Journal of Chemical Physics
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Nuclear moments and the change in the mean square charge radius of neutron deficient thallium isotopes

1992

The hyperfine structure, isotope and isomeric shifts in the atomic transition 6p 2 P 3/2−7s 2 S 1/2, λ=535 nm have been measured for theI=7 andI=2 states of190, 192, 194, 196Tl; theI=1/2 andI=9/2 states of191Tl and the I=7 isomer of188Tl. The thallium isotopes were prepared as fast atomic beams at the GSI on-line mass separator following fusion reactions and — in some cases — subsequentβ-decay. The nuclear dipole moments, electric quadrupole moments and the change in the nuclear mean square charge radius are evaluated. Theuu-isotopes show an isomeric shift which changes sign between192Tl and194Tl.

Isomeric shiftPhysicsNuclear and High Energy PhysicsDipoleIsotopeCharge radiusQuadrupoleNuclear fusionNeutronAtomic physicsHyperfine structureZeitschrift f�ur Physik A Hadrons and Nuclei
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Isotope shifts and hyperfine structure in the transitions of stable calcium isotopes and calcium-41

1998

Isotope shifts and hyperfine structure in the 4s2 1S0 → 4s4p 1P1 and 4s2 1S0 → 4s4d 1D2 transitions of calcium have been measured with high-precision laser spectroscopy. Calcium atoms in an atomic beam were excited with single-frequency cw dye and titanium sapphire lasers and then photoionized with the 363.8 nm or 514.5 nm line of an argon ion laser. The resulting ions were analyzed and detected with a quadrupole mass spectrometer. Isotope shifts for all stable calcium isotopes and the radionuclide 41Ca have been measured in both transitions. The corresponding field shift and specific mass shift coefficients as well as hyperfine structure constants for the isotopes 41, 43Ca have been derive…

IsotopeChemistryAnalytical chemistryAtomic and Molecular Physics and OpticsMolecular electronic transitionAnalytical ChemistryIsotopes of calciumExcited statePhysics::Atomic PhysicsAtomic physicsAtomic vapor laser isotope separationSpectroscopyInstrumentationHyperfine structureQuadrupole mass analyzerSpectroscopySpectrochimica Acta Part B: Atomic Spectroscopy
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High-resolution triple-resonance autoionization of uranium isotopes

2005

Abstract The near-threshold autoionization (AI) spectrum of uranium has been investigated by triple-resonance excitation with single-mode continuous lasers. Spectra were recorded over the first ∼30 cm − 1 above the first ionization limit at a resolution of 3 × 10 − 4 cm − 1 using intermediate states with different J values (6, 7, 8) to assign AI level total angular momentum J AI  = 5 to 9. Resonances with widths ranging from 8 MHz to 30 GHz were observed; the strongest ones have J AI  = 9 and widths of ∼60 MHz. Hyperfine structures for 235 U and isotope shifts for 234, 235 U have been measured in the two intermediate levels and in the final AI level for the most favorable excitation path. T…

IsotopeIsotopes of uraniumChemistryAnalytical chemistryResonancechemistry.chemical_elementUraniumAtomic and Molecular Physics and OpticsSpectral lineAnalytical ChemistryAutoionizationIonizationAtomic physicsInstrumentationHyperfine structureSpectroscopySpectrochimica Acta Part B: Atomic Spectroscopy
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Laser spectroscopy of neutron deficient lead and thallium isotopes: Systematics of nuclear radii in the Z = 82 region

1989

Publisher Summary The high sensitivity achievable in laser spectroscopic methods allows the extraction of nuclear quantities even of artificially produced short-lived nuclides far off from nuclear stability. By analyzing the hyperfine structure and the isotope shift magnetic dipole moments, the electric quadrupole moments and the change of the nuclear charge radius can be studied. This chapter describes an experiment that was carried out at the GSI on-line mass separator using collinear fast atomic-beam laser spectroscopy. Radioactive lead and thallium isotopes were produced by bombarding natural tungsten targets with oxygen beams. For the lighter thallium isotopes, a tantalum target was us…

IsotopeNuclear Theorychemistry.chemical_elementEffective nuclear chargeNuclear physicschemistryQuadrupolePhysics::Accelerator PhysicsThalliumNeutronPhysics::Atomic PhysicsNuclideNuclear ExperimentSpectroscopyHyperfine structure
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The mean square nuclear charge radius of

1996

We report on a collinear laser spectroscopy measurement of the nuclear charge radius of (I = 3/2), yielding . Within the experimental accuracy, the N = 20 neutron shell closure has no influence on the charge radii of the calcium isotopes.

Isotopes of calciumPhysicsNuclear and High Energy PhysicsNuclear TheoryShell (structure)NeutronCharge (physics)RadiusAtomic physicsNuclear ExperimentSpectroscopyHyperfine structureEffective nuclear chargeJournal of Physics G: Nuclear and Particle Physics
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Anomalous Muon Knight Shift Behavior in a Cd Single Crystal

1983

For the positive muon implanted in a metal the precession frequency shift due to hyperfine fields can be measured with high precision. This provides means to obtain information about the local electronic structure of a hydrogen like impurity in any metal in the indefinitely dilute impurity concentration. Ref. 1 gives a summary of the muon Knight shift (KS) investigations in 18 nontransition (simple) metals and some transition metals and discusses the results in the context of the electronic structure of hydrogen in metals.

Larmor precessionPhysicsMuonTransition metalCondensed matter physicsImpurityCondensed Matter::Strongly Correlated ElectronsContext (language use)Knight shiftElectronic structureHyperfine structure
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Multi-frequency EPR studies of a mononuclear holmium single-molecule magnet based on the polyoxometalate [Ho(III)(W5O18)2]9-.

2012

Continuous-wave, multi-frequency electron paramagnetic resonance (EPR) studies are reported for a series of single-crystal and powder samples containing different dilutions of a recently discovered mononuclear Ho(III) (4f(10)) single-molecule magnet (SMM) encapsulated in a highly symmetric polyoxometalate (POM) cage. The encapsulation offers the potential for applications in molecular spintronics devices, as it preserves the intrinsic properties of the nanomagnet outside of the crystal. A significant magnetic anisotropy arises due to a splitting of the Hund's coupled total angular momentum (J = L + S = 8) ground state in the POM ligand field. Thus, high-frequency (50.4 GHz) EPR studies reve…

Ligand field theorySpintronicsCondensed matter physics010405 organic chemistryChemistry010402 general chemistry01 natural sciences7. Clean energyNanomagnetMolecular physics0104 chemical scienceslaw.inventionInorganic ChemistryMagnetic anisotropylawSingle-molecule magnetGround stateElectron paramagnetic resonanceHyperfine structureDalton transactions (Cambridge, England : 2003)
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