Search results for "Ham"
showing 10 items of 2612 documents
A local picture associated with a triply degenerate vibrational mode: vibrational and rovibrational local states
1998
International audience; Abstract: A symmetrized basis adapted to the study of some vibrational excited states of spherical top molecules is proposed. This basis, consistent with the Cartesian picture associated with a three-dimensional mode, is then tested numerically through various XY6 and XY4 molecules. In addition, some simulations, made with 238UF6 and a simplified version of an effective Hamiltonian, clearly show that the method can be further extended through the construction of a symmetrized local rovibrational basis.
Study of the stretching modes of the arsine molecule
2003
Abstract To study local mode XY 3 molecules, we use properties of the group chain U ( 4 ) ⊃ U ( 3 ) ⊃ K ( 3 ) ⊃ S ( 3 ) ≈ C 3 v . For the Hamiltonian, we deduce diagonal terms and coupling terms between bonds. We analyze the stretching modes of the arsine molecule. An algebraic transition operator is built and applied to the same molecular system.
Collisional models in a nonperturbative approach
1992
Abstract A nonperturbative method set forth recently for handling quantum dynamics in the intermediate regime (far from either the sudden or the adiabatic limit) is applied to soluble two-state collisional models.
STABILITY AND SPECTRA OF SMALL 3He-4He CLUSTERS
2005
Diffusion Monte Carlo calculations have been systematically performed to analyze the stability of small mixed 3 He -4 He clusters, as well as their excitation spectra. The picture that emerges is that of systems with strong shell effects whose binding and excitation energies are essentially determined by the monopole properties of an effective Hamiltonian.
Driven harmonic oscillators in the adiabatic Magnus approximation
1993
The time evolution of driven harmonic oscillators is determined by applying the Magnus expansion in the basis set of instantaneous eigenstates of the total Hamiltonian. It is shown that the first-order approximation already provides transition probabilities close to the exact values even in the intermediate regime.
Manifestation of Hamiltonian Monodromy in Nonlinear Wave Systems
2011
International audience; We show that the concept of dynamical monodromy plays a natural fundamental role in the spatiotemporal dynamics of counterpropagating nonlinear wave systems. By means of an adiabatic change of the boundary conditions imposed to the wave system, we show that Hamiltonian monodromy manifests itself through the spontaneous formation of a topological phase singularity (2 - or -phase defect) in the nonlinear waves. This manifestation of dynamical Hamiltonian monodromy is illustrated by generic nonlinear wave models. In particular, we predict that its measurement can be realized in a direct way in the framework of a nonlinear optics experiment.
Instabilities of optical solitons and Hamiltonian singular solutions in a medium of finite extension
2011
International audience; We analyze the role of soliton solutions and Hamiltonian singularities in the dynamics of counterpropagating waves in a medium of finite spatial extension. The soliton solution can become unstable due to the finite extension of the system. We show that the spatiotemporal dynamics then relaxes toward a Hamiltonian singular state of a nature different than that of the soliton state. This phenomenon can be explained through a geometrical analysis of the singularities of the stationary Hamiltonian system.
Adiabatic approximation for quantum dissipative systems: formulation, topology and superadiabatic tracking
2010
A generalized adiabatic approximation is formulated for a two-state dissipative Hamiltonian which is valid beyond weak dissipation regimes. The history of the adiabatic passage is described by superadiabatic bases as in the nondissipative regime. The topology of the eigenvalue surfaces shows that the population transfer requires, in general, a strong coupling with respect to the dissipation rate. We present, furthermore, an extension of the Davis-Dykhne-Pechukas formula to the dissipative regime using the formalism of Stokes lines. Processes of population transfer by an external frequency-chirped pulse-shaped field are given as examples.
Transition cancellations of 87Rb and 85Rb atoms in a magnetic field
2020
We have analyzed the magnetic field dependencies of the intensities of all the optical transitions between magnetic sublevels of hyperfine levels, excited with σ + , π , and σ − polarized light, for the D 1 and D 2 lines of 87 R b and 85 R b atoms. Depending on the type of transition and the quantum numbers of the involved levels, the Hamiltonian matrices are of 1 × 1 , 2 × 2 , 3 × 3 , or 4 × 4 dimension. As an example, analytical expressions are presented for the case of 2 × 2 dimension matrices for the D 1 line of both isotopes. Eigenvalues and eigenkets are given, and the expression for the transition intensity as a function of B has been determined. It is found that some π transitions o…
High-rate x-ray spectroscopy in mammography with a CdTe detector: A digital pulse processing approach
2010
Purpose:Direct measurement of mammographic x-ray spectra under clinical conditions is a difficult task due to the high fluence rate of the x-ray beams as well as the limits in the development of high resolution detection systems in a high counting rate environment. In this work we present a detection system, based on a CdTe detector and an innovative digital pulse processing (DPP) system, for high-rate x-ray spectroscopy in mammography. Methods: The DPP system performs a digital pile-up inspection and a digital pulse height analysis of the detector signals, digitized through a 14-bit, 100 MHz digitizer, for x-ray spectroscopy even at high photon counting rates. We investigated on the respon…