Search results for "Heck"
showing 10 items of 682 documents
Kihon Checklist to assess frailty in older adults: Some evidence on the internal consistency and validity of the Spanish version
2021
Aim The aim of this study was to assess the internal consistency, hypothesis testing and criterion-related validity of the Spanish versions of the Kihon Checklist (KCL) - the original 25-item and reduced 15-item versions - for screening frailty in community-dwelling older adults. Methods A cross-sectional study was carried out between March and September 2018 in Valencia province (Spain). A sample of 251 participants was recruited. Construct validity was assessed using four different frailty instruments, and alternative measures corresponding to the KCL domains (handgrip strength, gait speed, the Short Physical Performance Battery, skeletal muscle mass index, physical activity level, functi…
Dimensions underlying frailty indicators in the Kihon Checklist.
2019
Aim Frailty has become a current topic of debate in recent years among researchers as a key concept of clinical care in old age. One of the scales developed for its measurement is the Kihon Checklist (KCL). However, the dimensionality of the KCL has not been tested yet, and therefore the aim of the present study was to validate its dimensional structure. Methods This was a cross-sectional study carried out between March and September 2018 in Valencia province (Spain). Participation in the study was voluntary. A total of 251 participants were sampled. They answered sociodemographic and medical indicators, as well as five frailty scales, including the KCL. Results Five confirmatory models wit…
Spatial analysis of the relationship between mortality from cardiovascular and cerebrovascular disease and drinking water hardness
2004
Journal Article; Research Support, Non-U.S. Gov't; Reproduced with permission from Environmental Health Perspectives. Previously published scientific papers have reported a negative correlation between drinking water hardness and cardiovascular mortality. Some ecologic and case-control studies suggest the protective effect of calcium and magnesium concentration in drinking water. In this article we present an analysis of this protective relationship in 538 municipalities of Comunidad Valenciana (Spain) from 1991-1998. We used the Spanish version of the Rapid Inquiry Facility (RIF) developed under the European Environment and Health Information System (EUROHEIS) research project. The strateg…
Effective strategies for promoting physical activity through the use of digital media among school-age children: A systematic review
2021
Digital media are widespread among school-age children, and their incorrect use may lead to an increase in sedentary levels and the consequences associated with it. There are still few studies that have investigated whether physical activity levels could be increased through their use. The aim of this study was to systematically review the scientific literature in order to identify whether digital strategies and technologies are capable of increasing the level of physical activity. A literature search was performed using the following databases: Pubmed, Scopus, and Web of Science. The main outcomes evaluated the increase in physical activity levels, the number of steps, and the reduction of…
Gli Ortotteri di Sicilia: check-list commentata.
2011
Biogeographia I./qO'I.A)O'O( - 2011 (Pubblicato il 23 dicembre 2011) La Biogeografia della Sicilia Gli Ortotteri di Sicilia: check—list commentata BRUNO MASSA Dipartimerzto DEMETRA (Sezione Entomologizz, Acarologia, Zoologia) Ea’. 4, Vle della Scienze, 90128 Palermo e—maz'[: brzmo. mam: @um'pzz. it Key words: grasshoppers, annotated check-list, endemisms, species richness, Sicily SUMMARY The author analyses all the bibliographic references on Sicilian Orthoptera and many unpublished data, with which he carries out an annotated check—list of species so Far known in the island. On the whole, 127 species of Or- thoptera are currently known in Sicily (including small islands surr…
DEEP EUTECTIC SOLVENTS E LIQUIDI IONICI: SOLVENTI PER LO SVILUPPO DI PROCESSI ECO-COMPATIBILI
2020
L’obiettivo di questi tre anni di Dottorato è stato lo studio e l’utilizzo nuovi solventi di reazione in grado di sostituire i solventi organici classici. In particolare sono stati studiati i Deep Eutectic Solvent (DES) e le miscele di Liquidi Ionici (IL). I DES sono stati utilizzati come solventi per lo studio di reazioni organiche, usate per la formazione di nuovi legami C-C. Nello specifico sono state studiate la reazione di Diels-Alder, e diverse reazioni di coupling C-C catalizzate da Pd. In seguito, i DES sono stati utilizzati per la formazione di nuovi gel supramolecolari, chiamati eutectogel. Questi gel sono stati formati usando come gelator amminoacidi naturali, consentendo quindi …
Ultra-Low Catalyst Loading as a Concept in Economical and Sustainable Modern Chemistry: The Contribution of Ferrocenylpolyphosphane Ligands
2007
The challenge of sustainability in modern chemistry will be met with new technologies and processes provided significant progress is made in several key research areas, such as the expansion of chemistry from renewable feedstock, the design of environmentally benign chemicals and solvents, the minimization of depletive resources, and the development of high-performance catalysis. In this prospect, ligand chemistry is a pivotal science that links modern-organic,-inorganic, -organometallic, and -coordination chemistry through a vast number of valuable applications, precisely associated to catalysis. We review in this article our recent work on catalysis promoted by original ferrocenyl tetra-,…
An E-Factor Minimized Protocol for a Sustainable and Efficient Heck Reaction in Flow
2014
A highly sustainable and waste-minimized protocol for Heck coupling has been defined. Optimal conditions have been defined by exploiting a heterogeneous catalyst based on supported ionic liquid-like phases featuring high Pd loading (10 wt %) and by optimizing its efficiency in a recoverable green reaction medium (acetonitrile/water azeotrope). Pure products 4a–l and 6a–h have been isolated chromatography-free in high yields (74–99%) and with extremely low environmental factor (E-factor) values (2.3–5.0). With the application of flow technology, the selected heterogeneous base and Pd catalyst have been fully recovered and reused, and minimum palladium leaching allowed for isolation of the fi…
Recyclable heterogeneous palladium catalysts in pure water: sustainable developments in Suzuki, Heck, Sonogashira and Tsuji-Trost reactions
2010
This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium-catalyzed transformations for carbon-carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji-Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.
A survey to evaluate safety in protected crops in western Sicily
2017
Protected crops in the Mediterranean area has reached advanced production systems, but they should solve environmental, energy and money problems. The greenhouse, in fact, is a system characterized by high energy inputs with a reduced environmental sustainability compared to extensive farming and intensive open field. In Sicily, the area dedicated to annual greenhouse cultivation is 8,200 ha with a total number of farms greater than 6,000; although the sector is of great importance in the Sicilian economy, issues as workplace, food and environmental safety are often overlooked. A survey was carried out with the aim of identifying the possibilities to improve environmental, work and food saf…