Search results for "Humic"

Humic substances along the profile of two Typic Haploxerert.

2002

In Vertisols, organic matter contributes to soil colour by formation of organo-mineral complexes and affects morphological, physico-chemical, biological and biochemical properties. Turbation may affect the chemical and structural composition of the most stabilised fractions of soil organic matter (SOM), i.e., humic substances (HS). The objectives of this study were to: (1) characterise SOM in two Vertisols (V1 and V2) developed under Mediterranean climate in Italy, using some HS characteristics as indicators of SOM turnover in Vertisols, and (2) explore possible differences related to the pedomorphologic conditions of the area under which two soils have formed. SOM evolution along the soil …

Solid state NMR spectroscopy in the evaluation of the conformational changes of humic substances as affected by thermal variations

2009

Immobilised Humic Substances as Low-Cost Sorbents for Emerging Contaminants

2021

Environmental pollution with contaminants of emerging concern (CECs) is a worldwide problem that is receiving increasing attention. Although these substances have been released in the aquatic environment for a long time, wastewater treatment plants are still incapable of removing emerging contaminants completely. Consequently, trace metals, metalloids and pharmaceuticals, as well as surfactant leftovers, are often found in environmental samples. Environmentally friendly and cost-effective sorbents such as humic substances can be used for purification if their sorption properties are increased by immobilization. To our knowledge, immobilized humic substances have not been widely studied as s…

Spectroscopic and conformational properties of size-fractions separated from a lignite humic acid

2007

Abstract A lignite humic acid (HA) was fractionated by preparative high performance size-exclusion chromatography (HPSEC) in seven different size-fractions. The size-fractions were characterized by cross polarization (CP) magic angle spinning (MAS) 13 C NMR spectroscopy and a further analytical HPSEC elution under UV and fluorescence detection. The alkyl hydrophobic components mainly distributed in the largest molecular-size-fraction, whereas the amount of oxidized carbons increased with decreasing size of fractions. Cross polarization time ( T CH ) and proton spin-lattice relaxation time in the rotating frame ( T 1 ρ (H)) were measured from variable contact time (VCT) experiments. The bulk…

Surface Activity of Humic Substances Within Peat Profile

2012

Humic substances are able to reduce the surface tension of their solutions and thus can act as surface-active substances in natural environment and possibly also for industrial applications. The ability to influence the surface tension of humic substance solutions depends on their origin. The objective of this study is a comparison of the ability of humic substances from peat profile to influence the surface tension of their solutions and identification of the structural characteristics of peat humic acids, determining their surfactant properties. Humic acids isolated from peat demonstrated significant impact of the surface tension of their solutions – they act as weak surfactants. The surf…

Influence of organic amendments on diuron leaching through an acidic and a calcareous vineyard soil using undisturbed lysimeters.

2008

9 pages; International audience; The influence of different organic amendments on diuron leaching was studied through undisturbed vineyard soil columns. Two composts (A and D), the second at two stages of maturity, and two soils (VR and Bj) were sampled. After 1 year, the amount of residues (diuron þ metabolites) in the leachates of the VR soil (0.19e0.71%) was lower than in the Bj soil (4.27e8.23%), which could be explained by stronger diuron adsorption on VR. An increase in the amount of diuron leached through the amended soil columns, compared to the blank, was observed for the Bj soil only. This result may be explained by the formation of mobile complexes between diuron and water-extrac…

Differences of stabilized organic carbon fractions and microbiological activity along Mediterranean Vertisols and Alfisols profiles

2010

This study examined the chemical and structural properties of humic substances and microbiological activity in order to verify differences in carbon dynamics along soil profiles in two Vertisols (Typic Haploxerert and Xeric Epiaquert) and two Alfisols (Mollic Haploxeralf and Ultic Haploxeralf) developed under Mediterranean climate in Italy. Humification parameters, thermal methods, including differential scanning calorimetry (DSC) and thermogravimetry (TG), together with Fourier transform infrared (FT-IR) and fluorescence spectroscopies were used to characterize humic acids (HA). Microbiological activity of soils was assessed by basal respiration, metabolic quotient (qCO2) and Cmic:Corg rat…

Suspended particulate matter fluxes along with their associated metals, organic matter and carbonates in a coastal Mediterranean area affected by min…

2016

International audience; A study of suspended particulate matter (SPM) fluxes along with their associated metals, organic matter and carbonates, was conducted off the Mejerda River outlet in May 2011 and in March and July 2012 at depths of 10, 20 and 40 m using sediment traps. SPM fluxes are more significant near the Mejerda outlet, especially in winter, but dissipate further offshore. Normalization reveals that the Mejerda is a major source of Pb, Zn, Cd, Cu, Ni, and Co, all of which are the result of human activities. In contrast, Fe, Mn and N are of authigenic origin. The enrichment factor shows that Pb, Zn and especially Cd are the most highly polluting metals off the Mejerda outlet. Thi…

Degradation of 2,4‐D, 2,4‐Dichlorophenol, and 4‐Chlorophenol in Soil after Sorption on Humified and Nonhumified Organic Matter

1999

Soil organic matter (SOM) primarily governs sorption processes and therefore affects the availability of organic chemicals to degrading microorganisms. Transformations of 14 C-ring-labeled 2,4-dichlorophenoxyacetic acid (2,4-D); 2,4-dichlorophenol (2,4-DCP); and 4-chlorophenol (4-CP) sorbed on organic materials with increasing degrees of humification (wood, fresh straw, composted straw, ligain, and humic acid) and on a reference mineral sorbent (Al-oxide) were studied during soil incubation experiments. Chemicals previously sorbed on the different sorbents were applied to the soil. Mineralization kinetics, analysis of water and methanol extracts and measurements of the nonextractable radioa…

Identification of bound alcohols in soil humic acids by gas chromatography-mass spectrometry

2000

International audience; Humic acids are complex, partly macromolecular, yellow-brownish substances occurring in soils, waters and sediments. In order to shed some light on their molecular structure, crop humic acids were cleaved by alkaline hydrolysis (KOH). The products were fractionated by thin layer chromatography to give mono-alcohols which were analysed as acetate derivatives by gas chromatography coupled to mass spectrometry. Linear alcohols, sterols, stanols and plant-derived triterpenoid alcohols were identified by co-injection of pure standards and by comparison with literature data. These findings imply that alcohols could have been incorporated into the humic matrix by esterifica…