Search results for "INFRARED"
showing 10 items of 2110 documents
Preparation and structural characterization of organotin(IV) complexes with ligands containing a hetero {N} atom and a hydroxy group or hydroxy and c…
2005
AbstractTwenty-two n-butyltin(IV) and t-butyltin(IV) complexes of ligands containing an –OH (–C@O) group or –OH and –COOHgroups and an aromatic {N} donor atom were prepared by metathetical reactions. On the basis of the FT-IR and Mo¨ssbauer spec-troscopic data, molecular structures were assigned to these compounds. The binding sites of the ligands were identified by means ofFT-IR spectroscopic measurements, and it was found that in most cases the organotin(IV) moiety reacts with the phenolic form ofthese ligands. In the complexes with –OH and –COOH functions, the –COOH group is coordinated to the organotin(IV) centres in amonodentate manner. The 119 Sn Mo¨ssbauer and the FT-IR studies suppor…
Prototyping Sentinel-2 green LAI and brown LAI products for cropland monitoring.
2022
Abstract For agricultural applications, identification of non-photosynthetic above-ground vegetation is of great interest as it contributes to assess harvest practices, detecting crop residues or drought events, as well as to better predict the carbon, water and nutrients uptake. While the mapping of green Leaf Area Index (LAI) is well established, current operational retrieval models are not calibrated for LAI estimation over senescent, brown vegetation. This not only leads to an underestimation of LAI when crops are ripening, but is also a missed monitoring opportunity. The high spatial and temporal resolution of Sentinel-2 (S2) satellites constellation offers the possibility to estimate …
Solid microcrystalline dispersion films as a new strategy to improve the dissolution rate of poorly water soluble drugs: A case study using olanzapine
2016
In this study, we evaluate the dissolution rate enhancement of solid microcrystalline dispersion (SMD) films of olanzapine (OLZ) formulated with four water-soluble polymers namely poly(N-vinylpyrrolidone) (PVP), poloxamer 188 (P188), poloxamer 407 (P407) and Soluplus(®) (SLP). Prepared formulations were characterised to determine particle size, morphology, hydrogen bonding interactions, thermal characteristics as well as in vitro dissolution studies conducted under sink conditions (pH 6.8). Particle size of OLZ in all formulations ranged between 42 and 58μm. Attenuated Total Reflectance Fourier Transform Infrared spectroscopy (ATR-FTIR), Differential Scanning Calorimetry (DSC) and Hot-Stage…
ATR-Spin: an open-source 3D printed device for direct cytocentrifugation onto attenuated total reflectance crystals.
2021
Infrared Spectroscopy (IR) enables the direct and rapid characterization of cells at the molecular level. Achieving a rapid and consistent cell preparation is critical for the development of Point-of-Care diagnostics for cell analysis. Here we introduce an open-source, 3D printed device for integrating the isolation, preconcentration, and measurement of attenuated total reflectance IR spectra of cells from biofluids. The tool comprises a disposable card for cytocentrifugation, equipped with magnets, which allows reproducible integration into the pathlength of the IR spectrophotometer. Preliminary results using cell media containing A459 cells indicate that this system enables a qualitative …
Preparation of polycrystalline TiO2 photocatalysts impregnated with various transition metal ions : characterization and photocatalytic activity for …
2002
A set of polycrystalline TiO2 photocatalysts loaded with various ions of transition metals (Co, Cr, Cu, Fe, Mo, V, and W) were prepared by using the wet impregnation method. The samples were characterized by using some bulk and surface techniques, namely X-ray diffraction, BET specific surface area determination, scanning electron microscopy, point of zero charge determination, and femtosecond pump-probe diffuse reflectance spectroscopy (PP-DRS). The samples were employed as catalysts for 4-nitrophenol photodegradation in aqueous suspension, used as a probe reaction. The characterization results have confirmed the difficulty to find a straightforward correlation between photoactivity and si…
Sublimation of icy aggregates in the coma of comet 67P/Churyumov–Gerasimenko detected with the OSIRIS cameras on board Rosetta
2016
Beginning in 2014 March, the OSIRIS (Optical, Spectroscopic, and Infrared Remote Imaging System) cameras began capturing images of the nucleus and coma (gas and dust) of comet 67P/Churyumov¿Gerasimenko using both the wide angle camera (WAC) and the narrow angle camera (NAC). The many observations taken since July of 2014 have been used to study the morphology, location, and temporal variation of the comet's dust jets. We analysed the dust monitoring observations shortly after the southern vernal equinox on 2015 May 30 and 31 with the WAC at the heliocentric distance Rh = 1.53 AU, where it is possible to observe that the jet rotates with the nucleus. We found that the decline of brightness a…
Challenges in clinical analysis by infrared spectroscopy
2014
En els últims anys, el desenvolupament de metodologies d’anàlisi clínic basades en espectroscòpia infraroja (IR) s’ha convertit en un camp molt actiu d’investigació. Millores en la instrumentació i en el processament de les dades han contribuït a que l’espectroscòpia IR s’utilitze per a obtindré informació de la composició de fluids i teixits biològics. Aquesta tesis consolida aquesta tècnica com una eina versàtil en el desenvolupament de metodologies per a extraure una gran quantitat d’informació en un ampli espectre de mostres mitjançant instrumentació senzilla, ràpida i econòmica. Tot i que la tècnica té problemes de sensibilitat i selectivitat, els resultats obtinguts en aquesta Tesi de…
Influence de la symétrie et de la taille de la molécule adsorbée sur le processus d'adsorption des composés éthyléniques sur une zéolithe de topologi…
2005
This manuscript lies within the scope of the understanding of the stepped isotherm observed during adsorption, on MFI zeolites, of some organic compounds which have a similar size to that of the pore opening of zeolite. During this work, the process of adsorption of ethylene and tetramethylethylene is initially studied by gravimetry and then by in situ infrared spectroscopy. This last technique enables to follow simultaneously the modifications of the adsorbent and the adsorbate. The analysis of these data lets suppose that the step in adsorption isotherm can be explained by taking account simultaneously of the symmetry and the size of the admolecule. In addition to the infrared bands chara…
DISTRIBUTION OF CARBON STARS IN THE GALAXY
2018
A search for new faint carbon (C) stars in the Polar region δ > 55o has been accomplished by obtaining objective prism spectra in the near infrared 550 -- 900 nm on images of CCD camera of Baldone Schmidt telescope of Astrophysical observatory. The positions of stars having color indices (J – K) > 1.3 mag in Two Micron All Sky Infrared Survey (2MASS) were selected to pick out suspicious carbon stars.Our survey is limited in brightness by J < 10 mag. 24 new carbon stars were found and their characteristics obtained. The correlative relation between Teff and spectral gradient [757 – 685] was confirmed. Such characteristics as Teff, distance from the Sun, absolute Mk were obtained…
Solid sampling Fourier transform infrared determination of Mancozeb in pesticide formulations
2004
Abstract A series of approaches have been assayed for FTIR determination of Mancozeb in several solid commercial fungicides using different calibration strategies. The simplest procedure was based on the use of the ratio between the absorbance of a characteristic band of Mancozeb and that of a KSCN internal standard measured in the FTIR spectra obtained from KBr pellets. It was employed the quotient between peak height absorbance values at 1525 cm−1 for Mancozeb and 2070 cm−1 for KSCN. In these conditions a precision as relative standard deviation (RSD) of 0.6% and a relative accuracy error of 0.8% (w/w) were found. For complex formulations, containing other compounds with characteristic ab…