Search results for "IRRADIATION"

Assessment of contamination of Salmonella spp. in imported black pepper and sesame seed and salmonella inactivation by gamma irradiation

2021

This study shows the frequency of seeds samples contaminated by Salmonella spp. collected randomly from local markets; on 30 black pepper sample no contaminated sample was found while Salmonella spp. was detected in 3 of 36 (8.3%) analyzed sesame samples; three different serotypes were identified: S. Montevideo, S. Stanleyville e S. Tilene. The efficacy of gamma irradiation to inactivate Salmonella Montevideo in black pepper and sesame irradiated between 1 and 5 kGy was evaluated. 3 kGy is sufficient to reduce of 3-4 log CFU/g; whereas 5 kGy have been need to reduce 5.5-6 log CFU/g for samples of black pepper and sesame. No statistically significant differences were found between black pepp…

Synthesis of complex organic molecules in soft x-ray irradiated ices

2019

We study the chemical evolution of H2O:CO:NH3 ice mixtures irradiated with soft X-rays, in the range 250-1250 eV. We identify many nitrogen-bearing molecules such as e.g., OCN-, NH4+ , HNCO, CH3CN, HCONH2, and NH2COCONH2. Several infrared features are compatible with glycine or its isomers. During the irradiation, we detected through mass spectroscopy many species desorbing the ice. Such findings support either the infrared identifications and reveal less abundant species with not clear infrared features. Among them, m/z = 57 has been ascribed to methyl isocyanate (CH3NCO), a molecule of prebiotic relevance, recently detected in protostellar environments. During the warm up after the irradi…

Non-conventional methods and media for the activation and manipulation of carbon nanoforms

2013

Very often, chemical transformations require tedious and long procedures, which, sometimes, can be avoided using alternative methods and media. New protocols, enabling us to save time and solvents, allow us also to explore new reaction profiles. This Tutorial Review focuses on the physical and chemical behavior of carbon nanoforms, CNFs (fullerenes, nanotubes, nanohorns, graphene, etc.) when non-conventional methods and techniques, such as microwave irradiation, mechano-chemistry or highly ionizing radiations are employed. In addition, the reactivity of CNFs in non-conventional media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed.

Functional hydrogels containing polyaniline nanoparticles through e-beam irradiation

2009

Radiation induced generation of non-bridging oxygen hole center in silica: Intrinsic and extrinsic processes

2007

Abstract The generation of non-bridging oxygen hole center ( Si–O ) was investigated in a wide variety of natural (fused quartz) and synthetic silica samples exposed to different γ- and β-irradiation doses by looking at its optical bands. We distinguish two different generation processes: intrinsic associated with the cleavage of Si–O bond and characterized by a sublinear law and extrinsic due to the conversion of OH precursor characterized by a growth curve with a saturating tendency. The interplay between the two processes and the role of H are discussed.

Growth of paramagnetic defects by gamma rays irradiation in oxygen-deficient silica

2005

Abstract We report an electron paramagnetic resonance (EPR) study of gamma rays irradiation effects on an oxygen-deficient silica obtained from fused quartz. We have found that three types of E′ centers, E α ′ , E γ ′ and E δ ′ , and a paramagnetic defect in a spin triplet state (S = 1) are induced. The EPR signals dependence on the microwave power have been investigated. The concentrations of these centers as a function of gamma ray irradiation show that for high dose a limit value is reached suggesting a generation process from precursors.

Thermo-mechanical analysis of irradiation swelling and design optimization of the IFMIF target assembly with bayonet backplate

2017

Abstract The availability of a high flux neutron source for testing candidate materials under irradiation conditions, which will be typically encountered in future fusion power reactors (ITER, DEMO, FPR), is a fundamental step towards the development of fusion energy. To this purpose, the International Fusion Materials Irradiation Facility (IFMIF) represents the reference option to provide the fusion community with a DEMO-relevant neutron source capable of irradiating samples at a damage rate of up to 20 dpa/fpy (in steel) in a volume of 0.5 l. In the framework of the engineering design activities of IFMIF, ENEA is committed in the design of the lithium target assembly (TA) with removable (…

Fuzzy fault tree analysis in modern γ-ray industrial irradiator: Use of fuzzy version of HEART and CREAM techniques for human error evaluation

2008

As well known, the lack of accurate quantitative human reliability data is a serious limitation and source of uncertainty in risk assessment. Therefore, in the last years, many Authors suggested that the use of the fuzzy sets theory can fill up this gap, performing as useful tool when dealing with qualitative or vague information. In such a framework, the present paper refers to the obtained results by using Fuzzy Fault Tree analyses of accidental scenarios which entail the potential exposure of operators working in γ-ray irradiation industrial plant. For these analyses the HEART methodology, a first generation HRA (Human Reliability Analysis) method, has been employed to evaluate the proba…

GaP/TiO2 Composite Photocatalyst for CO2 Reduction in Gas-Solid Regime under Simulated Solar Light Irradiation

2014

EPR investigations of polymeric and H2O2 -modified C3N4 -based photocatalysts

2019

The C3N4 -based nanopowders prepared by thermal condensation of melamine (MCN) with subsequent thermal etching (MCN-TE) and H2O2 -treatment were investigated by Q- and X-band EPR spectroscopy in dark and upon in situ UVA or visible-light exposure. Lorentzian signal at g = 2.003, more pronounced in the case of the thermally etched material, dominates EPR spectra of MCN and MCN-TE. More complex spectra were found for H2O2 -treated photocatalysts revealing the presence of signals attributed to the radicals produced via H2O2 interaction with C/N sites in the C3N4 polymeric network. The X-band spectra monitored upon in situ irradiation of the C3N4 -based photocatalysts evidenced the intensity gr…