Search results for "Kaolinite"
showing 10 items of 65 documents
X-ray diffraction Warren–Averbach mullite analysis in whiteware porcelains: influence of kaolin raw material
2018
ABSTRACTCompositional and microstructural analysis of mullites in porcelain whitewares obtained by the firing of two blends of identical triaxial composition using a kaolin B consisting of ‘higher-crystallinity’ kaolinite or a finer halloysitic kaolin M of lower crystal order was performed. No significant changes in the average Al2O3 contents (near the stoichiometric composition 3:2) of the mullites were observed. Fast and slow firing at the same temperature using B or M kaolin yielded different mullite contents. The Warren–Averbach method showed increase of the D110 mullite crystallite size and crystallite size distributions with small shifts to greater values with increasing firing temper…
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in th…
2017
Mineral dust and secondary organic aerosols (SOA) account for a major fraction of atmospheric particulate matter, affecting climate, air quality and public health. How mineral dust interacts with SOA to influence cloud chemistry and public health, however, is not well understood. Here, we investigated the formation of reactive oxygen species (ROS), which are key species of atmospheric and physiological chemistry, in aqueous mixtures of SOA and mineral dust by applying electron paramagnetic resonance (EPR) spectrometry in combination with a spin-trapping technique, liquid chromatography-tandem mass spectrometry (LC-MS/MS), and a kinetic model. We found that substantial amounts of ROS includi…
Environmental and climatic controls of the clay mineralogy of Albian deposits in the Paris and Vocontian basins (France)
2020
18 pages; International audience; High-resolution clay mineral analyses were performed on lower and middle Albian deposits from the Paris and Vocontian basins in order to specify the weathering conditions that prevailed at that time. The clay mineral assemblages are composed of small proportions of chlorite and vermiculitic clays associated with abundant illite, R0 type illite-smectite mixed-layers (smectite) and kaolinite. Clay minerals originated from the physical alteration and chemical weathering of rocks and soils outcropping on the Variscan massifs bordering the studied areas. In the Paris Basin, the covariation of illite and kaolinite suggests the reworking of these latter minerals f…
Conjunctive use of spectral gamma-ray logs and clay mineralogy in defining late Jurassic-early Cretaceous palaeoclimate change (Dorset, U.K.).
2006
Abstract Detrital clay mineralogy is controlled by weathered source rock, climate, transport and deposition that in turn influence the spectral gamma-ray (SGR) response of resultant sediments. Whilst a palaeoclimate signal in clay mineralogy has been established in some ancient successions, the SGR response remains contentious, largely because the data sets have yet to be collected at the same or appropriate vertical scales to allow comparison. In addition, the influence of organic matter on SGR is not always considered. Here, we present clay mineralogical, total organic carbon (TOC) and SGR analyses from the late Jurassic and early Cretaceous of the Wessex Basin, a period of previously doc…
The Mid-Cenomanian Event in southeastern France: evidence from palaeontological and clay mineralogical data.
2013
16 pages; International audience; Reconstruction of main palaeoenvironmental conditions across the Mid-Cenomanian Event (MCE I) in the hemipelagic Tethyan section of Blieux (Southeast France, Vocontian Basin) is proposed. Quantitative analyses of calcareous nannofossil, ammonoid and clay mineral assemblages have been made and compared with respect to sea level changes and the carbon cycle perturbations. The nannofossil primary productivity, as recorded by nannofossil fluxes and relative abundances of meso-eutrophic taxa, is low just below and during the MCE Ia, then slightly increases in the interval including the MCE Ib. The clay assemblages mainly consist of illite/smectite mixed-layers w…
Late Jurassic palaeoclimatic change from clay mineralogy and gamma-ray spectrometry of the Kimmeridge Clay, Dorset, UK
2009
Abstract: The Late Jurassic was a time of increasing aridity in NW Europe. Here, a new clay mineral dataset is presented from a 600 m thick composite core through the Kimmeridge Clay Formation, southern England. Clay mineral assemblages comprise mainly illite and kaolinite, with minor randomly interstratified illite–smectite mixed-layer clays. SEM observations indicate that clay minerals are mainly detrital, except in silty strata of late Tithonian age, which contain abundant pore-filling kaolinite aggregates. Th/K ratios determined from gamma-ray spectrometry mirror palaeoclimatically significant variations in kaolinite/illite ratios, with notable exception where diagenetic kaolinite occur…
Characterization of the porous structure of Chilean volcanic soils by nitrogen adsorption and mercury porosimetry
2004
Pore volume, specific surface area (SSA), and total intragranular porosity (TIP) of Chilean soils derived from volcanic materials were studied. Soil samples involving the 0-15 and 15-30 cm depth of virgin and cultivated Collipulli (Ultisol) and Diguillin (Andisol) soils at two particle size fractions (<1 mm and <2 µm) were considered. From mercury porosimetry and N2 adsorption, mainly mesopores (pore diameter, dpore, about 10 nm) were determined for <1 mm Collipulli samples. Diguillin <1 mm soil shows macroporosity with dpore from 70 nm to 7000 nm. The clay fraction of Collipulli has macropores (dpore from 2000 nm to 40000 nm) and mesopores (dpore from 3 nm to 23 nm), while for Diguillin cl…
Retention of Vanadium(V), Molybdenum(VI) and Tungsten(VI) by Kaolin
1993
Abstract The ability of kaolin (approximately H2Al2Si2O8 · H2O), a well known clay mineral constituent, to retain V(V) andMo(VI) species from 10−5 and 10−4 M solutions, and W(VI) species from 10−4 M solutions was investigated in the pH range 2–7.5 using a solid/liquid ratio 1:100 (w:v). The equilibration time in the adsorption studies was 72 h, and the shaking time in the desorption studies was 17 h. 0.02 M KCl was used as ionic medium and desorbing liquid. V(V), Mo(VI) and W(VI) were all retained by kaolin to some extent, and the amounts of the elements which could be washed away from kaolin with 0.02 M KCl were very small. The pH dependence of the adsorption was considerable: when added a…
Selective adsorption of oppositely charged PNIPAAM on halloysite surfaces: a route to thermo-responsive nanocarriers.
2018
Halloysite nanotubes were functionalized with stimuli-responsive macromolecules to generate smart nanohybrids. Poly(N-isopropylacrylamide)-co-methacrylic acid (PNIPAAM-co-MA) was selectively adsorbed into halloysite lumen by exploiting electrostatic interactions. Amine-terminated PNIPAAM polymer was also investigated that selectively interacts with the outer surface of the nanotubes. The adsorption site has a profound effect on the thermodynamic behavior and therefore temperature responsive features of the hybrid material. The drug release kinetics was investigated by using diclofenac as a non-steroidal anti-inflammatory drug model. The release kinetics depends on the nanoarchitecture of th…