Search results for "LI-ION"
showing 10 items of 17 documents
High-performing Sn-Co nanowire electrodes as anodes for lithium-ion batteries
2012
Abstract The preparation of Sn 2 Co 3 nanowire arrays (NWs) electrogrown inside the channels of polycarbonate membranes and their characterization as anodes for Li-ion batteries both in half-cell vs. Li and in battery configuration are reported. The Sn 2 Co 3 NW electrodes tested by deep galvanostatic charge/discharge cycles in ethylene carbonate-dimethylcarbonate (1:1) – LiPF 6 1 M displayed 80% capacity retention after 200 cycles at C/2 and 30 °C, and a high charge and discharge rate capability at C-rate from C/3 (0.33 A/g) to 10C (10 A/g) at 30° and 10 °C. Electrodes with the highest alloy loading delivered up to 0.6 mAh cm −2 at C/2. The performance of these electrodes in battery config…
Toward Tin-Based High-Capacity Anode for Lithium-Ion Battery
2014
Electrochemical deposition of SnCo alloys inside the nanometric pores of commercial membranes is described. Composition, morphology and crystallographic structure of the synthesized nanostructured alloys are reported as well as the results of electrochemical tests carried out both in half-cell and in full battery configuration to investigate the performance of these SnCo alloys as anodes for lithium-ion batteries. Optimized depositions yielded nanostructured alloys that performed 200 deep galvanostatic cycles at C/2 and 30 °C with 80 % capacity retention and coulombic efficiency higher than 97 % after 40 cycles Moreover, charge-discharge rate capability tests showed the high performance of …
Modelling, simulation and characterization of Li-Ion battery cell
2019
The decarbonizing process of the transportation system and the spread of unplanned renewables energy source, such as photovoltaic and wind energies, brought the constant need of ever more efficient energy storage technologies. Among these technologies, batteries, particularly the li-ion chemistry, are widely used in automotive and energy storage applications. For an optimized management of the cell it is advisable to have models that can accurately describe cell behaviour. In this paper a battery model for performance simulation in automotive application is identified. The main shapes of battery cells with their own advantages and disadvantages are shown, and a roundup of the best available…
Technical-economical evaluation for distributed storage applications. An Italian case study for a medium-scale public facility
2014
Time-of-use energy cost management involves the use of storage by customers to reduce their electricity bills. This can be accomplished by charging the storage during off-peak time periods, when electricity energy prices are low, and discharging it during times when on-peak energy prices are applied. This article addresses the question whether it is economically viable to install medium-scale distributed storage devices in the power system designed to lower the electricity cost for a customer-side application, assuming flexible electricity tariffs. The technical/economical evaluation is carried out referring to Lithium ion (Li-ion), Sodium Sulphur (NaS) and Vanadium Redox Battery (VRB) tech…
A comparison of two innovative customer power devices for Smart Micro-Grids
2015
The paper presents a comparison of two prototypes of innovative Customer Power Devices designed for applications in Smart Micro-Grids. The devices are both equipped with Energy Storage Systems, consisting in Lithium batteries and have been assembled, independently, by the DIAEE of the University of Rome 'La Sapienza' and the DEIM of the University of Palermo in collaboration with the Italian National Agency for New Technologies, Energy and Sustainable Economic Development (ENEA). In the paper, the characteristics and the operating modes of the devices are examined and some consideration on their application in Low Voltage Smart Micro-Grids are provided. © 2015 IEEE.
Sensitive magnetometry reveals inhomogeneities in charge storage and weak transient internal currents in Li-ion cells
2020
The ever-increasing demand for high-capacity rechargeable batteries highlights the need for sensitive and accurate diagnostic technology for determining the state of a cell, for identifying and localizing defects, and for sensing capacity loss mechanisms. Here, we leverage atomic magnetometry to map the weak induced magnetic fields around Li-ion battery cells in a magnetically shielded environment. The ability to rapidly measure cells nondestructively allows testing even commercial cells in their actual operating conditions, as a function of state of charge. These measurements provide maps of the magnetic susceptibility of the cell, which follow trends characteristic for the battery materia…
Ab initio calculations of Li2(Co, Mn)O8 solid solutions for rechargeable batteries
2019
The presented study has been financed via the Latvian Science Council Grant No. 2018/2-0083. The author is grateful to Professors M. R. Philpott, G. Ceder and G. Borstel for many stimulating discussions during his work at Singapore. We performed all our ab initio calculations at North German Parallel Computer Center located at Hannover (HLRN).
Wood and Black Liquor-Based N-Doped Activated Carbon for Energy Application
2021
The research was funded by the Latvian Council of Science project “Nanostructured Nitrogenated Carbon Materials as Promoters in Energy Harvesting and Storage Technologies”, project No LZP-2018/1-0194, “New biomass origin materials hybrid carbon composites for energy storage” project No LZP-2020/2-0019 and postdoc project “Nitrogen and phosphorus-containing biomass based activated carbons for fuel cells and supercapacitors” project No 1.1.1.2/VIAA/4/20/596.
INTERPRETATION OF POTENTIAL INTERMITTENCE TITRATION TECHNIQUE EXPERIMENTS FOR VARIOUS Li-INTERCALATION ELECTRODES
2002
In this paper we compare two different approaches for the calculation of the enhancement factor Wi , based on its definition as the ratio of the chemical and the component diffusion coefficients for species in mixed-conduction electrodes, originated from the “dilute solution” or “lattice gas” models for the ion system. The former approach is only applicable for small changes of the ion concentration while the latter allows one to consider a broad range of intercalation levels. The component diffusion coefficient of lithium ions has been determined for a series of lithium intercalation anodes and cathodes. A new “enhancement factor” for the ion transport has been defined and its relations to…
Effect of doping and crystallite size on the electrochemical performance of Li4Ti5O12
2016
Abstract Defect spinel phase lithium titanate (Li 4 Ti 5 O 12 ) has been suggested as a promising negative electrode material for next generation lithium ion batteries. Flame spray pyrolysis has been shown to be a viable fast, one-step process for synthesis of nanoparticulate Li 4 Ti 5 O 12 . However, due to the rapid quenching that is integral to the process the crystallite size remain very small and non-uniform. To overcome this shortcoming a vertical flow tube furnace was used to increase the high-temperature residence time. This resulted in an increase in the crystallite size and crystallinity of the product. As a result of this increase the electrochemical performance of the Li 4 Ti 5 …