Search results for "LIMIT"
showing 10 items of 2826 documents
Crónica de una pandemia: confinamiento en Castelló de la Plana, España
2021
Este artículo presenta los resultados de una investigación comenzada a raíz de la declaración del estado de alarma en España (Real Decreto [RD] No. 463/2020, de 14 de marzo) después que la Organización Mundial de la Salud (OMS) declarase la enfermedad por coronavirus 2019 (COVID-19) como pandemia el día 11 de marzo de 2020. Este decreto limitaba la libre circulación de las personas, así como el derecho de reunión, tanto en lugares públicos como privados, además de imponer la obligatoriedad de mantener una distancia de seguridad entre los individuos y la limitación del aforo en aquellos establecimientos que permanecían abiertos, entre otras medidas. Todo ello supuso un cambioen las rutinas d…
Bounding principles for elastic-plastic-creeping solids loaded below and above the shakedown limit
1982
Solids of elastic-perfectly plastic creeping material subjected to variable loads are considered within the infinitesimal displacement framework and a bounding principle is presented which holds below and above the shakedown limit. Through the choice of some free parameters, this principle generates a number of deformation bounds with practical meanings, some of wich coincide with known results for creeping and noncreeping material, while others constitute new results or generalizations of known results. The topic will be further studied in a subsequent paper [35].
High Nitrogen Removal in a Constructed Wetland Receiving Treated Wastewater in a Cold Climate
2018
Constructed wetlands provide cost-efficient nutrient removal, with minimal input of human labor and energy, and their number is globally increasing. However, in northern latitudes, wetlands are rarely utilized, because their nutrient removal efficiency has been questioned due to the cold climate. Here, we studied nutrient retention and nitrogen removal in a boreal constructed wetland (4-ha) receiving treated nitrogen-rich wastewater. On a yearly basis, most of the inorganic nutrients were retained by the wetland. The highest retention efficiency was found during the ice-free period, being 79% for ammonium-nitrogen (NH4+-N), 71% for nitrate-nitrogen (NO3--N), and 88% for phosphate-phosphorus…
Indoor air quality in schools of a highly polluted south Mediterranean area
2019
This study aimed at surveying lower secondary schools in southern Italy, in a highly polluted area. A community close to an industrial area and three villages in rural areas was investigated. Indoor temperature, relative humidity (RH), gaseous pollutants (CO 2 and NO 2 ), selected biological pollutants in indoor dust, and the indoor/outdoor mass concentration and elemental composition of PM 2.5 were ascertained. Temperature and RH were within, or close to, the comfort range, while CO 2 frequently exceeded the threshold of 1000 ppm, indicating inadequate air exchange rate. In all the classrooms, median NO 2 levels were above the WHO threshold value. Dermatophagoides p. allergen concentration…
La delimitación de los espacios marítimos españoles
2000
I. INTRODUCCIÓN. II. LAS DELIMITACIONES PACTADAS. 1. Delimitaciones pactadas con Francia. 1.1. Delimitación de las aguas interiores en la desembocadura del Río Bidasoa y en la Bahía de Higuer. 1.2. Delimitación del mar territorial hispano-francés en el Golfo de Vizcaya (o de Gascuña). 1.3. Delimitación de la plataforma continental en el Golfo de Vizcaya (o de Gascuña). 2. Delimitación de la plataforma continental hispano-italiana en el Mar Mediterráneo. 3. Delimitación del mar territorial hispano-portugués en la desembocadura del Río Miño. III. LAS DELIMITACIONES PENDIENTES DE SOLUCIÓN. 1. La delimitación inacabada de los espacios marítimos en el Golfo de Vizcaya. 2. Problemas de delimitaci…
Ultrahigh-Resolution Mass Spectrometry in Real Time: Atmospheric Pressure Chemical Ionization Orbitrap Mass Spectrometry of Atmospheric Organic Aeros…
2018
The accurate and precise mass spectrometric measurement of organic compounds in atmospheric aerosol particles is a challenging task that requires analytical developments and adaptations of existing techniques for the atmospheric application. Here we describe the development and characterization of an atmospheric pressure chemical ionization Orbitrap mass spectrometer (APCI-Orbitrap-MS) for the measurement of organic aerosol in real time. APCI is a well-known ionization technique, featuring minimal fragmentation and matrix dependencies, and allows rapid alternation between the positive and negative ionization mode. As a proof of principle, we report ambient organic aerosol composition in rea…
Rapid evaluation of ammonium in different rain events minimizing needed volume by a cost-effective and sustainable PDMS supported solid sensor.
2020
Abstract The presence of ammonium ion in rainwater is due to atmospheric processes which involve its scavenging from gas phase and particulate matter. The fractionated samplings of rainwater can provide information about these processes and their potential sources. However, only a low sample volume may be available, which constrained the analysis in general and more particularly in situ mode. For minimizing this limitation, this work proposes a polydimethylsiloxane (PDMS)-salicylate sensor that produces a color change. The embedding of solid reagents into PDMS was optimized. Good analytical characteristics (analysis time of 10 min, sample volume of 500 μL, limit of detection 0.03 μgmL−1) we…
Flow injection near-infrared determination of ethanol in chloroform
1995
A simple and direct flow injection (FIA) procedure has been developed for the determination of the stabilizing agent ethanol in chloroform samples. The procedure is based on the use of the absorbance band of ethanol in the near-infrared (NIR) region at 2272 nm, measured in front of a reference sample of chloroform stabilized with amylene. The method developed provides a limit of detection of 0.0045% (v/v) and a dynamic range until 10% (v/v) with a typical variation coefficient of 0.4% for six independent analysis of a real sample containing approximately 1% (v/v) of ethanol. The sample injection frequency allowed by the method is 78 h−1.
Comparative study of reflectance cells for PLS-FTIR determination of sugars in soft drinks
1998
A comparative study has been carried out between a horizontal Attenuated Total Reflectance (h-ATR) cell and a Cylindrical Internal Reflection (CIR) cell (CIRCLE cell). Both cells were employed for the determination of glucose, fructose, sucrose and total sugar in soft drinks and fruit juices using absorbance measurements at two resolution values (4 and 8 cm–1). Data were processed by Partial Least Squares regression (PLS). Using a resolution of 4 cm–1, mean relative errors of prediction from 0.6% to 1.3% were obtained using the horizontal-ATR and from 0.6% to 2.8% using the CIRCLE cell resulting in a limit of detection from 0.03% in the case of sucrose to 0.21% for total sugar for the h-ATR…
Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF
2017
Abstract We developed a simple self-chemical optical sensor for the monitoring and removal of ultra-trace levels of Hg(II) from aqueous media. The development of this sensor was based on the covalent attachment of amino-functionalized aluminum-based MOF particles with ninhydrin. The new sensor is densely coated with a chelating ligand to permit an ultra-fast, selective, pH-dependent visualization for removal of Hg(II) with detection limit (LOD∼0.494 μg L−1). Monitoring was accomplished via both a colorimetric signal visible to the naked eye as well as UV–vis absorption spectroscopy. Digital image-based colorimetric analysis has also used as a semi-quantitative analysis for determination the…