Search results for "Lability"

Framework for complex quantum state generation and coherent control based on on-chip frequency combs

2018

Integrated frequency combs introduce a scalable framework for the generation and manipulation of complex quantum states (including multi-photon and high-dimensional states), using only standard silicon chip and fiber telecommunications components.

Run-time scalable NoC for FPGA based virtualized IPs

2017

The integration of virtualized FPGA-based hardware accelerators in a cloud computing is progressing from time to time. As the FPGA has limited resources, the dynamic partial reconfiguration capability of the FPGA is considered to share resources among different virtualized IPs during runtime. On the other hand, the NoC is a promising solution for communication among virtualized FPGA-based IPs. However, not all the virtualized regions of the FPGA will be active all the time. When there is no demand for virtualized IPs, the virtualized regions are loaded with blank bitstreams to save power. However, keeping active the idle components of the NoC connecting with the idle virtualized regions is …

Scalable and Selective Preparation of 3,3′,5,5′-Tetramethyl-2,2′-biphenol

2016

Biphenols are indispensable building blocks in ligand systems for organic catalysis. 3,3′5,5′-Tetramethyl-2,2′-biphenol is a particular versatile motif in different catalytic systems. We developed an easy to perform and scalable process to give access to large quantities of this important building block by the use of selenium dioxide, a common and readily available oxidizer.

The [Pd(bipy)]2+ “merry-go-round”: Insights into the lability of the Pd–N bond

2009

Abstract Two tripods (1 and 2) featuring pyrimidinyl pendant arms have been synthesized from 5-(1H-pyrazol-3-yl)-pyrimidine (5) and 1,3,5-tribromomethylbenzene derivatives. Reaction with three equivalents of [Pd(bipy)](NO3)2 to form a macrotricycle closed by palladium coordination unexpectedly afforded the mononuclear species [Pd(1)(bipy)]2+ and [Pd(2)(bipy)]2+. These complexes show fluxional behavior on the 1H NMR timescale, the [Pd(bipy)]2+ fragment hopping between the pyrimidinyl coordinating moieties. The ΔGc‡’s estimated by the coalescence method are temperature independent, which means that ΔSc‡ = 0. This indicates that the “merry-go-round” process of [Pd(bipy)]2+ occurs intramolecula…

Multispectral high resolution sensor fusion for smoothing and gap-filling in the cloud

2020

Remote sensing optical sensors onboard operational satellites cannot have high spectral, spatial and temporal resolutions simultaneously. In addition, clouds and aerosols can adversely affect the signal contaminating the land surface observations. We present a HIghly Scalable Temporal Adaptive Reflectance Fusion Model (HISTARFM) algorithm to combine multispectral images of different sensors to reduce noise and produce monthly gap free high resolution (30 m) observations over land. Our approach uses images from the Landsat (30 m spatial resolution and 16 day revisit cycle) and the MODIS missions, both from Terra and Aqua platforms (500 m spatial resolution and daily revisit cycle). We implem…

Controlled time integration for the numerical simulation of meteor radar reflections

2016

We model meteoroids entering the Earth[U+05F3]s atmosphere as objects surrounded by non-magnetized plasma, and consider efficient numerical simulation of radar reflections from meteors in the time domain. Instead of the widely used finite difference time domain method (FDTD), we use more generalized finite differences by applying the discrete exterior calculus (DEC) and non-uniform leapfrog-style time discretization. The computational domain is presented by convex polyhedral elements. The convergence of the time integration is accelerated by the exact controllability method. The numerical experiments show that our code is efficiently parallelized. The DEC approach is compared to the volume …

Modelling and Analysis of Flow Rate and Pressure Head in Pipelines

2019

Currently, various approaches with several utilities are proposed to identify damage in the pipeline. The pipeline system is modeled in the form of a distributed parameter system, such that the state space related to the distributed parameter system contains infinite dimension. In this paper, a novel technique is proposed to analyze and model the flow in the pipeline. Important theorems are proposed for testing the observability as well as controllability of the proposed model.

Cloud detection on the Google Earth engine platform

2017

The vast amount of data acquired by current high resolution Earth observation satellites implies some technical challenges to be faced. Google Earth Engine (GEE) platform provides a framework for the development of algorithms and products built over this data in an easy and scalable manner. In this paper, we take advantage of the GEE platform capabilities to exploit the wealth of information in the temporal dimension by processing a long time series of satellite images. A cloud detection algorithm for Landsat-8, which uses previous images of the same location to detect clouds, is implemented and tested on the GEE platform.

2021

Abstract Contaminated soils are lands in Europe deemed less favourable for conventional agriculture. To overcome the problem of their poor fertility, bio-fertilization could be a promising approach. Soil inoculation with a choice of biological species (e.g. earthworm, mycorrhizal fungi, diazotroph bacteria) can be performed in order to improve soil properties and promote nutrients recycling. However, questions arise concerning the dynamics of the contaminants in an inoculated soil. The aim of this study was to highlight the soil-plant-earthworm interactions in the case of a slightly contaminated soil. For this purpose, a pot experiment in controlled conditions was carried out during 2 month…

Bioavailable 87Sr/86Sr in different environmental samples — Effects of anthropogenic contamination and implications for isoscapes in past migration s…

2012

(87)Sr/(86)Sr reference maps (isoscapes) are a key tool for investigating past human and animal migrations. However, there is little understanding of which biosphere samples are best proxies for local bioavailable Sr when dealing with movements of past populations. In this study, biological and geological samples (ground vegetation, tree leaves, rock leachates, water, soil extracts, as well as modern and archeological animal teeth and snail shells) were collected in the vicinity of two early medieval cemeteries ("Thuringians", 5-6th century AD) in central Germany, in order to characterize (87)Sr/(86)Sr of the local biosphere. Animal tooth enamel is not appropriate in this specific context t…