Search results for "Least Squares"
showing 10 items of 268 documents
Partial least squares-near infrared determination of pesticides in commercial formulations
2007
Abstract A solvent free, fast and environmentally friendly near infrared-based methodology (NIR) was developed for pesticide determination in commercially available formulations. This methodology was based on the direct measurement of the diffuse reflectance spectra of solid samples and a multivariate calibration model (partial least squares, PLS) to determine the active principle concentration in commercial formulations. The PLS calibration set was built on using the spiked samples by mixing different amounts of pesticide standards and powdered samples. Buprofezin, Diuron and Daminozide were used as test analytes. Concentration of Buprofezin in the samples was calculated employing a 4-fact…
Quantitative Transfer Function Approaches in Palaeoclimatic Reconstruction Using Quaternary Ostracods
2012
Abstract Quantifying (palaeo-)environmental changes is a key challenge for aquatic biological proxies, but the number of published transfer functions is increasing rapidly for the main palaeoecologically relevant groups such as diatoms and chironomids, and several transfer functions have also been developed during the past decades based on ostracod findings. The main environmental variables influencing the species assemblage composition in ostracod training sets are specific ion concentrations or ratios, salinity, water temperature and/or water depth. The available transfer functions and training sets are globally scattered, but often regionally restricted in their application. The most com…
Fast nonstationary preconditioned iterative methods for ill-posed problems, with application to image deblurring
2013
We introduce a new iterative scheme for solving linear ill-posed problems, similar to nonstationary iterated Tikhonov regularization, but with an approximation of the underlying operator to be used for the Tikhonov equations. For image deblurring problems, such an approximation can be a discrete deconvolution that operates entirely in the Fourier domain. We provide a theoretical analysis of the new scheme, using regularization parameters that are chosen by a certain adaptive strategy. The numerical performance of this method turns out to be superior to state-of-the-art iterative methods, including the conjugate gradient iteration for the normal equation, with and without additional precondi…
Multivariate Methods Based Soft Measurement for Wine Quality Evaluation
2014
Published version of an article in the journal: Abstract and Applied Analysis. Also available from the publisher at: http://dx.doi.org/10.1155/2014/740754 Open Access Soft measurement is a new, developing, and promising industry technology and has been widely used in the industry nowadays. This technology plays a significant role especially in the case where some key variables are difficult to be measured by traditional measurement methods. In this paper, the quality of the wine is evaluated given the wine physicochemical indexes according to multivariate methods based soft measurement. The multivariate methods used in this paper include ordinary least squares regression (OLSR), principal c…
Experimental determination of mode I fracture parameters in orthotropic materials by means of Digital Image Correlation
2020
Abstract The mode I fracture parameters for an orthotropic body are directly calculated from full-field deformation measurements provided by Digital Image Correlation (DIC). Three complementary and direct approaches are evaluated and compared: (i) the determination of the Stress Intensity Factor (SIF) by fitting the displacement field using the analytical expression proposed by Lekhnitskii; (ii) the determination of the J-Integral by using the Energy Domain Integral (EDI) formulation on the raw DIC data; and (iii) the calculation of the J-Integral using the EDI approach on the displacement data fitted using Lekhnitskii’s formulation. A comparative experimental study is performed by testing …
Engagement with Travel Web Sites and the Influence of Online Comparative Behaviour
2015
We propose a Web site engagement measurement, and study the influence of potential antecedents and consequences. Utilising partial least squares path modeling, we contrast a model with data obtained from respondents choosing a holiday in the Seychelles, on a Web site capable of tracing online within-page and within-site behaviour.
Naturally constrained reduced form and stuctural parameters estimation
1988
To characterize such a situation, we introduce the concept of a "natural constraint", which is presented and discussed is section 1 of the present paper. Section 2 is concerned with the efficient estimation of the naturally constrained reduced form. From it, we derive efficient estimators of the structural parameters (by indirect GLS) and propose a simple test of the a priori restrictions. In section 3 we discuss estimation by 2SLS. In addition to the resultsobtained by Turkington and Pesaran, we develop a 2SLS-GLS estimator and assess its asymptotic properties. Several full information estimatorsof the 3SLS type are presented and compared in section 4 and some efficiency aspects of the ins…
Categorization of chlordecone potential transformation products to predict their environmental fate
2016
EABIOmE; Chlordecone (C10Cl10O; CAS number 143-50-0) has been used extensively as an organochlorine insecticide but is nowadays banned and listed on annex A in The Stockholm Convention on Persistent Organic Pollutants (POPs). Although experimental evidences of biodegradation of this compound are scarce, several dechlorination products have been proposed by Dolfing et al. (2012) using Gibbs free energy calculations to explore different potential transformation routes. We here present the results of an in silico classification (TyPol similar to Typology of Pollutants) of chlordecone transformation products (TPs) based on statistical analyses combining several environmental endpoints and struc…
Economic Returns to Education in France: OLS and Instrumental Variable Estimations
2013
En ligne sur : http://121.52.153.179/JOURNAL/LJE%20VOL%2018-2/Bhatti,%20Bourdon%20and%20Aslam.pdf; International audience; This article estimates the economic returns to schooling as well as analyzing other explanatory factors for the French labor market. It addresses the issue of endogeneity bias and proposes two new instruments for use in the instrumental variable two-stage least squares technique. Our results show that the proposed instruments are relevant and adequate, based on evidence from the available literature. After using the proposed instruments, we find that the OLS coefficients for schooling are biased downwards. Finally, we choose between the two proposed instruments.
Classification of persimmon fruit origin by near infrared spectrometry and least squares-support vector machines
2014
Abstract The main objective of this work has been the authentication by Fourier transform near infrared (FT-NIR) spectrometry of the origin of persimmon fruits cultivated in different regions of Spain. In order to achieve this goal, 166 persimmon samples from 7 different regions of Spain were analyzed by FT-NIR spectrometry. By splitting the spectral data in training and independent test sets, a classification model was built using least squares support vector machines chemometric technique. Orthogonal signal correction and principal component analysis were performed prior to conduct the classification strategy. The verified model was applied for the prediction of the origin of 50 samples f…