Search results for "Ligo"

showing 10 items of 1427 documents

The analysis of modified peroxisome proliferator responsive elements of the peroxisomal bifunctional enzyme in transfected HepG2 cells reveals two re…

1995

AbstractPeroxisome proliferators (PPs) are non-genotoxic carcinogens in rodents. They can induce the expression of numerous genes via the heterodimerization of two members of the steroid hormone receptor superfamily, called the peroxisome proliferator-activated receptor (PPAR) and the 9-cis retinoic acid receptor (RXR). Many of the PP responsive genes possess a peroxisome proliferator response element (PPRE) formed by two TGACCT-related motifs. The bifunctional enzyme (HD) PPRE contains 3 such motifs, creating DR1 and DR2 sequences. PPAR and RXR regulate transcription via the DR1 element while DR2 modulates the expression of the gene via auxiliary factors in HepG2 cells.

Peroxisome proliferator-activated receptor gammaReceptors Retinoic AcidSteroid hormone receptorMolecular Sequence DataResponse elementBiophysicsReceptors Cytoplasmic and NuclearPeroxisome proliferator-activated receptorchemical and pharmacologic phenomenaIn Vitro TechniquesRegulatory Sequences Nucleic AcidRetinoid X receptorBiologyPeroxisomal Bifunctional EnzymeTransfectionMicrobodiesBiochemistryGene Expression Regulation EnzymologicTranscriptional activationPeroxisomal Bifunctional EnzymeMultienzyme ComplexesStructural BiologyPeroxisome proliferator response element9-cis Retinoic acid receptor alphaTumor Cells CulturedGeneticsHumansRNA MessengerIsomerasesEnoyl-CoA HydrataseMolecular Biologychemistry.chemical_classificationBinding SitesBase Sequence3-Hydroxyacyl CoA DehydrogenasesPeroxisome proliferator-activated receptorCell BiologyDNA-Binding ProteinsRetinoic acid receptorRetinoid X ReceptorsLiverOligodeoxyribonucleotidesBiochemistrychemistryRat peroxisomal enoyl-CoA hydratase/3-hydroxyacyl-CoA dehydrogenaseEnzyme InductionPeroxisome proliferator-activated receptor alphaTranscription FactorsFEBS Letters
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Flexibility of phenylene oligomers revealed by single molecule spectroscopy

2006

The rigidity of a p-phenylene oligomer (p-terphenyl) has been investigated by single molecule confocal fluorescence microscopy. Two different rylene diimide dyes attached to the terminal positions of the oligomer allowed for wavelength selective excitation of the two chromophores. In combination with polarization modulation the spatial orientation of the transition dipoles of both end groups could be determined independently. We have analyzed 597 single molecules in two different polymer hosts, polymethylmethacrylate and Zeonex. On average we find a 22 degrees deviation from the linear gas phase geometry (T = 0 K), indicating a rather high flexibility of the p-phenylene oligomer independent…

Persistence lengthAnalytical chemistryGeneral Physics and AstronomyChromophoreOligomerchemistry.chemical_compoundCrystallographyMolecular geometrychemistryDiimidePhenyleneMoleculeDensity functional theoryPhysical and Theoretical ChemistryThe Journal of Chemical Physics
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A methacrylic hyaluronic acid derivative for potential application in oral treatment of celiac disease.

2017

Objective: Aim of this work was the synthesis of a methacrylic hyaluronic acid (HA) derivative and the production, via photocrosslinking, of related hydrogels loaded with an endopeptidase intended for a potential oral treatment of celiac disease. Methods: The methacrylic derivative of HA was prepared through a one-pot procedure involving the reaction with ethylenediamine (EDA) and methacrylic anhydride (MA). The obtained derivative, named HA-EDA-MA, was used to prepare photocrosslinked hydrogels loaded with a prolyl endopeptidase derived from Flavobacterium meningosepticum (PEP FM) able to detoxify gliadin. Obtained hydrogels were recovered as gels or freeze-dried powders. Results: Hydrogel…

Pharmaceutical ScienceMethacrylic anhydrideprolyl endopeptidaseEthylenediamineAdministration OralEthylenediamine02 engineering and technologyMethacrylate010402 general chemistryMethacrylate01 natural sciencescomplex mixtureschemistry.chemical_compoundMiceProlyl endopeptidaseoral enzyme releaseDrug DiscoveryHyaluronic acidmedicineOrganic chemistryAnimalsHumansHyaluronic AcidPharmacologyChemistryAnimalDrug Discovery3003 Pharmaceutical ScienceOrganic ChemistrySerine Endopeptidasestechnology industry and agricultureUV irradiationHydrogels021001 nanoscience & nanotechnologyEthylenediaminesEndopeptidase0104 chemical sciencesSerine EndopeptidaseHydrogelCeliac DiseaseSelf-healing hydrogelsMethacrylates0210 nano-technologyProlyl OligopeptidasesDerivative (chemistry)Nuclear chemistrymedicine.drugHumanDrug development and industrial pharmacy
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Mechanism of action of Rhodiola, salidroside, tyrosol and triandrin in isolated neuroglial cells: An interactive pathway analysis of the downstream e…

2014

Abstract Aim The aim of this study was to identify the targets (genes, interactive signaling pathways, and molecular networks) of Rhodiola rosea extract in isolated neuroglia cells and to predict the effects of Rhodiola extract on cellular functions and diseases. In addition, the potential mechanism of action of Rhodiola rosea extract was elucidated, and the “active principle” among the three isolated constituents (salidroside, triandrin, and tyrosol) was identified. Methods Gene expression profiling was performed using the T98G human neuroglia cell line after treatment with the Rhodiola rosea SHR-5 extract and several of its individual constituents (salidroside, triandrin and tyrosol). An …

Pharmaceutical SciencePharmacologyCell Linechemistry.chemical_compoundGlucosidesPhenolsDrug DiscoveryRhodiolaHumansGeneOligonucleotide Array Sequence AnalysisPharmacologybiologyPlant ExtractsMicroarray analysis techniquesGene Expression ProfilingSalidrosideErythropoietin-producing hepatocellular (Eph) receptorPhenylethyl Alcoholbiology.organism_classificationGene expression profilingRhodiola roseaGene Expression RegulationComplementary and alternative medicinechemistryMolecular MedicineRhodiolaSignal transductionTranscriptomeNeurogliaSignal TransductionPhytomedicine
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Mitochondrial function and energy metabolism in neuronal HT22 cells resistant to oxidative stress

2014

Background and Purpose The hippocampal cell line HT22 is an excellent model for studying the consequences of endogenous oxidative stress. Extracellular glutamate depletes cellular glutathione by blocking the glutamate/cystine antiporter system xc−. Glutathione depletion induces a well-defined programme of cell death characterized by an increase in reactive oxygen species and mitochondrial dysfunction. Experimental Approach We compared the mitochondrial shape, the abundance of mitochondrial complexes and the mitochondrial respiration of HT22 cells, selected based on their resistance to glutamate, with those of the glutamate-sensitive parental cell line. Key Results Glutamate-resistant mitoch…

PharmacologyOligomycinATP synthaseCellular respirationOxidative phosphorylationMitochondrionBiologymedicine.disease_causechemistry.chemical_compoundMitochondrial permeability transition poreBiochemistrychemistrymedicinebiology.proteinATP–ADP translocaseOxidative stressBritish Journal of Pharmacology
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Molecular Motion, Defect Structures and Phase Transitions in Oligomer Crystals

1983

Defect structures in the high temperature modifications of oligomer crystals can generally be discribed as a superposition of chain rotations, longitudinal shifts of the molecules and the occurrence of conformational defects. Applying a suitable combination of experimental techniques it is possible to discriminate between the different components of disorder. This is demonstrated in a discussion of results obtained on n-alkanes, cycloalkanes and perfluoro-n-alkanes.

Phase transitionSuperposition principleCrystallographychemistry.chemical_compoundChain (algebraic topology)ChemistryGeneral Chemical EngineeringMolecular motionMoleculeOligomerBerichte der Bunsengesellschaft für physikalische Chemie
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Phosphatidylinositol-3-kinase activity during in vitro dendritic cell generation determines suppressive or stimulatory capacity.

2011

Modulating PI3K at different stages of dendritic cells (DC) generation could be a novel means to balance the generation of immunosuppressive versus immunostimulatory DC. We show that PI3K inhibition during mouse DC generation in vitro results in cells that are potently immunosuppressive and characteristic of CD8alpha- CD11c+ CD11b+ DC. These DC exhibited low surface class I and class II MHC, CD40, and CD86 and did not produce TNF-alpha. In allogeneic MLR, these DC were suppressive. Although in these mixed cultures, there was no increase in the frequency of CD4+ CD25+ Foxp3+ cells, the Foxp3 content on a per cell basis was significantly increased. Sustained TLR9 signaling in the presence of …

Phosphatidylinositol-3-kinaseSignaling.TLROligonucleotidesImmunoregulationDendritic cells
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Phosphorylation of GAP-43 (growth-associated protein of 43 kDa) by conventional, novel and atypical isotypes of the protein kinase C gene family: dif…

1996

GAP-43 (growth-associated protein of 43 kDa; also known as neuromodulin, P-57, B-50 and F-1) is a neuronal calmodulin binding protein and a major protein kinase C (PKC) substrate in mammalian brain. Here we describe the phosphorylation by and the site specificity of different PKC isotypes. The conventional PKC beta 1 and the novel PKCs delta and epsilon effectively phosphorylated recombinant GAP-43 in vitro; atypical PKC zeta did not. The K(m) values (between 0.6 and 2.3 microM) were very low, demonstrating a high-affinity interaction between kinase and substrate. All PKC isotypes were shown to phosphorylate serine-41 in GAP-43. When using a 19-amino-acid oligopeptide based on the GAP-43 ph…

PhosphopeptidesCalmodulinMolecular Sequence DataNerve Tissue ProteinsPeptidePeptide MappingBiochemistrySubstrate SpecificityGAP-43 ProteinAmino Acid SequencePhosphorylationGap-43 proteinMolecular BiologyProtein Kinase CProtein kinase Cchemistry.chemical_classificationOligopeptideMembrane GlycoproteinsbiologyKinaseBinding proteinCell BiologyMolecular biologyRecombinant ProteinsIsoenzymesKineticsBiochemistrychemistryMultigene Familybiology.proteinPhosphorylationPeptidesOligopeptidesResearch ArticleBiochemical Journal
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Pathogen-Mimicking MnO Nanoparticles for Selective Activation of the TLR9 Pathway and Imaging of Cancer Cells

2009

Here, design of the first pathogen-mimicking metal oxide nanoparticles with the ability to enter cancer cells and to selectively target and activate the TLR9 pathway, and with optical and MR imaging capabilities, is reported. The immobilization of ssDNA (CpG ODN 2006) on MnO nanoparticles is performed via the phosphoramidite route using a multifunctional polymer. The multifunctional polymer used for the nanoparticle surface modification not only affords a protective organic biocompatible shell but also provides an efficient and convenient means for loading immunostimulatory oligonucleotides. Since fluorescent molecules are amenable to photodetection, a chromophore (Rhodamine) is introduced …

PhosphoramiditeMaterials scienceOligonucleotideNanoparticleNanotechnology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciences0104 chemical sciencesElectronic Optical and Magnetic MaterialsBiomaterialsRhodaminechemistry.chemical_compoundchemistryCancer cellElectrochemistryBiophysicsSurface modification0210 nano-technologyDrug carrierBiosensorAdvanced Functional Materials
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Antisense Phosphorothioate Oligonucleotides to the p65 Subunit of NF-κB Abrogate Fulminant Septic Shock Induced byS. typhimuriumin Mice

2001

The aim of this study was to characterize the functional relevance of the transcription factor NF-κB in the pathogenesis of septic shock. BALB/c mice were infected with two wild-type (WT 1, WT 2) strains of S. typhimurium that induce NF-κB or an escape variant that lacks this ability (P21) at a dose of 1 × 109/animal, respectively. Furthermore, wild-type infected mice were treated with antisense oligonucleotides directed against NF-κB 24 h before and 3 or 6 h after infection, while mismatched oligonucleotides were used as controls. Subsequently, the clinical course, histological and immunological alterations were monitored. Infection with WT 1 and WT 2 strains led to lethal septic shock wit…

Phosphorothioate OligonucleotidesNecrosisSeptic shockFulminantImmunologyInterleukinGeneral MedicineBiologymedicine.diseaseVirologyMolecular biologyPathogenesisInterferonmedicineTumor necrosis factor alphamedicine.symptommedicine.drugScandinavian Journal of Immunology
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