Search results for "Llar"
showing 10 items of 3592 documents
Simultaneous gas chromatographic determination of aliphatic C2−C20 n-carboxylic acids and their methyl esters using SE-30 and OV-351 quartz capillary…
1983
Simultaneous determination of aliphatic C2−C20 carboxylic acids and their methyl esters was carried out using SE-30 and OV-351 quartz capillary columns with temperature programming. Complete resolution of all 36 components was achieved. On SE-30 the methyl ester and the corresponding free acid are eluted in turn, whereas on OV-351 acetic acid eluted after methyl octanoate, after which the Cn methyl ester and Cn-6 carboxylic acid (n>9) are eluted one after the other. A non-polar SE-30 column is better for long-chain acids giving sharp peaks without tailing, the analysis time of the mixture being less than 16 minutes. The weight response correction factors for compounds under optimum operatin…
A micellar liquid chromatographic method for quality control of pharmaceutical preparations containing tricyclic antidepressants
2002
Micellar liquid chromatography methods for quality control of pharmaceutical preparations (capsules, pills, tablets, injections) containing the tricyclic antidepressants amineptine, amitriptiline, clomipramine, doxepin, imipramine, melitracen and nortriptyline alone or together with other CNS drugs like diazepam, medazepam and perphenazine are described. The methods using micellar solutions of cetyltrimethylammonium bromide as mobile phases and UV detection are rapid and reproducible. Due to the versatility of interactions in micellar liquid chromatography, it is possible determine highly hydrophobic compounds such as TCAs in a short time using mobile phases containing low organic solvent c…
Gas chromatography of homologous esters
1985
Abstract The retention behaviour of C 1 C 18 n -alkyl esters of butanoic 2-, 3- and 4-chlorobutanoic acids was examined isothermally at several temperatures on SE-30 and OV-351 capillary columns. Retention increments showing the effects of each position of chlorine substitution are presented. The considerable enhancement of terminal chlorine substitution is discussed together with the corresponding behaviour of the monochloropropanoate esters.
Direct acid-catalysed mechanical depolymerisation of fibre sludge to reducing sugars using planetary milling
2016
Abstract This study performed a direct solvent-free acid-catalysed mechanical depolymerisation of fibre sludge to reducing sugars which involves one step of acid milling in a planetary mill. The common reported ‘solvent-free’ mechanocatalytic depolymerisation of lignocellulose which includes 1) acid impregnation, 2) vacuum evaporation and 3) mechanocatalytic depolymerisation was also performed as a reference. The major converted monosaccharides were determined by capillary electrophoresis and the results of total reducing sugar (TRS) yields were carried out based on the 3,5-dinitrosalicylic acid (DNS) method. The results showed that the TRS conversion of direct acid-catalysed mechanical dep…
Determination of cationic surfactants by capillary zone electrophoresis and micellar electrokinetic chromatography with deoxycholate micelles in the …
2000
Mixtures of the cationic surfactants benzalkonium chloride (BKC) and cetylpyridinium chloride (CPC) were quickly resolved and reproducibly and reliably determined by using background electrolytes (BGEs) containing 80 mM borate, pH 8.5, bile salts and large concentrations of an organic solvent. When the bile salt is present, the separation mechanism changes from capillary zone electrophoresis (CZE) to a mixed micellar electrokinetic chromatography (MEKC)-CZE, with predominant MEKC interactions, which lead to an excellent resolution of all the solutes, including the C12-C18 homologues of BKC and CPC. A BGE containing 50 mM sodium deoxycholate and 30% ethanol for an extreme resolution, or 20% …
Characterization of totally chlorine-free effluents from Kraft pulp bleaching
1999
A capillary zone electrophoresis (CZE) method for analyzing the total acid hydrolysis products (monosaccharides and their derivatives) of the dissolved carbohydrates from a totally chlorine-free bleaching plant was developed. Several borate buffer concentrations and other running conditions were tested. Neutral monosaccharides (arabinose, galactose, glucose, mannose, rhamnose and xylose) in hydrolysates were derivatized by means of 4-aminobenzonitrile and resolved by 500 mM borate buffer (pH 9.5, 16.0 kV). The detection level was less than 10 fmol. In addition, the separation of some uronic acids and oligosaccharides was studied.
Langmuir-Blodgett Mono- and Multilayer Assemblies of Amphiphilic Liquid- Crystalline n-Alkyl-4′-n-alkoxybiphenyl-4-carboxylates. I
1991
Five n-Alkyl-4′-Alkoxy-biphenyl-4-carboxylates were investigated as Langmuir monolayers at the air/ water interface and as Langmuir-Blodgett (LB) films on solid supports. All five compounds form stable monolayers at the air/water interface and can be transferred onto solid supports yielding LB-films, whose structures and kinetic behavior strongly depend on the headgroup. The structures of the LB-films were investigated by means of optical textures and X-ray diffraction and compared with the structures of the corresponding bulk phases which were investigated by means of Differential Scanning Calorimetry and X-ray powder diffraction. The LB-films of the acid and the two methyl esters exhibit …
Prediction of the curing time of Spanish hams using peptide profiles established by capillary zone electrophoresis
2009
Abstract A capillary zone electrophoresis procedure for the prediction of curing time of Spanish hams using peptide profiles has been developed. Excellent resolution between the seven peptide peaks was achieved within 30 min analysis time with a BGE containing 60 mM MgSO 4 and 50 mM phosphate at pH 2.5. Using hams with curing times of 6, 8 and 12 months, both linear discriminant analysis (LDA) and multiple linear regression (MLR) models were constructed. In both cases, two different normalisation procedures of the peak areas were compared. Using LDA, all the ham samples corresponding to the three categories were correctly classified. Using MLR, the ham curing time could be predicted with av…
Determination of optical purity of phosphonic acid analogues of aromatic amino acids by capillary electrophoresis with alpha-cyclodextrin.
2000
A simple and efficient method for the determination of enantiomeric purity of structurally diverse phosphonic and phosphinic acid analogues of phenylalanine and phenylglycine using capillary electrophoresis is presented. These preliminary studies indicated that the enantiomer separation is strongly dependent on the structure of the aminophosphonic acid.
Gas chromatography of homologous esters
1984
Abstract The gas chromatographic retention behaviour of the butanoyl and 2-, 3- and 4-chlorobutanoyl esters of C 3 —C 5 saturated aliphatic branched-chain and unsaturated C 3 —C 6 alcohols on SE-30 and OV-351 glass capillary columns operated iso-thermally at several temperatures is reported. Retention index increments at 80, 120 and 160°C show the effects of chain branching and the olefinic and acetylenic unsaturation in the alkyl chain and the effect of the position of the chlorine substituent in the acyl chain. The results are compared with the behaviour of the corresponding n -alkyl esters and the chlorinated propanoyl esters.