Search results for "MICE"

FT-IR Investigation of the Urea State in AOT Reversed Micelles

2001

Abstract FT-IR spectra of the urea/sodium bis(2-ethylhexyl) sulfosuccinate (AOT)/CCl 4 system as a function of the urea-to-AOT molar ratio ( R urea ) at a fixed AOT concentration ([AOT]=0.1 mol·kg −1 ) have been recorded at 25°C. The experimental data are consistent with the hypothesis that at low R urea values urea is dispersed as monomers among the hydrophilic core of AOT reversed micelles, whereas at R urea >0.13 it is encapsulated as small molecular clusters. These clusters display some departures from the H-bonded structure of the pure solid urea attributable to their small size and to urea–AOT head group interactions. The stretching modes of AOT sulfonate groups are affected by the pr…

Halloysite nanotubes as nanoreactors for heterogeneous micellar catalysis

2021

Abstract Hypothesis Electrostatic attractions between the anionic head group of sodium alkylsulphates and the positively charged inner surface of halloysite nanotubes (HNTs) drive to the formation of tubular inorganic micelles, which might be employed as nanoreactors for the confinement of non polar compounds in aqueous media. On this basis, sodium alkylsulphates/halloysite hybrids could be efficient nanocatalysts for organic reactions occurring in water. Experiments Sodium decylsulphate (NaDeS) and sodium dodecylsulphate (NaDS) were selected for the functionalization of the halloysite cavity. The composition, the structure and the surface charge properties of the hybrid nanotubes were dete…

Structure, stability, and fragmentation of sodium bis(2-ethylhexyl)sulfosuccinate negatively charged aggregates in vacuo by MD simulations.

2014

Negatively charged supramolecular aggregates formed in vacuo by n bis(2-ethylhexyl)sulfosuccinate (AOT(-)) anions and n + n(c) sodium counterions (i.e., [AOT(n) Na(n+nc)](nc)) have been investigated by molecular dynamics (MD) simulations for n = 1 to 20 and n(c) = -1 to -5. By comparing the maximum excess charge values of negatively and positively charged AOTNa aggregates, it is found that the charge storage capability is higher for the latter systems, the difference decreasing as the aggregation number increases. Statistical analysis of physical properties like gyration radii and moment of inertia tensors of aggregates provides detailed information on their structural properties. Even for …

A halocin acting on Na+/H+ exchanger of Haloarchaea as a new type of inhibitor in NHE of mammals

2006

10 páginas, 3 figuras.

Flow cytometric kinetic assay of the activity of Na+/H+ antiporter in mammalian cells.

2004

Background The Na+/H+ exchanger (NHE) of mammalian cells is an integral membrane protein that extrudes H+ ion in exchange for extracellular Na+ and plays a crucial role in the regulation of intracellular pH (pHi). Thus, when pHi is lowered, NHE extrudes protons at a rate depending of pHi that can be expressed as pH units/s. Methods To abolish the activity of other cellular pH-restoring systems, cells were incubated in bicarbonate-free Dulbecco's modified Eagle's medium buffered with HEPES. Flow cytometry was used to determine pHi with 2′,7′-bis-(2-carboxyethyl)-5-(and-6)-carboxyfluorescein acetoxymethyl ester or 5-(and-6)-carboxy SNARF-1 acetoxymethyl ester acetate, and the appropriate fluo…

Fast-growing willow (Salix viminalis) as a filler in polyethylene composites

2018

Abstract The study investigated the possibility of using wood flour obtained from fast-growing willow chips (Salix viminalis) as an alternative for standard hard- and softwood flours used in the production of wood polymer composites (WPCs). The composites contained willow flour and polyethylene matrix (OPCs) were prepared, characterized and compared with other WPCs which had been filled with hard- or softwood flours. Moreover, the structural and functional properties were investigated and discussed. Greater hemicellulose contents and lower lignin contents in OPCs resulted in better impact strength values of those materials. Which is interesting, the chemical composition of OPCs was found si…

Evaluating pulp stiffness from fibre bundles by ultrasound

2012

A non-destructive ultrasonic tester was developed to measure the stiffness of pulp bundles. The mechanical properties of pulp are important when estimating the behaviour of paper under stress. Currently available pulp tests are tedious and alter the fibres structurally and mechanically. The developed tester employs (933 ± 15) kHz tweezer-like ultrasonic transducers and time-of-flight measurement through (9.0 ± 2.5) mm long and (0.8 ± 0.1) mm thick fibre bundles kept at (19.1 ± 0.4) °C and (62 ± 1)% RH. We determined the stiffness of soft wood pulps produced by three kraft pulping modifications: standard kraft pulp, (5.2 ± 0.4) GPa, prehydrolysis kraft pulp, (4.3 ± 0.4) GPa, and alkali extra…

Thermochemical behavior of Norway spruce ( Picea abies ) at 180-225 °C

2002

Norway spruce (Picea abies) was heated for 2–8 h in the temperature range 180–225 °C, under a steam atmosphere. The chemical analyses of the treated feedstock samples indicated that during heating (total mass loss 1.5–12.5% of the initial DS) carbohydrates (hemicelluloses and cellulose) were clearly more amenable to various degradation reactions than lignin. In addition, major water-soluble products released from the feedstock material during the treatments were classified into several compound groups and changes in the relative mass portion of these groups were monitored by GC during a separate experiment.

Solubilizzazione di composti organici in micelle di copolimeri termo- e pH-sensibili

2010

Reversed-phase liquid chromatography with mixed micellar mobile phases of Brij-35 and sodium dodecyl sulphate: a method for the analysis of basic com…

2015

Micellar liquid chromatography (MLC) is a reversed-phase liquid chromatographic (RPLC) mode, which uses a surfactant as a modifier, with significant changes in retention and selectivity with regard to the classical RPLC mode that employs mixtures of water and organic solvent. The anionic sodium dodecyl sulphate (SDS) is the most usual surfactant in MLC, but it also requires the addition of an organic solvent to decrease the retention times and increase the efficiency. In particular, positively charged basic compounds are strongly retained by the stationary phase modified by adsorption of SDS monomers and require the addition of a strong solvent, such as propanol or pentanol. The non-ionic s…