Search results for "Magnetic Resonance"

showing 10 items of 4721 documents

Neutron Radiography Visualization of Solid Particles in Stirring Liquid Metal

2015

Abstract This paper presents the analysis of the first dynamic neutron radiography experiment that visualized motion of solid particles in liquid metal, which was stirred by a system of four counter-rotating magnets. The paper also contains the quantitative results derived from neutron images: the distribution of particle concentration, number of admixed particles and velocities as functions of the magnet rotation speed.

permanent magnet stirrerLiquid metalMaterials scienceSolid particleNeutron imagingRotational speedsolid particlesPhysics and Astronomy(all)Molecular physicsVisualizationNuclear magnetic resonanceliquid metalneutron radiographyMagnetParticleNeutronPhysics Procedia
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Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct

2017

The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). The electronic structure of 1 is probed using combination of magnetic measurements, EPR spectroscopy and computational studies. The V–Si bond strength and complex forming mechanism between vanadocene and NHSi ligand is elucidated using computational methods.   peerReviewed

piiVanadiumchemistry.chemical_elementElectronic structure010402 general chemistryPhotochemistry01 natural sciencesvanadiiniAdductlaw.inventionInorganic Chemistrychemistry.chemical_compoundlawcoordination complexesElectron paramagnetic resonanceta116010405 organic chemistryChemistryLigandBond strengthSilylenesiliconkompleksiyhdisteetVanadocene0104 chemical sciencesCrystallographyvanadiumDalton Transactions
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Grafting of polymer chains on the surface of carbon nanotubes via nitroxide radical coupling reaction

2016

Poly(butylene succinate)/MWCNTs nanocomposites with improved dispersion and with nanotubes embedded/immobilized into the polymer matrix were here prepared by an alternative "grafting to" method based on thenitroxide radical coupling reaction. Poly(butylene succinate) (PBS) was grafted on the surface of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) modified multi-walled carbon nanotubes (MWCNTs) via a nitroxide radical coupling reaction. TEMPO functionalized MWCNTs (MWCNTs-g-TEMPO) were synthesized using the Cu(I)-catalyzed azide/alkyne click chemistry approach and the covalent bond of the nitroxide moieties onto the MWCNTs was confirmed via electron paramagnetic resonance (EPR) spectroscopy.…

polymer grafting; MWCNTs; nitroxide radical coupling (NRC); click chemistry; electron paramagnetic resonance (EPR); rheologyPolymers and PlasticsClick chemistryElectron paramagnetic resonance (EPR)MWCNTNitroxide radical coupling (NRC)RheologyPolymer grafting
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Acoustic, neural, and perceptual correlates of polyphonic timbre

2012

polyphonic timbremonophonic timbresointivärifMRInon-parametric statistical significance estimationhavaitseminenmusiikkipsykologiakognitiiviset prosessitfunctional magnetic resonance imagingacoustic featureshomofoniakorrelaatioaivokuoritoiminnallinen magneettikuvausperceptual dimensionstunteetakustiikkaaivotutkimuspolyfoniaaivot
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.Single-Ion Magnetic Behaviour in an Iron(III) Porphyrin Complex: A Dichotomy Between High Spin and 5/2-3/2 Spin Admixture

2020

International audience; A mononuclear iron(III) porphyrin compound exhibiting unexpectedly slow magnetic relaxation, which is a characteristic of single-ion magnet behaviour, is reported. This behaviour originates from the close proximity (approximate to 550 cm(-1)) of the intermediate-spinS=3/2 excited states to the high-spinS=5/2 ground state. More quantitatively, although the ground state is mostlyS=5/2, a spin-admixture model evidences a sizable contribution (approximate to 15 %) ofS=3/2 to the ground state, which as a consequence experiences large and positive axial anisotropy (D=+19.2 cm(-1)). Frequency-domain EPR spectroscopy allowed them(S)= |+/- 1/2⟩->|+/- 3/2&Rig…

porphyrinoids010402 general chemistry[MATH.MATH-FA]Mathematics [math]/Functional Analysis [math.FA]01 natural sciencesMolecular physicsCatalysislaw.inventionMagnetizationchemistry.chemical_compoundiron[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]lawMössbauer spectroscopy[CHIM.COOR]Chemical Sciences/Coordination chemistryAnisotropyElectron paramagnetic resonanceSpin (physics)010405 organic chemistryChemistryOrganic ChemistryGeneral ChemistryPorphyrin0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryExcited statesingle-ion magnetsdensity functional calculationsmagnetic propertiesGround state
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Cough is dangerous : neural correlates of implicit body symptoms associations

2016

The negative interpretation of body sensations (e.g., as sign of a severe illness) is a crucial cognitive process in pathological health anxiety (HA). However, little is known about the nature and the degree of automaticity of this interpretation bias. We applied an implicit association test (IAT) in 20 subjects during functional magnetic resonance imaging (fMRI) to investigate behavioral and neural correlates of implicit attitudes towards symptom words. On the behavioral level, body symptom words elicited strong negative implicit association effects, as indexed by slowed reaction times when symptom words were paired with the attribute harmless (incongruent condition) relative to a control …

prefrontal cortexprefrontal cortex (PFC)lcsh:BF1-990functional magnetic resonance imaging (fMRI)executive functionsfunctional magnetic resonance imagingExecutive Functionhealth anxietylcsh:Psychologyddc:150150 PsychologiePsychologyhealth anxiety implicit association test functional magnetic resonance imaging prefrontal cortex executive functionsimplicit association test150 PsychologyGeneral PsychologyHealth AnyietyOriginal Research
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Individualized Template MRI Is a Valid and Reliable Alternative to Individual MRI for Spatial Tracking in Navigated TMS Studies in Healthy Subjects

2020

Objectives: Navigated transcranial magnetic stimulation (nTMS) provides significant benefits over classic TMS. Yet, the acquisition of individual structural magnetic resonance images (MRIindividual) is a time-consuming, expensive, and not feasible prerequisite in all subjects for spatial tracking and anatomical guidance in nTMS studies. We hypothesize that spatial transformation can be used to adjust MRI templates to individual head shapes (MRIwarped) and that TMS parameters do not differ between nTMS using MRIindividual or MRIwarped.Materials and Methods: Twenty identical TMS sessions, each including four different navigation conditions, were conducted in 10 healthy subjects (one female, 2…

primary motor cortextranscranial magnetic stimulationtemplate magnetic resonance imagesspatial transformationmotor evoked potentialsnavigationlcsh:Neurosciences. Biological psychiatry. Neuropsychiatrylcsh:RC321-571Frontiers in Human Neuroscience
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Structured reporting of rectal cancer staging and restaging: A consensus proposal

2021

Background: Structured reporting (SR) in oncologic imaging is becoming necessary and has recently been recognized by major scientific societies. The aim of this study was to build MRI-based structured reports for rectal cancer (RC) staging and restaging in order to provide clinicians all critical tumor information. Materials and Methods: A panel of radiologist experts in abdominal imaging, called the members of the Italian Society of Medical and Interventional Radiology, was established. The modified Delphi process was used to build the SR and to assess the level of agreement in all sections. The Cronbach’s alpha (Cα) correlation coefficient was used to assess the internal consistency of ea…

re-stagingCancer Researchmedicine.medical_specialtyStagingColorectal cancerIntraclass correlationModified delphiArticle030218 nuclear medicine & medical imaging03 medical and health sciencesRe‐staging0302 clinical medicineMagnetic resonance imagingmagnetic resonance imaging; rectal cancer; re‐staging; staging; structured reportingCronbach's alphaStructured reportingInternal consistencymedicineMedical physicsRectal cancerRC254-282Final versionmedicine.diagnostic_testbusiness.industryNeoplasms. Tumors. Oncology. Including cancer and carcinogensInterventional radiologymedicine.diseaseOncology030220 oncology & carcinogenesisbusinessStructured reporting
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The McKenzie method in assessing, classifying and treating non-specific low back pain in adults with special reference to the centralization phenomen…

2010

reliabilityMcKenzie methodkipuortopedinen manipulaatiohoitofysioterapiacentralization phenomenonorthopaedic manual therapyselkäsairaudetalaselkäkipurandomized controlled trialadultsmagnetic resonance imagingselkäkuntoutusdiagnoosiMcKenzien menetelmälow back painaikuisetluokitusreliabiliteetti
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Characterization of the metabolic profile and identification of potential therapeutic targets in advanced prostate cancer patients

2023

INTRODUCCIÓN El cáncer de próstata (CaP) representa el segundo tumor en incidencia en hombres y es la quinta causa de muerte por cáncer a nivel global. El CaP es un tumor hormono-dependiente, que requiere de la activación del receptor de andrógenos (AR) para su proliferación. Clínicamente, se caracteriza por una gran variabilidad en su evolución, progresando desde una condición indolente hasta un fenotipo agresivo que puede diseminarse y metastatizar a los nodos linfáticos y huesos. Actualmente, el diagnóstico temprano del CaP se realiza mediante la determinación sérica del antígeno prostático específico (PSA) y el examen rectal digital (DRE). Si estas pruebas dan resultados anómalos y hay …

resonancia magnética nuclearesencialidad génicacáncer de próstatatherapeutic targetbiomarkersUNESCO::CIENCIAS TECNOLÓGICASprostate cancerdianas terapéuticasmetabolomicsnuclear magnetic resonancebiomarcadoresgene essentialityUNESCO::CIENCIAS MÉDICASmetabolómica
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