Search results for "Magnetization"
showing 10 items of 550 documents
Spin crossover in a tetranuclear Cr(III)-Fe(III)3 complex
2004
A novel heteronuclear exchange-coupled complex [Cr I I I {(CN)Fe I I I -( 5 L)} 3 (CN) 3 ] containing a pentadentate blocking ligand 5 L was synthesized. The X-ray structure shows that a meridional isomer applies with inequivalent Fe I I I centers. The complex exhibits a thermally induced spin crossover along with the exchange coupling. Mossbauer spectra indicate a spin transition between S = ½ and S = 5/2 states although a considerable amount of Fe I I I centers stays high-spin at T = 6 K. The magnetization, the magnetic susceptibility, and the Mossbauer data were fitted in one run with a spin crossover model taking into account exchange interactions among all metal centers.
Nonexponential 2H spin-lattice relaxation as a signature of the glassy state
1990
Abstract High-precision measurements of 2H spin-lattice relaxation on several molecular glass-forming liquids have been performed. As a general feature the following can be stated: At temperatures more than ten to twenty degrees above the calorimetric glass transition temperature Tg the 2H spin-lattice relaxation is exponential; below that temperature regime the relaxation is nonexponential. This crossover from exponential to nonexponential magnetization recovery implies that no common spin temperature caused by spin diffusion exists in a 2H glass. This contrasts 1H spin-lattice relaxation which is found to be strictly monoexponential throughout. The occurrence of nonexponential 2H relaxati…
Pressure induced increase in Tc for the organic-based magnet FeII(TCNE)2 (TCNE=tetracyanoethylene)
2013
Abstract Pressure dependent magnetization and 57Fe Mossbauer studies were performed on Fe(TCNE)[C4(CN)8]1/2·zCH2Cl2 (TCNE = tetracyanoethylene). Pressure did not influence the Mossbauer parameters in paramagnetic state. Mossbauer data reveals the onset of magnetic ordering at 130 K and significant enhancement of the magnetic ordering temperature from 100 to 150 K accompanied by an increase of the spontaneous magnetization, which is higher than reported from the magnetic data, and application of pressure induces the reversible formation of a new, metastable magnetic species. These changes suggest an increase of the dimensionality of magnetic interaction, i.e., stronger interlayer coupling. A…
Crystal field effects and magnetic properties of Dy2Te3
1995
Abstract Magnetic susceptibility and magnetization measurements are presented for Dy 2 Te 3 . By means of crystal field calculations the energy levels of ground state and crystal field potentials for Dy 3+ ions have been evaluated taking the exchange interactions into account.
Lateral indirect exchange coupling in a two-dimensional nanostripe array
2002
We observe a lateral indirect exchange coupling in a multistripe system of parallel Fe nanostripes grown by self-organized growth on a vicinal single-crystal W(110) surface. The width and the distance between the stripes of monolayer height were modified via the total amount of deposited Fe. The easy axis of the magnetization lies perpendicular to the stripe edges and in the surface plane, thus resulting in a ferromagnetic dipolar coupling. In addition to the dipolar coupling we observe an antiferromagnetic indirect exchange coupling for the nanostripe system covered by Au. The coupling causes a superferromagnetic phase transition in the nanostripe array.
Magnetization and61Ni Mössbauer effect study of the ternary arsenide CrNiAs
2008
The results of x-ray diffraction, dc magnetization, and 61Ni M?ssbauer spectroscopy studies of the ternary arsenide CrNiAs are reported. This compound crystallizes in the orthorhombic Fe2P-type structure (space group ) with the lattice parameters a = 6.1128(2)?? and c = 3.6585(1)??. CrNiAs is a mean-field ferromagnet with Curie temperature TC = 171.9(1)?K and the critical exponents ? = 0.514(18), ? = 1.010(16), and ? = 2.922(10). The temperature dependence of the magnetic susceptibility above TC follows the modified Curie?Weiss law with a paramagnetic Curie temperature of 176.0(3)?K and effective magnetic moment per transition metal atom of 2.42(1)??B. The magnetic moment per formula unit a…
Geometric, electronic, and magnetic structure ofCo2FeSi: Curie temperature and magnetic moment measurements and calculations
2005
In this work a simple concept was used for a systematic search for materials with high spin polarization. It is based on two semiempirical models. First, the Slater-Pauling rule was used for estimation of the magnetic moment. This model is well supported by electronic structure calculations. The second model was found particularly for ${\mathrm{Co}}_{2}$ based Heusler compounds when comparing their magnetic properties. It turned out that these compounds exhibit seemingly a linear dependence of the Curie temperature as function of the magnetic moment. Stimulated by these models, ${\mathrm{Co}}_{2}\mathrm{FeSi}$ was revisited. The compound was investigated in detail concerning its geometrical…
On/Off Photoswitching in a Cyanide-Bridged {Fe2Co2} Magnetic Molecular Square
2013
International audience; A repeatable bidirectional paramagnetic ↔ diamagnetic photomagnetic effect has been observed in the cyanide-bridged Fe-Co square complex {[Fe{B(pz)(4)}(CN)(3)](2)[Co(bik)(2)](2)}(ClO(4))(2)*3H(2)O [B(pz)(4) = tetrapyrazolylborate, bik = bis(1-methylimidazol-2-yl)ketone]. Magnetic measurements and low-temperature single-crystal X-ray diffraction experiments have shown that a complete electron transfer from the diamagnetic Fe(II)-Co(III) state to the paramagnetic Fe(III)-Co(II) metastable state is induced by 808 nm laser light irradiation, whereas the diamagnetic state is recovered in an almost quantitative yield under irradiation at 532 nm.
Cyanide-bridged Fe(III)–Co(II) bis double zigzag chains with a slow relaxation of the magnetisation
2003
Reaction of [FeIII(bipy)(CN)4]¯ with fully solvated MII cations [M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains [[FeIII(bipy)(CN)4]2MII(H2O)]·MeCN·1/2H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects. Luminita Marilena, Toma, Luminita.Toma@uv.es ; Lescouezec, Alain Francois Rodri, Alain.Lescouezec@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Julve Olcina, Miguel, Miguel.Julve@uv.es
Thermal Stability of a DC/DC Converter with Inductor in Partial Saturation
2021
Inductors operated in quasi saturation in dc–dc converters allow reduction of the core size and realization costs; on the other hand, they imply an increase of dissipated power that can jeopardize the thermal stability of the converter. In this article, this issue is studied by a mathematical model able to represent both the inductor nonlinearity and its temperature dependence. The main losses, such as ohmic, skin effect and magnetic, are taken into account in the model. The inductor is characterized by a polynomial curve whose parameters are a function of the temperature. Finally, the whole converter is modeled and simulation results, obtained on a boost converter, are compared with experi…