6533b874fe1ef96bd12d6262

RESEARCH PRODUCT

Cyanide-bridged Fe(III)–Co(II) bis double zigzag chains with a slow relaxation of the magnetisation

Michel VerdaguerMiguel JulveLuminita Marilena TomaFrancesc LloretRodrigue LescouëzecJacqueline Vaissermann

subject

Cyanide-bridged Fe(III)–Co(II)CyanideUNESCO::QUÍMICA:QUÍMICA [UNESCO]Catalysischemistry.chemical_compoundMagnetizationMaterials ChemistryAntiferromagnetismIsostructuralHysteresis effectsCondensed matter physicsUNESCO::QUÍMICA::Química inorgánicaRelaxation (NMR)Metals and AlloysGeneral ChemistryCyanide-bridged Fe(III)–Co(II) ; Slow relaxation ; Ferromagnetic ; Antiferromagnetic ; Hysteresis effectsAntiferromagnetic:QUÍMICA::Química inorgánica [UNESCO]Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyHysteresischemistryZigzagFerromagnetismFerromagneticCeramics and CompositesSlow relaxation

description

Reaction of [FeIII(bipy)(CN)4]¯ with fully solvated MII cations [M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains [[FeIII(bipy)(CN)4]2MII(H2O)]·MeCN·1/2H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects. Luminita Marilena, Toma, Luminita.Toma@uv.es ; Lescouezec, Alain Francois Rodri, Alain.Lescouezec@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Julve Olcina, Miguel, Miguel.Julve@uv.es

yearjournalcountryeditionlanguage
2003-08-23
10.1039/b302182nhttp://hdl.handle.net/10550/16806