Search results for "Metallurgy"

Electrical and structural characterization of metal-oxide-semiconductor capacitors with silicon rich oxide

2001

Metal-oxide-semiconductor capacitors in which the gate oxide has been replaced with a silicon rich oxide (SRO) film sandwiched between two thin SiO2 layers are presented and investigated by transmission electron microscopy and electrical measurements. The grain size distribution and the amount of crystallized silicon remaining in SRO after annealing have been studied by transmission electron microscopy, whereas the charge trapping and the charge transport through the dots in the SRO layer have been extensively investigated by electrical measurements. Furthermore, a model, which explains the electrical behavior of such SRO capacitors, is presented and discussed. © 2001 American Institute of …

Improving the material quality of silicon ingots by aluminum gettering during crystal growth

2016

We present a method for the purification of silicon ingots during the crystallization process that reduces significantly the width of the low charge carrier lifetime region at the ingot top. The back-diffusion of impurities from the ingot top is suppressed by adding a small amount of pure aluminum into the silicon melt right at the end of the solidification. We study the aluminum gettering effect by instrumental neutron activation analysis (INAA) and Fei imaging. Furthermore, we present a model for aluminum gettering of Fe in the silicon ingot that is in agreement with literature data for aluminum gettering at lower temperature. The distribution of iron in the ingots with and without alumin…

Potential of amorphous Mo–Si–N films for nanoelectronic applications

2003

The properties of amorphous metallic molybdenum–silicon–nitrogen (Mo–Si–N) films were characterised for use in nanoelectronic applications. The films were deposited by co-sputtering of molybdenum and silicon targets in a gas mixture of argon and nitrogen. The atomic composition, microstructure and surface roughness were studied by RBS, TEM and AFM analyses, respectively. The electrical properties were investigated in the temperature range 80 mK to 300 K. No transition into a superconductive state was observed. Nanoscale wires were fabricated using electron beam lithography with their properties measured as a function of temperature.

Microwave hydrothermal flash synthesis of nanocomposites Fe–Co alloy/cobalt ferrite

2004

Abstract The present article presents, for the first time, the last developments reported for an original microwave hydrothermal flash synthesis of Fe–Co alloys (FeyCo1−y)/cobalt ferrite (Fe3−xCoxO4) nanocomposites. Synthesis was performed in alcoholic solutions of ferrous chloride, cobalt chloride and sodium ethoxide (EtONa) using a microwave autoclave (The RAMO system) specially designed by authors. Compared with conventional synthesis, smaller grains (100 nm compared to 1 μm) can be produced in a short period (e.g. 10 s) using a less basic medium. In all the cases, the microstructure and the amount of metal inside the composite particles are very different from the product obtained via a…

MoSi2 Formation Mechanisms during a Spark Plasma Synthesis from Mechanically Activated Powder Mixture

2010

Preparation of Heusler thin films: The quaternary alloy CO2Fe0.5Mn0.5Si

2008

In this work the basic strategies for the preparation of CO2Mn0.5Fe0.5Si as an example for Heusler alloy thin films will be described. Texture and magnetic properties of these films will be discussed, especially with regard to different buffer layers and annealing temperatures. Finally, we will show the integration of Heusler thin films into magnetic tunnel junctions (MTJs) and calculate the effective spin polarization. (c) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Influence of nanoscale order–disorder transitions on the magnetic properties of Heusler compounds for spintronics

2017

Modifications in nanoscale chemical order are used to tune the magnetic properties, namely T-C, of Co2FeSixAl1-x (0 < x < 1). High-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) with Z-contrast reveals nanoscale regions of L2(1) order within a B2 matrix in the off-stoichiometry samples. Perhaps surprisingly, the latter, more chemically disordered structure, exhibits a higher T-C. Upon annealing, the off-stoichiometry samples become more homogeneous with the fraction of L2(1) order decreasing. The short-range order was also investigated using X-ray absorption fine structure (XAFS) measurements at the Co and Fe K edges. Since the local atomic environments of C…

Studies of the Phosphatization of Steel and its Corrosion Products

1986

The reaction of phosphoric acid with steel is a basic process in many technological procedures. A typical example is the pretreatment of steel surfaces for the application of coatings. The aim of the treatment is to clean the surface, to produce a homogeneousr tight, and smooth cover and to provide a reliable adhesion between the steel substrate and the coating. This example points out that the phase composition of the layer formed is of great interest, and that reactions with residues on the surface, such as oxides and corrosion products, have to be considered, too. The same holds for phosphate layers formed in order to modify the mechanical or corrosion behavior of steel surfaces. Because…

Influence of Plastic Deformation on the Corrosion Behaviour of As-Cast AlMg2 and AlCu4Mg1 Aluminium Alloys in NaCl Solution

2015

The influence of plastic deformation on the corrosion behavior of as-cast AlMg2 and AlCu4Mg1 aluminum alloys was studied at the microscale using the Electrochemical Microcell Technique and surface microgauges. It was shown that large strain gradients develop locally. The corrosion behavior of both alloys was affected by plastic deformation. The most active sites contain large strain gradients in AlMg2 and cracks with damage in the matrix in AlCu4Mg1.

Thermodiffusion of sodium polystyrene sulfonate in a supporting electrolyte

2019

Thermodiffusion, or the Soret phenomenon, is well understood in simple systems, but in multicomponent and polyvalent electrolyte systems the process becomes more complicated due to the coupling of fluxes. We experimentally investigate the time evolution of a concentration gradient generated by thermodiffusion of a polyelectrolyte (poly(sodium 4-styrene sulfonate), NaPSS) in a 1:1 supporting electrolyte. We also derive and solve the transport equations that are used to extract the Soret coefficient from the experimental observations. It is shown that NaPSS thermodiffusion in NaCl is strongly dependent on concentration, with almost 100% thermal separation in concentrations below 15 nmol L−1. …